基于Ni单原子/P,N掺杂非晶态NiFe2O4作为阳极和Ag@CuO/Cu2O纳米立方体作为阴极组成的高效光电化学系统用于微塑料氧化和二氧化碳还原

doi:10.1016/S1872-2067(25)64777-2

催化学报 ›› 2025, Vol. 76: 159-172.DOI: 10.1016/S1872-2067(25)64777-2

基于Ni单原子/P,N掺杂非晶态NiFe₂O₄作为阳极和Ag@CuO/Cu₂O纳米立方体作为阴极组成的高效光电化学系统用于微塑料氧化和二氧化碳还原

朱鸿睿^a^,¹, 王希伦^b^,¹, 赵娟涓^a, 尹梦晗^a, 徐慧民^a, 李高仁^a^,^*()

^a四川大学材料科学与工程学院, 四川成都 610065
^b中山大学化学学院, 广东广州 510275

收稿日期:2025-03-16 接受日期:2025-05-20 出版日期:2025-09-18 发布日期:2025-09-10
通讯作者: 李高仁
作者简介:第一联系人：
¹共同第一作者.
基金资助:
国家自然科学基金(52373215);四川省自然科学基金(2023NSFSC0086);高校基本业务费(YJ2021156)

Efficient photoelectrochemical cell composed of Ni single atoms/P, N-doped amorphous NiFe₂O₄ as anode catalyst and Ag NPs@CuO/Cu₂O nanocubes as cathode catalyst for microplastic oxidation and CO₂ reduction

Hong-Rui Zhu^a^,¹, Xi-Lun Wang^b^,¹, Juan-Juan Zhao^a, Meng-Han Yin^a, Hui-Min Xu^a, Gao-Ren Li^a^,^*()

^aCollege of Materials Science and Engineering, Sichuan University, Chengdu 610065, Sichuan, China
^bSchool of Chemistry, Sun Yat-sen University, Guangzhou 510275, Guangdong, China

Received:2025-03-16 Accepted:2025-05-20 Online:2025-09-18 Published:2025-09-10
Contact: Gao-Ren Li
About author:First author contact:
¹Contributed to this work equally.
Supported by:
the National Natural Science Foundation of China(52373215);the Sichuan Science and Technology Program(2023NSFSC0086);the Fundamental Research Funds for the Central Universities(YJ2021156)

摘要/Abstract

摘要：

塑料在人类生活中无处不在, 废弃的塑料已对环境和人体造成严重危害. 大气中二氧化碳(CO₂)的含量增加将导致温室效应. 因此, 利用环保高效的技术来处理微塑料垃圾和排放的CO₂迫在眉睫. 光电催化具有反应条件温和、环境友好等优势, 在塑料微垃圾资源化处理和CO₂再利用方面展现出巨大潜力. 聚对苯二甲酸乙二醇酯(PET)是一种典型的聚酯塑料, 易水解成单体有机物. 最近, 有报道称PET水解产物, 包括对苯二甲酸(TA)、乙二醇(EG)和邻苯二甲酸酯等, 可以通过光催化或电催化技术转化为甲酸酯或其他高价值产品.

在已报道的催化剂中, Ni单原子催化剂因其优异的催化活性和较高的反应效率, 非常适于PET降解. 此外, 尖晶石(AB₂O₄)材料具有催化活性高、生产成本低、易合成等优点. 目前, 大多数非贵金属(如Fe, Co, Ni, Cu, Zn等)的单原子以M-N₄或M-N-C键的形式存在. 由于尖晶石材料表面缺乏C或N位点, 在尖晶石材料上合成单原子尤为困难. 本研究通过P和N共掺杂替代NiFe₂O₄ (NFO)结构中Ni位点周围的O原子, 使NiO₄位点变成Ni-N₃-P位点, 成功合成了Ni单原子. 同时, 该过程会对NFO造成严重的晶格畸变, 并导致非晶结构的形成, 从而明显提升了催化性能.

本文开发了一种高效的光电催化系统, 该系统由P,N掺杂负载的Ni单原子(Ni SAs)的非晶态NiFe₂O₄ (Ni SAs/A-P-N-NFO)作为阳极, 由CuO/Cu₂O纳米立方体负载的Ag纳米粒子(Ag NPs) (Ag NPs@CuO/Cu₂O NCs)作为阴极, 并将该光电催化系统用于微塑料氧化和二氧化碳还原. 采用煅烧-H₂还原法合成的Ni SAs/A-P-N-NFO阳极在AM 1.5 G光下对PET溶液的氧化反应法拉第效率可达到93%. Ag NPs@CuO/Cu₂O NCs作为光电阴极在1.5 V vs. RHE下将CO₂还原成乙烯和CO, 选择性分别为42%和55%. 结果表明, 光电催化是一种环境友好型技术, 它能很好地降解PET微塑料以及高效还原二氧化碳. 通过控制温度和光照作为对比实验, 证明了在Ni SAs/A-P-N-NFO表面的光照会产生光热效应, 使得反应由光、电、热三种效应同时作用, 明显提高了目标产物的转化率. 通过原位红外和原位拉曼证明了反应过程中的中间体演变. 最后, 通过理论计算解释了可能的反应机理和反应路径, 加深了对反应过程的理解.

