Synthesis of bionic-macro/microporous MgO-modified TiO2 for enhanced CO2 photoreduction into hydrocarbon fuels

doi:10.1016/S1872-2067(15)61111-1

Chinese Journal of Catalysis ›› 2016, Vol. 37 ›› Issue (6): 863-868.DOI: 10.1016/S1872-2067(15)61111-1

• Articles • Previous Articles Next Articles

Synthesis of bionic-macro/microporous MgO-modified TiO₂for enhanced CO₂ photoreduction into hydrocarbon fuels

Fang Wang^a,b, Yong Zhou^a,c,d, Ping Li^c,d, Libang Kuai^c,d, Zhigang Zou^b,c

a Key Laboratory of Modern Acoustics, MOE, Institute of Acoustics, School of Physics, Nanjing University, Nanjing 210093, Jiangsu, China;
b Department of Materials Science and Engineering, Nanjing University, Nanjing 210093, Jiangsu China;
c Ecomaterials and Renewable Energy Research Center (ERERC), Nanjing University, Nanjing 210093, Jiangsu, China;
d National Laboratory of Solid State Microstructures, Collaborative Innovation Center of Advanced Microstructures, Jiangsu Key Laboratory for NanoTechnology, Nanjing University, Nanjing 210093, Jiangsu, China

Received:2016-01-29 Revised:2016-04-13 Online:2016-05-30 Published:2016-05-30
Contact: Yong Zhou, Zhigang Zou
Supported by:
This work was supported by the National Basic Research Program of China (973 Program, 2014CB239302, 2013CB632404), the Natural Science Foundation of Jiangsu Province (BK20130053), the National Natural Science Foundation of China (51272101, 51202005, 21473091).

Abstract

Abstract:

The stems of water convolvulus were employed as biotemplates for the replication of their optimized 3D hierarchical architecture to synthesize porous MgO-modified TiO₂. The photocatalytic reduction of CO₂ with H₂O vapor into hydrocarbon fuel was studied with these MgO-TiO₂ nanostructures as the photocatalysts with the benefits of improved CO₂ adsorption and activation through incorporated MgO. Various factors involving CO₂ adsorption capacity, migration of charge carriers to the surface, and the number of activity sites, which depend on the amount of added MgO, determine the photocatalytic conversion efficiency.

Key words: Magnesium oxide, Titanium dioxide, Carbon dioxide photoreduction, Carbon dioxide activiation, Bionic-porous structure, Biotemplate

Fang Wang, Yong Zhou, Ping Li, Libang Kuai, Zhigang Zou. Synthesis of bionic-macro/microporous MgO-modified TiO₂for enhanced CO₂ photoreduction into hydrocarbon fuels[J]. Chinese Journal of Catalysis, 2016, 37(6): 863-868.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61111-1

