SiO2-supported Au-Ni bimetallic catalyst for the selective hydrogenation of acetylene

Abstract

Abstract:

Supported Au catalysts have been reported to exhibit high ethylene selectivity in the hydrogenation of acetylene, but the conversion is relatively low. Adding a second metal to Au has proven to be a promising approach to enhance its catalytic performance in acetylene hydrogenation. In this work, SiO₂-supported Au-Ni bimetallic catalysts were synthesized and investigated in the selective hydrogenation of acetylene. The Au-Ni bimetallic catalysts exhibited much higher catalytic performance than that of the corresponding monometallic Au or Ni catalysts. By tuning the reduction temperature and/or Ni loading, we obtained an Au-Ni/SiO₂ catalyst with optimal performance. The results of transmission electron microscopy imaging revealed that the Au-Ni bimetallic particles were highly dispersed on the SiO₂ support. Meanwhile, analysis of the bimetallic catalyst by energy-dispersive X-ray spectroscopy, high-resolution transmission electron microscopy, and in situ diffuse reflectance infrared Fourier transform spectroscopy demonstrated the formation of Au-Ni alloy, which contributed to the synergistic effect between Au and Ni in the hydrogenation of acetylene.

Key words: Gold, Nickel, Bimetallic catalyst, Synergistic effect, Acetylene hydrogenation

Mengqian Chai, Xiaoyan Liu, Lin Li, Guangxian Pei, Yujing Ren, Yang Su, Hongkui Cheng, Aiqin Wang, Tao Zhang. SiO₂-supported Au-Ni bimetallic catalyst for the selective hydrogenation of acetylene[J]. Chinese Journal of Catalysis, 2017, 38(8): 1338-1346.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/

