Carbon-supported ruthenium catalysts prepared by a coordination strategy for acetylene hydrochlorination

doi:10.1016/S1872-2067(20)63616-6

Abstract

Abstract: The development of efficient and stable non-mercury catalysts for the chlor-alkali industry is desirable but remains a great challenge. Herein, we design a series of ruthenium catalysts for acetylene hydrochlorination by regulating the electronic structure of ruthenium ions through coordination with various ligands (thiourea, phenanthroline, and L-lactic). The turnover frequencies (TOFs) and apparent activation energies for the acetylene hydrochlorination have a linear relationship with the binding energy of Ru³⁺ in the ruthenium catalysts. The synergetic effect of the ruthenium ion and ligands plays an important role in acetylene hydrochlorination. The Ru-Thi/AC catalyst with thiourea as the ligand shows the highest TOF and stability in acetylene hydrochlorination. The present study provides a rational method to regulate the electronic structure of supported metal catalysts with high catalytic performance exhibited by the carbon-supported heterogeneous catalysts.

Key words: Ruthenium catalyst, Ligand, Electronic structure, Synergetic effect, Acetylene hydrochlorination

Xiaolong Wang, Guojun Lan, Zaizhe Cheng, Wenfeng Han, Haodong Tang, Huazhang Liu, Ying Li. Carbon-supported ruthenium catalysts prepared by a coordination strategy for acetylene hydrochlorination[J]. Chinese Journal of Catalysis, 2020, 41(11): 1683-1691.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(20)63616-6

https://www.cjcatal.com/EN/Y2020/V41/I11/1683

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