沉积于含硼金属有机框架的Pt(II)通过抑制分解来增强光催化H2O2的产生

doi:10.1016/S1872-2067(22)64163-9

催化学报 ›› 2023, Vol. 45: 132-140.DOI: 10.1016/S1872-2067(22)64163-9

沉积于含硼金属有机框架的Pt(II)通过抑制分解来增强光催化H₂O₂的产生

李昱杰, 刘媛媛(), 王泽岩, 王朋, 郑昭科, 程合锋, 戴瑛, 黄柏标()

山东大学晶体材料国家重点实验室, 山东济南250100

收稿日期:2022-07-08 接受日期:2022-08-01 出版日期:2023-02-18 发布日期:2023-01-10
通讯作者: 刘媛媛,黄柏标
基金资助:
国家重点研发计划(2020YFA0710301);国家自然科学基金(22172088);国家自然科学基金(51972195);国家自然科学基金(21832005);国家自然科学基金(21972078);国家自然科学基金(11374190);山东省自然科学基金(ZR2020YQ16);山东大学青年学者计划(2020QNQT012)

Enhanced photocatalytic H2O2 production over Pt(II) deposited boron containing metal-organic framework via suppressing the simultaneous decomposition

Yujie Li, Yuanyuan Liu(), Zeyan Wang, Peng Wang, Zhaoke Zheng, Hefeng Cheng, Ying Dai, Baibiao Huang()

State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong, China

Received:2022-07-08 Accepted:2022-08-01 Online:2023-02-18 Published:2023-01-10
Contact: Yuanyuan Liu, Baibiao Huang
Supported by:
National Key Research and Development Program of China(2020YFA0710301);National Natural Science Foundation of China(22172088);National Natural Science Foundation of China(51972195);National Natural Science Foundation of China(21832005);National Natural Science Foundation of China(21972078);National Natural Science Foundation of China(11374190);Shandong Province Natural Science Foundation(ZR2020YQ16);Young Scholars Program of Shandong University(2020QNQT012)

摘要/Abstract

摘要：

H₂O₂作为一种重要的化工资源越来越受到关注, 它不仅是环境友好的氧化剂, 而且是很有应用前景的新型液体燃料. 目前生产H₂O₂主要采用蒽醌法, 该方法存在能耗高、副产物有毒等缺点. 光催化合成H₂O₂因对环境友好而受到广泛关注, 该合成反应中同时发生H₂O₂的生成和分解. 目前光催化合成H₂O₂相关研究主要集中在H₂O₂的生成, 而有关H₂O₂分解的研究较少. 研究发现Pt作为助催化剂在提高光催化活性方面发挥着重要作用, 但Pt价态对光催化活性的影响, 特别是对H₂O₂的生成和分解的影响, 尚未进行详细研究.
本文将不同价态的Pt沉积在含硼金属有机骨架(UiO-67-B)上, 详细研究了Pt(0), Pt(II)和Pt(IV)在光催化产H₂O₂过程中的作用. 粉末X射线衍射(XRD)、X射线光电子能谱(XPS)和傅里叶转换红外光谱(FT-IR)等表征结果证明了UiO-67-B/Pt(0), UiO-67-B/Pt(II)和UiO-67-B/Pt(IV)样品的成功制备. 此外, UiO-67-B/Pt(II)的高分辨Cl 2p XPS光谱中出现了Cl-HO(Zr)峰, 而且FT-IR谱中出现Cl-H键表明, [PtCl₄]^2-中的Cl与UiO-67-B中Zr-OH处的H进行了络合. 密度泛函理论计算结果表明, UiO-67-B/Pt(II)上Cl与H之间存在弱吸附, 进一步证明了上述结论. 光催化反应结果表明, 样品中 UiO-67-B/Pt(II) 催化生成H₂O₂产率最高, 达到8275 μmol L^-1 h^-1. H₂O₂生成和分解速率常数拟合结果表明, Pt(II)的存在不仅促进H₂O₂的生成, 而且抑制了光催化过程中H₂O₂的分解. 光催化H₂O₂分解实验进一步证明了Pt(II)对H₂O₂分解的抑制作用. O₂程序升温脱附和高角度环形暗场扫描透射电子显微镜结果表明, UiO-67-B/Pt(II)具有最大的O₂吸附量, 且Pt(II)以单原子形式存在, 这为O₂的吸附提供了更多的吸附位点.
光致发光光谱、荧光寿命、光电流响应和阻抗图谱结果均表明, UiO-67-B/Pt(II)拥有更高的载流子转移和分离能力, 说明Pt(II)与UiO-67-B的相互作用建立了一个电子传输通道, 有效促进了UiO-67-B/Pt(II)的电荷传输和分离. 电子空间分布图也进一步证明了该结论. 此外, 进一步计算了反应过程中每一步所需的热力学自由能, 包括O₂吸附、中间体质子化过程和H₂O₂解吸过程. 结果表明, Pt(II)的引入更有利于O₂的吸附和•O₂^-质子化, 且Pt(II)的存在有利于H₂O₂的解吸. 综上, 本工作系统地研究了铂价态对H₂O₂生成的影响, 为设计具有良好的H₂O₂产生效率的光催化剂提供了一种新策略.