https://www.cjcatal.com/EN/Y2017/V38/I8/1338

References

[1] B. M. Collins, US Patent 4126645, 1978.
[2] A. Borodzinski, G. C. Bond, Catal. Rev. Sci. Eng., 2006, 48, 91-144.
[3] A. Borodzinski, G. C. Bond, Catal. Rev. Sci. Eng., 2008, 50, 379-469.
[4] B. Yang, R. Burch, C. Hardacre, G. Headdock, P. Hu, ACS Catal., 2012, 2, 1027-1032.
[5] A. Borodzinski, A. Cybulski, Appl. Catal. A, 2000, 198, 51-66.
[6] J. Osswald, K. Kovnir, M. Armbruster, R. Giedigkeit, R. E. Jentoft, U. Wild, Y. Grin, R. Schlogl, J. Catal., 2008, 258, 219-227.
[7] T. V. Choudhary, C. Sivadinarayana, A. K. Datye, D. Kumar, D. W. Goodman, Catal. Lett., 2003, 86, 1-8.
[8] Y. H. Park, G. L. Price, Ind. Eng. Chem. Res., 1992, 31, 469-474.
[9] J. Panpranot, K. Kontapakdee, P. Praserthdam, J. Phys. Chem. B, 2006, 110, 8019-8024.
[10] I. Y. Ahn, H. L. Ji, S. S. Kum, S. H. Moon, Catal. Today, 2007, 123, 151-157.
[11] Q. W. Zhang, J. Li, X. X. Liu, Q. M. Zhu, Appl. Catal. A, 2000, 197, 221-228.
[12] M. Haruta, T. Kobayashi, H. Sano, N. Yamada, Chem. Lett., 1987, 405-408.
[13] Q. Fu, H. Saltsburg, M. Flytzani-Stephanopoulos, Science, 2003, 301, 935-938.
[14] C. Della Pina, E. Falletta, M. Rossi, Chem. Soc. Rev., 2012, 41, 350-369.
[15] H. S. Wei, X. F. Wei, X. Yang, G. Z. Yin, A. Q. Wang, X. Y. Liu, Y. Q. Huang, T. Zhang, Chin. J. Catal., 2015, 36, 160-167.
[16] Y. Tan, X. Y. Liu, L. L. Zhang, A. Q. Wang, L. Li, X. L. Pan, S. Miao, M. Haruta, H. S. Wei, H. Wang, F. J. Wang, X. D. Wang, T. Zhang, An-gew. Chem. Int. Ed., 2017, 56, 2709-2713.
[17] C. Aprile, A. Corma, M. E. Domine, H. Garcia, C. Mitchell, J. Catal., 2009, 264, 44-53.
[18] A. C. Gluhoi, J. W. Bakker, B. E. Nieuwenhuys, Catal. Today, 2010, 154, 13-20.
[19] X. Y. Liu, C. Y. Mou, S. Lee, Y. N. Li, J. Secrest, B. W. L. Jang, J. Catal., 2012, 285, 152-159.
[20] X. L. Yan, J. H. Bao, C. Yuan, J. Wheeler, W. Y. Lin, R. F. Li, B. W. L. Jang, J. Catal., 2016, 344, 194-201.
[21] A. Sarkany, A. Horvath, A. Beck, Appl. Catal. A, 2002, 229, 117-125.
[22] A. Sarkany, Z. Schay, K. Frey, E. Szeles, I. Sajo, Appl. Catal. A, 2010, 380, 133-141.
[23] X. Y. Liu, Y. N. Li, J. W. Lee, C. Y. Hong, C. Y. Mou, B. W. Jang, Appl. Catal. A, 2012, 439, 8-14.
[24] J. W. Lee, X. Y. Liu, C. Y. Mou, J. Chin. Chem. Soc., 2013, 60, 907-914.
[25] A. Sarkany, O. Geszti, G. Safran, Appl. Catal. A, 2008, 350, 157-163.
[26] A. J. McCue, R. T. Baker, J. A. Anderson, Faraday Discuss., 2016, 188, 499-523.
[27] G. Kyriakou, M. B. Boucher, A. D. Jewell, E. A. Lewis, T. J. Lawton, A. E. Baber, H. L. Tierney, M. Flytzani-Stephanopoulos, E. H. Sykes, Science, 2012, 335, 1209-1212.
