Catalytic epoxidation of cyclohexene over mesoporous-silica immobilized Keggin-type tungstophosphoric acid

doi:10.1016/S1872-2067(11)60459-2

Abstract

Abstract: A series of aminosilylated mesoporous silica (SBA-15) samples with different contents of (3-aminopropyl)triethoxysilane (APTES), synthesized using a simple one-pot method, were used as hosts for immobilization of Keggin-type 12-phosphotungstic acid (H₃PW₁₂O₄₀). The loading of H₃PW₁₂O₄₀ increased with increasing content of grafted APTES. The obtained materials were calcined at different temperatures, and the tungsten species were highly dispersed inside the SBA-15 channels. The catalytic activities of these samples were tested in heterogeneous oxidation of cyclohexene using H₂O₂ as the oxidant. The effects of different loadings and treatment temperatures on the activities of the catalysts were also investigated. The catalysts calcined at 400 °C showed high catalytic activities and reusabilities.

Key words: 12-phosphotungstic acid, aminosilylation, SBA-15, epoxidation, cyclohexene

CAI Wen-Jia, ZHOU Yan, BAO Ren-Lie, YUE Bin, HE He-Yong. Catalytic epoxidation of cyclohexene over mesoporous-silica immobilized Keggin-type tungstophosphoric acid[J]. Chinese Journal of Catalysis, 2013, 34(1): 193-199.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60459-2

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