关键词: 硼掺杂, H₂O₂分解, H₂O₂生成, 金属有机框架, 铂价态, 光催化

Abstract:

Photocatalytic H₂O₂ evolution has received extensive attention as an environmentally friendly method, which is a dynamic process of formation and decomposition. At present, researches mainly focus on the H₂O₂ formation, while the decomposition of H₂O₂ is rarely studied. In addition, platinum as a cocatalyst plays an important role in enhancing the photocatalytic activity, but the effects of platinum valence state on the activity, especially towards H₂O₂ formation and decomposition, has not been studied in detail to the best of our knowledge. In this work, platinum with different valence state were deposited onto boron containing metal organic frameworks (UiO-67-B), and the roles of Pt(0), Pt(II) and Pt(IV) in the photocatalytic H₂O₂ process were explored in detail. Both the experimental results and theoretical calculations indicate that the presence of Pt(II) plays an important role not only in promoting the H₂O₂ formation but also in inhibiting the H₂O₂ decomposition.

Key words: Boron doping, H₂O₂ decomposition, H₂O₂ production, Metal-organic frameworks, Platinum valence state, Photocatalysis

李昱杰, 刘媛媛, 王泽岩, 王朋, 郑昭科, 程合锋, 戴瑛, 黄柏标. 沉积于含硼金属有机框架的Pt(II)通过抑制分解来增强光催化H₂O₂的产生[J]. 催化学报, 2023, 45: 132-140.

Yujie Li, Yuanyuan Liu, Zeyan Wang, Peng Wang, Zhaoke Zheng, Hefeng Cheng, Ying Dai, Baibiao Huang. Enhanced photocatalytic H2O2 production over Pt(II) deposited boron containing metal-organic framework via suppressing the simultaneous decomposition[J]. Chinese Journal of Catalysis, 2023, 45: 132-140.

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图/表 6

Fig. 1. (a) XRD patterns of UiO-67-B, UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV). High-resolution XPS spectra of Pt 4f (b) and Cl 2p (c) for UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV). (d) The optimized structure model for UiO-67-B/Pt(II). (e) FTIR spectra for UiO-67-B and UiO-67-B/Pt(II).

Fig. 2. (a) Time course of H2O2 production over UiO-67-B, UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV). (b) Comparison of H2O2 production over UiO-67-B/Pt(II) and other photocatalysts reported in recent studies. (c) Time course of H2O2 production over UiO-67-B/Pt(II) with different platinum contents (x% is the mass ratio of platinum to UiO-67-B). Reaction conditions for H2O2 production: 0.3 g L-1 catalyst, 90 mL water + 10 mL isopropanol, simulated sunlight.

Fig. 3. N2 adsorption-desorption isotherms (a) and TPD curves (b) of O2 for UiO-67-B, UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV). HAADF-STEM images of UiO-67-B/Pt(II) (c) and UiO-67-B/Pt(0) (d). (e) The formation (Kf, blue histogram) and decomposition rate constant (Kd, cyan histogram) for H2O2 over UiO-67-B, UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV). (f) The photocatalytic decomposition of H2O2 (C0 = 1 mmol L-1) over UiO-67-B, UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV).

Fig. 4. (a) Time-resolved PL decay spectra for UiO-67-B, UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV). (b) ESR signals of DMPO-?O2- over UiO-67-B, UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV) under simulated sunlight irradiation. Transient photocurrent response (c) and EIS plots (d) for UiO-67-B, UiO-67-B/Pt(0), UiO-67-B/Pt(II) and UiO-67-B/Pt(IV).