https://www.cjcatal.com/EN/Y2016/V37/I6/863

References

[1] H. Yoneyama, Catal. Today, 1997, 39, 169-175.
[2] P. Usubharatana, D. McMartin, A. Veawab, P. Tontiwachwuthikul, Ind. Eng. Chem. Res, 2006, 45, 2558-2568.
[3] G. R. Dey, J. Nat. Gas. Chem., 2007, 16, 217-226.
[4] V. P. Indrakanti, J. D. Kubicki, H. H. Schobert, Energ. Environ. Sci., 2009, 2, 745-758.
[5] S. C. Roy, O. K. Varghese, M. Paulose, C. A. Grimes, ACS Nano., 2010, 4, 1259-1278.
[6] M. R. Hoffmann, J. A. Moss, M. M. Baum, Dalton Trans., 2011, 40, 5151-5158.
[7] T. Inoue, A. Fujishima, S. Konishi, K. Honda, Nature, 1979, 277, 637-638.
[8] K. R. Thampi, J. Kiwi, M. Gratzel, Nature, 1987, 327, 506-508.
[9] W. N. Wang, W. J. An, B. Ramalingam, S. Mukherjee, D. M. Niedzwiedzki, S. Gangopadhyay, P. Biswas, J. Am. Chem. Soc., 2012, 134, 11276-11281.
[10] F. C. Meunier, Angew. Chem. Int. Ed., 2011, 50, 4053-4054.
[11] Y. S. Chaudhary, T. W. Woolerton, C. S. Allen, J. H. Warner, E. Pierce, S. W. Ragsdale, F. A. Armstrong, Chem. Commun., 2012, 48, 58-61.
[12] S. C. Yan, S. X. Ouyang, J. Gao, M. Yang, J. Y. Feng, X. X. Fan, L. J. Wan, Z. S. Li, J. H. Ye, Y. Zhou, Z. G. Zou, Angew. Chem. Int. Ed., 2010, 49, 6400-6404.
[13] Q. Liu, Y. Zhou, J. H. Kou, X. Y. Chen, Z. P. Tian, J. Gao, S. C. Yan, Z. G. Zou, J. Am. Chem. Soc., 2010, 132, 14385-14387.
[14] N. Zhang, S. X. Ouyang, T. Kako, J. H. Ye. Chem. Commun., 2012, 48, 1269-1271.
[15] Y. H. Fu, D. R. Sun, Y. J. Chen, R. K. Huang, Z. X. Ding, X. Z. Fu, Z. H. Li, Angew. Chem. Int. Ed., 2012, 51, 3364-3367.
[16] W. G. Tu, Y. Zhou, Q. Liu, Z. P. Tian, J. Gao, X. Y. Chen, H. T. Zhang, J. G. Liu, Z. G. Zou, Adv. Funct. Mater., 2012, 22, 1215-1221.
[17] W. G. Tu, Y. Zhou, Q. Liu, S. C. Yan, S. S. Bao, X. Y. Wang, M. Xiao, Z. G. Zou, Adv. Funct. Mater., 2013, 23, 1743-1749.
[18] Y. Zhou, Z. P. Tian, Z. Y. Zhao, Q. Liu, J. H. Kou, X. Y. Chen, J. Gao, S. C. Yan, Z. G. Zou, ACS Appl. Mater. Interfaces, 2011, 3, 3594-3601.
[19] X. Y. Chen, Y. Zhou, Q. Liu, Z. D. Li, J. G. Liu, Z. G. Zou, ACS Appl. Mater. Interfaces, 2012, 4, 3372-3377.
[20] P. Li, Y. Zhou, W. G. Tu, Q. Liu, S. C. Yan, Z. G. Zou, ChemPlusChem, 2013, 78, 274-278.
[21] S. C. Feng, X. Y. Chen, Y. Zhou, W. G. Tu, P. Li, H. J. Li, Z. G. Zou, Nanoscale, 2014, 6, 1896-1900.
[22] K. Teramura, T Tanaka, H Ishikawa, Y Kohno, and T.O Funabiki, J. Phys. Chem. B, 2004, 108, 346-354.
[23] L. J. Liu, C. Y. Zhao, D. Pitts, H. L. Zhao, Y. Li, Catal. Sci. Technol., 2014, 4, 1539-1546.
[24] N. M. Dimitrijevic, B. K. Vijayan, O. G. Poluektov, T. Rajh, K. A. Gray, H. Y. He, P. Zapol, J. Am. Chem. Soc., 2011, 133, 3964-3971.
[25] D. Uner, M. M. Oymak, Catal. Today, 2012, 181, 82-88.
[26] H. Zhou, J. J. Guo, P. Li, T. X. Fan, D. Zhang, J. H. Ye, Sci. Rep., 2013, 3, 1667.
[27] F. Wang, Y. Zhou, P. Li, H. J. Li, W. G. Tu, S. C. Yan, Z. G. Zou, RSC Adv., 2014, 4, 43172-43177.
[28] Q. Y. Li, L. L. Zong, C. Li, J. J. Yang, Appl. Surf. Sci., 2014, 314, 458-463.
[29] M. S. Xue, Q. L. Guo, J. Chem. Phys., 2007, 127, 054705/1- 054705/5.
[30] D. K. Aswal, K. P. Muthe, S. Tawde, S. Chodhury, N. Bagkar, A. Singh, S. K. Gupta, J. V. Yakhmi, J. Cryst. Growth, 2002, 236, 661-666.
[31] J. S. Corneille, J. W. He, D. W. Goodman, Surf. Sci., 1994, 306, 269-278.
[32] K. S. W. Sing, D. H. Everett, R. Haul, L. Moscou, R. A. Pierotti, J. Rouquerol, T. Siemieniewska, Pure Appl. Chem., 1985, 57, 603-619.

