金属卤化物促进糖类催化转化制备5-羟甲基糠醛

doi:10.1016/S1872-2067(14)60012-7

催化学报 ›› 2014, Vol. 35 ›› Issue (4): 496-500.DOI: 10.1016/S1872-2067(14)60012-7

金属卤化物促进糖类催化转化制备5-羟甲基糠醛

任秋鹤^a,b, 黄义争^a, 马红^a, 高进^a, 徐杰^a

a 中国科学院大连化学物理研究所催化基础国家重点实验室, 洁净能源国家实验室, 辽宁大连116023;
b 中国科学院大学, 北京100049

收稿日期:2013-11-24 修回日期:2013-12-25 出版日期:2014-03-20 发布日期:2014-03-21
通讯作者: 徐杰
基金资助:
中国科学院知识创新工程重要方向项目（KSCX2-EW-G-5）；中国科学院战略性先导科技专项-应对气候变化的碳收支认证及相关问题（XDA05010203）；国家自然科学基金（21233008）.

Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides

Qiuhe Ren^a,b, Yizheng Huang^a, Hong Ma^a, Jin Gao^a, Jie Xu^a

a Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received:2013-11-24 Revised:2013-12-25 Online:2014-03-20 Published:2014-03-21
Supported by:
This work was supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (KSCX2-E-G-5), the “Strategic Priority Research Program-Climate Change: Carbon Budget and Related Issues” of the Chinese Academy of Sciences (XDA05010203), and the National Natural Science Foundation of China (21233008).

摘要/Abstract

摘要：

研究了碱金属卤化物对AlCl₃催化葡萄糖转化制备5-羟甲基糠醛（HMF）的促进作用. 结果表明，NaF对反应有显著抑制作用，而NaI和NaBr对反应有显著促进作用，而且NaI比NaBr的促进效果更明显. 在N，N-二甲基乙酰胺（DMAC）中，以NaI为添加剂，130 ℃反应15 min，AlCl₃催化葡萄糖转化制备HMF，葡萄糖转化率由71%提高到86%，HMF收率由36%提高到62%. AlCl₃-NaI-DMAC体系也可用于果糖、甘露糖等单糖，蔗糖、麦芽糖、纤维二糖等二糖，以及菊粉等多糖的转化. 以蔗糖为原料，HMF收率可达63%.

关键词: 糖类化合物, 5-羟甲基糠醛, 金属卤化物, 催化

Abstract:

The promotion effect of alkali metal halides toward the AlCl₃-catalyzed conversion of glucose to 5-hydroxymethylfurfural (HMF) was investigated. The results show that NaF inhibited the reaction. However, NaI and NaBr promoted the reaction significantly, and the promotion effect of NaI was more obvious than that of NaBr. In N,N-dimethylacetamide (DMAC), when NaI was used as an additive for the AlCl₃-catalyzed conversion of glucose at 130 ℃ for 15 min, glucose conversion increased from 71% to 86%, and the HMF yield increased from 36% to 62%. The AlCl₃-NaI-DMAC system could also be used for the catalytic conversion of other carbohydrates such as fructose, mannose, sucrose, maltose, cellobiose, and inulin to HMF. When sucrose was used as the feedstock, a 63% HMF yield was achieved.

Key words: Carbohydrate, 5-Hydroxymethylfurfural, Metal halide, Catalysis

任秋鹤, 黄义争, 马红, 高进, 徐杰. 金属卤化物促进糖类催化转化制备5-羟甲基糠醛[J]. 催化学报, 2014, 35(4): 496-500.

Qiuhe Ren, Yizheng Huang, Hong Ma, Jin Gao, Jie Xu. Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides[J]. Chinese Journal of Catalysis, 2014, 35(4): 496-500.

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金属卤化物促进糖类催化转化制备5-羟甲基糠醛

Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides

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