Fig. 5. (a) Electronic spatial distribution of UiO-67-B/Pt(II) at CBM and VBM. (b) The optimized models and adsorption energy of O2 molecules over UiO-67-B and UiO-67-B/Pt(II). (c) Free energy diagrams for H2O2 generation on UiO-67-B and UiO-67-B/Pt(II).

Fig. 6. Plausible mechanism of H2O2 formation and decomposition over UiO-67-B (a) and UiO-67-B/Pt(II) (b).

参考文献

[1]	P. Zhang, Y. Tong, Y. Liu, J. J. M. Vequizo, H. Sun, C. Yang, A. Yamakata, F. Fan, W. Lin, X. Wang, W. Choi, Angew. Chem. Int. Ed., 2020, 59, 16209-196217.
[2]	Y. Yamada, M. Yoneda, S. Fukuzumi, Energy Environ. Sci., 2015, 8, 1698-1701.
[3]	Y. Shiraishi, S. Kanazawa, Y. Kofuji, H. Sakamoto, S. Ichikawa, S. Tanaka, T. Hirai, Angew. Chem. Int. Ed., 2014, 53, 13454-13459.
[4]	C. Feng, L. Tang, Y. Deng, J. Wang, J. Luo, Y. Liu, X. Ouyang, H. Yang, J. Yu, J. Wang,, Adv. Funct. Mater., 2020, 30, 2001922.
[5]	S. Kim, G. Moon, H. Kim, Y. Mun, P. Zhang, J. Lee, W. Choi, J. Catal., 2018, 357, 51-58.
[6]	Y. Shiraishi, S. Kanazawa, Y. Sugano, D. Tsukamoto, H. Sakamoto, S. Ichikawa, T. Hirai, ACS Catal., 2014, 4, 774-780.
[7]	F. Sandelin, P. Oinas, T. Salmi, J. Paloniemi, H. Haario, Ind. Eng. Chem. Res., 2006, 45, 986-992.
[8]	T. Hirakawa, Y. Nosaka, J. Phys. Chem. C, 2008, 112, 15818-15823.
[9]	H. Goto, Y. Hanada, T. Ohno, M. Matsumura, J. Catal., 2004, 225, 223-229.
[10]	L. Zheng, H. Su, J. Zhang, L. S. Walekar, H. V. Molamahmood, B. Zhou, M. Long, Y. H. Hu, Appl. Catal. B, 2018, 239, 475-484.
[11]	G. Moon, W. Kim, A. D. Bokare, N. Sung, W. Choi, Energy Environ. Sci., 2014, 7, 4023-4028.
[12]	D. Friedmann, C. Mendive, D. W. Bahnemann, Appl. Catal. B, 2010, 99, 398-406.
[13]	H. Song, L. Wei, C. Chen, C. Wen, F. Han, J. Catal, 2019, 376, 198-208.
[14]	X. Xiong, X. Zhang, S. Liu, J. Zhao, Y. Xu, Photochem. Photobiol. Sci., 2018, 17, 1018-1022.
[15]	X. Qu, S. Hu, P. Li, Z. Li, H. Wang, H. Ma, W. Li, Diam. Relat. Mater., 2018, 86, 159-166.
[16]	L. Shi, L. Yang, W. Zhou, Y. Liu, L. Yin, X. Hai, H. Song, J. Ye, Small, 2018, 14, 1703142.
[17]	H. Wang, Y. Guan, S. Hu, Y. Pei, W. Ma, Z. Fan, Nano, 2019, 14, 1950023.
[18]	S. Hu, X. Qu, P. Li, F. Wang, Q. Li, L. Song, Y. Zhao, X. Kang, Chem. Eng. J., 2018, 334, 410-418.
[19]	Y. Yang, Z. Zeng, G. Zeng, D. Huang, R. Xiao, C. Zhang, C. Zhou, W. Xiong, W. Wang, M. Cheng, W. Xue, H. Guo, X. Tang, D. He, Appl. Catal. B, 2019, 258, 117956.
[20]	X. Zeng, Z. Wang, G. Wang, T. R. Gengenbach, D. T. McCarthy, A. Deletic, J. Yu, X. Zhang, Appl. Catal. B, 2017, 218, 163-173.
[21]	Z. M. Zhang, T. Zhang, C. Wang, Z. Lin, L. S. Long, W. Lin, J. Am. Chem. Soc., 2015, 137, 3197-3200.
