Thermal coupled photoconductivity as a tool to understand the photothermal catalytic reduction of CO2

doi:10.1016/S1872-2067(19)63475-3

Abstract

Abstract: Photocatalysis shows great promise in the field of solar energy conversion. One of the reasons for this is because it promotes the development of multi-field-coupled catalysis. In order to explore the principles of multi-field-coupled catalytic reactions, an in situ multi-field-coupled characterization technique is required. In this study, we obtained hydrogenated ST-01 TiO₂ and observed enhanced catalytic activity by thermal coupled photocatalysis. In situ photoconductivity was employed to understand the activity enhancement. The effects of the reaction temperature, reaction atmosphere, and oxygen vacancy (Ov) on the photoconductivity of TiO₂ were studied. After coupling thermal into photoconductivity measurement, highly active Ov-TiO₂ displayed rapid decay of photoconductivity in a CO₂ atmosphere and slow decay of photoconductivity in a N₂ atmosphere. These phenomena revealed that photothermal coupling assisted the detrapping of electrons at the Ov surface and promoted electron transfer to CO₂, which clearly explained the high photothermal catalytic activity of Ov-TiO₂. This study demonstrated that photoconductivity is a useful tool to help understand photothermal catalytic phenomena.

Key words: Photoconduction, Photothermalcatalytic, Titanium dioxide, Oxygen vacancy, Carbon dioxide reduction

Dashuai Li, Yu Huang, Songmei Li, Changhua Wang, Yingying Li, Xintong Zhang, Yichun Liu. Thermal coupled photoconductivity as a tool to understand the photothermal catalytic reduction of CO₂[J]. Chinese Journal of Catalysis, 2020, 41(1): 154-160.

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Thermal coupled photoconductivity as a tool to understand the photothermal catalytic reduction of CO₂

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