Synthesis of bionic-macro/microporous MgO-modified TiO₂for enhanced CO₂ photoreduction into hydrocarbon fuels

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Sikai Wang, Xiang-Ting Min, Botao Qiao, Ning Yan, Tao Zhang. Single-atom catalysts: In search of the holy grails in catalysis [J]. Chinese Journal of Catalysis, 2023, 52(9): 1-13.
[2]	Weikang Wang, Shaobin Mei, Haopeng Jiang, Lele Wang, Hua Tang, Qinqin Liu. Recent advances in TiO₂-based S-scheme heterojunction photocatalysts [J]. Chinese Journal of Catalysis, 2023, 55(12): 137-158.
[3]	Yunqing Liu, Peiyu Xia, Lingyu Li, Xinyue Wang, Jiaqi Meng, Yuxin Yang, Yihang Guo. In-situ route for the graphitized carbon/TiO₂ composite photocatalysts with enhanced removal efficiency to emerging phenolic pollutants [J]. Chinese Journal of Catalysis, 2020, 41(9): 1378-1392.
[4]	Hui Xu, Ji-Long Shi, Shaoshuai Lyu, Xianjun Lang. Visible-light photocatalytic selective aerobic oxidation of thiols to disulfides on anatase TiO₂ [J]. Chinese Journal of Catalysis, 2020, 41(10): 1468-1473.
[5]	Dashuai Li, Yu Huang, Songmei Li, Changhua Wang, Yingying Li, Xintong Zhang, Yichun Liu. Thermal coupled photoconductivity as a tool to understand the photothermal catalytic reduction of CO₂ [J]. Chinese Journal of Catalysis, 2020, 41(1): 154-160.
[6]	Yapeng Dong, Rong Nie, Jixian Wang, Xiaogang Yu, Pengcheng Tu, Jiazang Chen, Huanwang Jing. Photoelectrocatalytic CO₂ reduction based on metalloporphyrin-modified TiO₂ photocathode [J]. Chinese Journal of Catalysis, 2019, 40(8): 1222-1230.
[7]	Yanting Shi, Qiaoling Zhang, Youzhi Liu, Junbo Chang, Jing Guo. Preparation of amphiphilic TiO₂ Janus particles with highly enhanced photocatalytic activity [J]. Chinese Journal of Catalysis, 2019, 40(5): 786-794.
[8]	Bin Shao, Wenning Zhao, Shu Miao, Jiahui Huang, Lili Wang, Gao Li, Wenjie Shen. Facet-dependent anchoring of gold nanoparticles on TiO₂ for CO oxidation [J]. Chinese Journal of Catalysis, 2019, 40(10): 1534-1539.
[9]	Ting Wang, Wanwen Li, Dandan Xu, Xuanmin Wu, Liwei Cao, Jianxin Meng. Strong visible absorption and excellent photocatalytic performance of brown TiO₂ nanoparticles synthesized using one-step low-temperature process [J]. Chinese Journal of Catalysis, 2017, 38(7): 1184-1195.
[10]	Yazi Liu, Shanshan Ding, Jian Xu, Huayang Zhang, Shaogui Yang, Xiaoguang Duan, Hongqi Sun, Shaobin Wang. Preparation of a p-n heterojunction BiFeO₃@TiO₂ photocatalyst with a core-shell structure for visible-light photocatalytic degradation [J]. Chinese Journal of Catalysis, 2017, 38(6): 1052-1062.
[11]	Susana Tostón, Rafael Camarillo, Fabiola Martínez, Carlos Jiménez, Jesusa Rincón. Supercritical synthesis of platinum-modified titanium dioxide for solar fuel production from carbon dioxide [J]. Chinese Journal of Catalysis, 2017, 38(4): 636-650.
[12]	Longhui Zheng, Xiaojuan Yu, Mingce Long, Qilin Li. Humic acid-mediated visible-light degradation of phenol on phosphate-modified and Nafion-modified TiO₂ surfaces [J]. Chinese Journal of Catalysis, 2017, 38(12): 2076-2084.
[13]	Honglin Gao, Jianmei Liu, Jin Zhang, Zhongqi Zhu, Genlin Zhang, Qingju Liu. Influence of carbon and yttrium co-doping on the photocatalytic activity of mixed phase TiO₂ [J]. Chinese Journal of Catalysis, 2017, 38(10): 1688-1696.
[14]	Guohong Xie, Xin Chang, Bal Ram Adhikari, Sapanbir S. Thind, Aicheng Chen. Photoelectrochemical degradation of acetaminophen and valacyclovir using nanoporous titanium dioxide [J]. Chinese Journal of Catalysis, 2016, 37(7): 1062-1069.
[15]	Jiejing Kong, Xiaodong Lai, Zebao Rui, Hongbing Ji, Shengfu Ji. Multichannel charge separation promoted ZnO/P25 heterojunctions for the photocatalytic oxidation of toluene [J]. Chinese Journal of Catalysis, 2016, 37(6): 869-877.