[28] G. X. Pei, X. Y. Liu, A. Q. Wang, L. Li, Y. Q. Huang, T. Zhang, J. W. Lee, B. W. L. Jang, C. Y. Mou, New J. Chem., 2014, 38, 2043-2051.
[29] S. Hwang, J. Lee, U. G. Hong, J. C. Jung, J. H. Baik, D. J. Koh, H. Lim, I. K. Song, J. Nanosci. Nanotechnol., 2012, 12, 6051-6057.
[30] H. Ozay, Sci. Adv. Mater., 2013, 5, 575-582.
[31] H. Nishikawa, D. Kawamoto, Y. Yamamoto, T. Ishida, H. Ohashi, T. Akita, T. Honma, H. Oji, Y. Kobayashi, A. Hamasaki, T. Yokoyama, M. Tokunaga, J. Catal., 2013, 307, 254-264.
[32] S. A. Nikolaev, E. V. Golubina, L. M. Kustov, A. L. Tarasov, O. P. Tkachenko, Kinet. Catal., 2014, 55, 311-318.
[33] A. V. Chistyakov, P. A. Zharova, M. V. Tsodikov, S. A. Nikolaev, I. N. Krotova, D. I. Ezzhelenko, Kinet. Catal., 2016, 57, 803-811.
[34] A. Aguilar-Tapia, L. Delannoy, C. Louis, C. W. Han, V. Ortalan, R. Zanella, J. Catal., 2016, 344, 515-523.
[35] Y. Azizi, C. Petit, V. Pitchon, J. Catal., 2008, 256, 338-334.
[36] G. X. Pei, X. Y. Liu, A. Q. Wang, A. F. Lee, M. A. Isaacs, L. Li, X. L. Pan, X. F. Yang, X. D. Wang, Z. J. Tai, K. Wilson, T. Zhang, ACS Catal., 2015, 5, 3717-3725.
[37] G. X. Pei, X. Y. Liu, X. F. Yang, L. L. Zhang, A. Q. Wang, L. Li, H. Wang, X. D. Wang, T. Zhang, ACS Catal., 2017, 7, 1491-1500.
[38] S. Labat, F. Bocquet, B. Gilles, O. Thomas, Scripta Mater., 2004, 50, 717-721.
[39] M. Tsuji, D. Yamaguchi, M. Matsunaga, K. Ikedo, Cryst. Growth Des., 2011, 11, 1995-2005.
[40] S. H. Zhou, Z. Ma, H. F. Yin, Z. L. Wu, B. Eichhorn, S. H. Overbury, S. Dai, J. Phys. Chem. C, 2009, 113, 5758-5765.
[41] X. Y. Liu, A. Q. Wang, X. D. Wang, C. Y. Mou, T. Zhang, Chem. Com-mun., 2008, 3187-3189.
[42] X. Wei, X. F. Yang, A. Q. Wang, L. Li, X. Y. Liu, T. Zhang, C. Y. Mou, J. Li, J. Phys. Chem. C, 2012, 116, 6222-6232.
[43] A. Q. Wang, X. Y. Liu, C. Y. Mou, T. Zhang, J. Catal., 2013, 308, 258-271.
[44] D. S. Wang,Y. D. Li, J. Am. Chem. Soc., 2010, 132, 6280-6281.
[45] X. Y. Liu, M. H. Liu, Y. C. Luo, C. Y. Mou, S. D. Lin, H. K. Cheng, J. M. Chen, J. F. Lee, T. S. Lin, J. Am. Chem. Soc., 2012, 134, 10251-10258.
[46] M. Mihaylov, H. Knoezinger, K. Hadjiivanov, B. C. Gates, Chem. Ing. Tech., 2007, 79, 795-806.
[47] K. I. Hadjiivanov, G. N. Vayssilov, Adv. Catal., 2002, 47, 307-511.
[48] S. A. Nikolaev, D. A. Pichugina, D. F. Mukhamedzyanova, Gold Bull., 2012, 45, 221-231.
[49] X. Y. Liu, C. Y. Mou, S. Lee, Y. N. Li, J. Secrest, B. W. L. Jang, J. Catal., 2012, 285, 152-159.
[50] M. Boronat, P. Concepción, A. Corma, J. Phys. Chem. C, 2009, 113, 16772-16784.
[51] J. H. Xu, Y. Q. Huang, X. F. Yang, L. He, H. R. Zhou, Q. Q. Lin, T. Zhang, H. R. Geng, J. Nanosci. Nanotechnol., 2014, 14, 6894-6899.

