Tuning the growth of Cu-MOFs for efficient catalytic hydrolysis of carbonyl sulfide

Abstract

Abstract:

Development of the high activity, promoter-free catalysts for carbonyl sulfide (COS) hydrolysis is important for the efficient utilization of various feedstocks. In this study, the Cu-based met-al-organic framework HKUST-1 is synthesized by a simple and mild anodic-dissolution electro-chemical method. The physical and chemical properties of the samples are characterized by several techniques, including scanning electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller analysis and X-ray photoelectron spectroscopy. The results reveal that the synthesis voltage plays a crucial role in controlling the morphology of the resulting HKUST-1. The obtained samples function as novel catalysts for the hydrolysis of COS. A high efficiency, approaching 100%, can be achieved for the conversion of COS at 150℃ over the optimal HKUST-1 synthesized at 25 V. This is significantly higher than that of the sample pre-pared by the traditional hydrothermal method. Additionally, the effects of the water temperature and the flow velocity on the hydrolysis of COS are also investigated in detail. Finally, a possible reaction pathway of COS hydrolysis over HKUST-1 is also proposed. This work represents the first example of MOFs applied to the catalytic hydrolysis of COS. The results presented in this study can be anticipated to give a feasible impetus to design novel catalysts for removing the sulfur-containing compounds.

Key words: Metal-organic framework, Carbonyl sulfide, Electrochemical synthesis, Catalytic hydrolysis, HKUST-1

Lijuan Shen, Gaojie Wang, Xiaoxiao Zheng, Yanning Cao, Yufeng Guo, Ke Lin, Lilong Jiang. Tuning the growth of Cu-MOFs for efficient catalytic hydrolysis of carbonyl sulfide[J]. Chinese Journal of Catalysis, 2017, 38(8): 1373-1381.

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