Pt/Nb-WOx for the chemoselective hydrogenolysis of glycerol to 1,3-propanediol: Nb dopant pacifying the over-reduction of WOx supports

doi:10.1016/S1872-2067(18)63074-8

Abstract

Abstract:

Selective hydrogenolysis of glycerol to 1,3-propanediol (1,3-PD) is an important yet challenging method for the transformation of biomass into value-added chemicals due to steric hindrance and unfavorable thermodynamics. In previous studies, chemoselective performances were found demanding and sensitive to H₂ pressure. In this regard, we manipulate the chemical/physical characteristics of the catalyst supports via doping Nb into WO_x and prepared 1D needle-, 2D flake-, and 3D sphere-stack mesoporous structured Nb-WO_x with increased surface acid sites. Moreover, Nb doping can successfully inhibit the over-reduction of active W species during glycerol hydrogenolysis and substantially broaden the optimal H₂ pressure from 1 to 5 MPa. When Nb doping is 2%, supported Pt catalysts showed promising performance for the selective hydrogenolysis of glycerol to 1,3-PD over an unprecedentedly wide H₂ pressure range, which will guarantee better catalyst stability in the long run, as well as expand their applications to other hydrogen-related reactions.

Key words: Nb-doped WO_x, Glycerol, 1,3-propanediol, Selective hydrogenolysis

Man Yang, Xiaochen Zhao, Yujing Ren, Jia Wang, Nian Lei, Aiqin Wang, Tao Zhang. Pt/Nb-WO_x for the chemoselective hydrogenolysis of glycerol to 1,3-propanediol: Nb dopant pacifying the over-reduction of WO_x supports[J]. Chinese Journal of Catalysis, 2018, 39(6): 1027-1037.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(18)63074-8

https://www.cjcatal.com/EN/Y2018/V39/I6/1027

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Pt/Nb-WO_x for the chemoselective hydrogenolysis of glycerol to 1,3-propanediol: Nb dopant pacifying the over-reduction of WO_x supports

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