[22]	T. C. Zhuo, Y. Song, G. L. Zhuang, L. P. Chang, S. Yao, W. Zhang, Y. Wang, P. Wang, W. Lin, T. B. Lu, Z. M. Zhang, J. Am. Chem. Soc., 2021, 143, 6114-6122.
[23]	S. Fu, S. Yao, S. Guo, G. C. Guo, W. Yuan, T. B. Lu, Z. M. Zhang, J. Am. Chem. Soc., 2021, 143, 20792.
[24]	S. S. Fu, X. Y. Ren, S. Guo, G. Lan, Z. M. Zhang, T. B. Lu, W. Lin, iScience, 2020, 23, 100793.
[25]	R. Gao, J. Wang, Z. F. Huang, R. Zhang, W. Wang, L. Pan, J. Zhang, W. Zhu, X. Zhang, C. Shi, J. Lim, J. J. Zou, Nat. Energy, 2021, 6, 614-623.
[26]	R. Shen, W. Chen, Q. Peng, S. Lu, L. Zheng, X. Cao, Y. Wang, W. Zhu, J. Zhang, Z. Zhuang, C. Chen, D. Wang, Y. Li, Chem, 2019, 5, 2099-2110.
[27]	I. Katsounaros, W. B. Schneider, J. C. Meier, U. Benedikt, P. U. Biedermann, A. A. Auer, K. J. J. Mayrhofer, Phys. Chem. Chem. Phys., 2012, 14, 7384-7391.
[28]	Y. Kon, H. Yazawa, Y. Usui, K. Sato, Chem. Asian J., 2008, 3, 1642-1648.
[29]	Y. Li, F. Ma, L. Zheng, Y. Liu, Z. Wang, P. Wang, Z. Zheng, H. Cheng, Y. Dai, B. Huang, Mater. Horiz., 2021, 8, 2842-2850.
[30]	Y. Li, G. Zhai, Y. Liu, Z. Wang, P. Wang, Z. Zheng, H. Cheng, Y. Dai, B. Huang, Chem. Eng. J., 2022, 437, 135363.
[31]	C. Ke, M. Li, G. Fan, L. Yang, F. Li, Chem. Asian J., 2018, 13, 2714-2722.
[32]	O. Kerrec, D. Devilliers, H. Groult, P. Marcus, Mater. Sci. Eng. B, 1998, 55, 134-142.
[33]	A. Romanchenko, M. Likhatski, Y. Mikhlin, Minerals, 2018, 8, 578.
[34]	Y. Cao, K. Z. Guo, R. Y. Qian, Acta Chim. Sin., 1985, 3, 425-432.
[35]	P. Asselin, P. Soulard, M. E. Alikhani, J. P. Perchard, Chem. Phys., 1999, 249, 73-87.
[36]	Y. Shiraishi, T. Takii, T. Hagi, S. Mori, Y. Kofuji, Y. Kitagawa, S. Tanaka, S. Ichikawa, T. Hirai, Nat. Mater., 2019, 18, 985-993.
[37]	Y. C. Hsieh, L. C. Chang, P. W. Wu, Y. M. Chang, J. F. Lee, Appl. Catal. B, 2011, 103, 116-127.
[38]	H. M. Yasin, G. Denuault, D. Pletcher, J. Electroanal. Chem., 2009, 633, 327-332.
[39]	X. Li, W. Bi, L. Zhang, S. Tao, W. Chu, Q. Zhang, Y. Luo, C. Wu, Y. Xie, Adv. Mater., 2016, 28, 2427-2431.
[40]	F. Li, G. F. Han, H. J. Noh, S. J. Kim, Y. Lu, H. Y. Jeong, Z. Fu, J. B. Baek, Energy Environ. Sci., 2018, 11, 2263-2269.
[41]	Y. He, Y. Li, J. Zhang, S. Wang, D. Huang, G. Yang, X. Yi, H. Lin, X. Han, W. Hu, Y. Deng, J. Ye, Nano Energy, 2020, 77, 105010.
[42]	H. Q. Zheng, Y. N. Zeng, J. Chen, R. G. Lin, W. E Zhuang, R. Cao, Z. J. Lin, Inorg. Chem., 2019, 58, 6983-6992

沉积于含硼金属有机框架的Pt(II)通过抑制分解来增强光催化H₂O₂的产生

Enhanced photocatalytic H2O2 production over Pt(II) deposited boron containing metal-organic framework via suppressing the simultaneous decomposition

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