SiO₂-supported Au-Ni bimetallic catalyst for the selective hydrogenation of acetylene

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Defa Liu, Bin Sun, Shuojie Bai, Tingting Gao, Guowei Zhou. Dual co-catalysts Ag/Ti₃C₂/TiO₂ hierarchical flower-like microspheres with enhanced photocatalytic H₂-production activity [J]. Chinese Journal of Catalysis, 2023, 50(7): 273-283.
[2]	Gong Zhang, Wei-Song Zhang, Xiao-Yu Wang, Yang Yang, Ding-Wei Ji, Boshun Wan, Qing-An Chen. Ni-catalyzed unnatural prenylation and cyclic monoterpenation of heteroarenes with isoprene [J]. Chinese Journal of Catalysis, 2023, 49(6): 123-131.
[3]	Jingjing Li, Fengwei Zhang, Xinyu Zhan, Hefang Guo, Han Zhang, Wen-Yan Zan, Zhenyu Sun, Xian-Ming Zhang. Precise design of nickel phthalocyanine molecular structure: Optimizing electronic and spatial effects for remarkable electrocatalytic CO₂ reduction [J]. Chinese Journal of Catalysis, 2023, 48(5): 117-126.
[4]	Eun Hyup Kim, Min Hee Lee, Jeehye Kim, Eun Cheol Ra, Ju Hyeong Lee, Jae Sung Lee. Synergy between single atoms and nanoclusters of Pd/g-C₃N₄ catalysts for efficient base-free CO₂ hydro-genation to formic acid [J]. Chinese Journal of Catalysis, 2023, 47(4): 214-221.
[5]	Diab khalafallah, Yunxiang Zhang, Hao Wang, Jong-Min Lee, Qinfang Zhang. Energy-saving electrochemical hydrogen production via co-generative strategies in hybrid water electrolysis: Recent advances and perspectives [J]. Chinese Journal of Catalysis, 2023, 55(12): 44-115.
[6]	Qixian Xie, Dan Ren, Lichen Bai, Rile Ge, Wenhui Zhou, Lu Bai, Wei Xie, Junhu Wang, Michael Grätzel, Jingshan Luo. Investigation of nickel iron layered double hydroxide for water oxidation in different pH electrolytes [J]. Chinese Journal of Catalysis, 2023, 44(1): 127-138.
[7]	Jiang Zhang, Zijian Wang, Mugeng Chen, Yifeng Zhu, Yongmei Liu, Heyong He, Yong Cao, Xinhe Bao. N-doped carbon layer-coated Au nanocatalyst for H₂-free conversion of 5-hydroxymethylfurfural to 5-methylfurfural [J]. Chinese Journal of Catalysis, 2022, 43(8): 2212-2222.
[8]	Yingjie Zhou, Tianfu Liu, Yuefeng Song, Houfu Lv, Qingxue Liu, Na Ta, Xiaomin Zhang, Guoxiong Wang. Highly dispersed nickel species on iron-based perovskite for CO₂ electrolysis in solid oxide electrolysis cell [J]. Chinese Journal of Catalysis, 2022, 43(7): 1710-1718.
[9]	Cong Liu, Xuanhao Mei, Ce Han, Xue Gong, Ping Song, Weilin Xu. Tuning strategies and structure effects of electrocatalysts for carbon dioxide reduction reaction [J]. Chinese Journal of Catalysis, 2022, 43(7): 1618-1633.
[10]	Huining Wang, Anxiang Guan, Junbo Zhang, Yuying Mi, Si Li, Taotao Yuan, Chao Jing, Lijuan Zhang, Linjuan Zhang, Gengfeng Zheng. Copper-doped nickel oxyhydroxide for efficient electrocatalytic ethanol oxidation [J]. Chinese Journal of Catalysis, 2022, 43(6): 1478-1484.
[11]	Jinling Cheng, Dingsheng Wang. 2D materials modulating layered double hydroxides for electrocatalytic water splitting [J]. Chinese Journal of Catalysis, 2022, 43(6): 1380-1398.
[12]	Wei Zhong, Jiachao Xu, Ping Wang, Bicheng Zhu, Jiajie Fan, Huogen Yu. Novel core-shell Ag@AgSe_x nanoparticle co-catalyst: In situ surface selenization for efficient photocatalytic H₂ production of TiO₂ [J]. Chinese Journal of Catalysis, 2022, 43(4): 1074-1083.
[13]	Bo Zhou, Mengyu Li, Yingying Li, Yanbo Liu, Yuxuan Lu, Wei Li, Yujie Wu, Jia Huo, Yanyong Wang, Li Tao, Shuangyin Wang. Cobalt-regulation-induced dual active sites in Ni₂P for hydrazine electrooxidation [J]. Chinese Journal of Catalysis, 2022, 43(4): 1131-1138.
[14]	Lulu An, Shaofeng Deng, Xuyun Guo, Xupo Liu, Tonghui Zhao, Ke Chen, Ye Zhu, Yuxi Fu, Xu Zhao, Deli Wang. Enhancing hydrogen electrocatalytic oxidation on Ni₃N/MoO₂ in-plane heterostructures in alkaline solution [J]. Chinese Journal of Catalysis, 2022, 43(12): 3154-3160.
[15]	Haoran Yu, Danxu Liu, Hengyi Wang, Haishuang Yu, Qingyun Yan, Jiahui Ji, Jinlong Zhang, Mingyang Xing. Singlet oxygen synergistic surface-adsorbed hydroxyl radicals for phenol degradation in CoP catalytic photo-Fenton [J]. Chinese Journal of Catalysis, 2022, 43(10): 2678-2689.