综上, 本文展示了一种通过光电催化技术将PET微塑料转化为高价值化学品的策略, 并证明了该策略的可行性和经济价值. PEC系统的催化剂由地球上储量高的元素所制备, 生产成本较低. 本工作为降解微塑料提供了灵感和可行策略, 也为设计低成本的二氧化碳还原催化剂提供了创新思路.

关键词: Ni单原子, NiFe₂O₄, 光电催化, 聚对苯二甲酸乙二醇酯塑料氧化, CO₂还原反应

Abstract:

Plastics are ubiquitous in human life and pose certain hazards to the environment and human body. The increasing amount of CO2 in the atmosphere will lead to the greenhouse effect. Therefore, it is urgent to treat microplastic waste and CO2 by using environmentally friendly and efficient technologies. In this work, we developed an efficient photoelectrocatalytic system composed of Ni single atoms (Ni SAs) supported by P, N-doped amorphous NiFe2O4 (Ni SAs/A-P-N-NFO) as anode and Ag nanoparticles (Ag NPs) supported by CuO/Cu2O nanocubes (Ag NPs@CuO/Cu2O NCs) as cathode for microplastic oxidation and CO2 reduction. The Ni SAs/A-P-N-NFO was synthesized by calcination-H2 reduction method, and it achieved a Faraday efficiency of 93% for the oxidation reaction of poly (ethylene terephthalate) (PET) solution under AM 1.5 G light. As a photocathode, the synthesized Ag NPs@CuO/Cu2O NCs was utilized to reduce CO2 to ethylene and CO at 1.5 V vs. RHE with selectivity of 42% and 55%, respectively. This work shows that the photoelectrocatalysis, as an environmentally friendly technology, is a feasible strategy for reducing the environmental and biological hazards of light plastics, as well as for efficient CO2 reduction.

Key words: Ni single atom, NiFe2O4, Photoelectrocatalysis, Poly (ethylene terephthalate) plastics, oxidation, CO2 reduction reaction

朱鸿睿, 王希伦, 赵娟涓, 尹梦晗, 徐慧民, 李高仁. 基于Ni单原子/P,N掺杂非晶态NiFe₂O₄作为阳极和Ag@CuO/Cu₂O纳米立方体作为阴极组成的高效光电化学系统用于微塑料氧化和二氧化碳还原[J]. 催化学报, 2025, 76: 159-172.

Hong-Rui Zhu, Xi-Lun Wang, Juan-Juan Zhao, Meng-Han Yin, Hui-Min Xu, Gao-Ren Li. Efficient photoelectrochemical cell composed of Ni single atoms/P, N-doped amorphous NiFe₂O₄ as anode catalyst and Ag NPs@CuO/Cu₂O nanocubes as cathode catalyst for microplastic oxidation and CO₂ reduction[J]. Chinese Journal of Catalysis, 2025, 76: 159-172.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(25)64777-2

https://www.cjcatal.com/CN/Y2025/V76/I9/159

图/表 8

Fig. 1. Schematic illustration of synthesis procedures of Ni SAs/A-P-N-NFO.

Fig. 2. TEM images (a) and AC-HAADF-STEM images (b) of Ni SAs/A-P-N-NFO. (c) Statistical analysis of Ni single-atoms in Ni SAs/A-P-N-NFO. (d) Magnified images from (b). (c,d) show the intensity profile marked by the yellow dashed circle, indicating the isolated arrangement of Ni atoms. XRD patterns (e) and EPR spectra (f) of Ni SAs/A-P-N-NFO, P-NFO and C-NFO. XANES spectra of the Ni-K edge (g), Ni-K edge EXAFS spectra (h), and the wavelet-transformed EXAFS spectra (i) of Ni SAs/A-P-N-NFO and P-NFO.

Fig. 3. Performance of Ni SAs/A-P-N-NFO electrode toward PET hydrolysate oxidation at the photoanode under dark conditions. (a) LSV curves of with different P contents of NFO samples and Ni SAs/A-P-N-NFO in 1 mol L-1 KOH solutions with 0.1 mol L-1 PET hydrolysate. (b) Tafel slopes from LSV curves. (c) Faradaic efficiency on Ni SAs/A-P-N-NFO at different potentials. Error bars correspond to the standard deviation of measurements. (d) EIS spectra of different samples. (e) LSV curves of different reaction conditions of Ni SAs/A-P-N-NFO. (f) 1H NMR spectra of products before and after electrolysis of PET hydrolysate, applied bias is 1.5V vs. RHE.

Fig. 4. UV-vis DRS (a), Tauc’s plots (b), and PL spectra (c) of Ni SAs/A-P0.09-N-NFO, P-NFO and C-NFO. ESR spectra of DMPO-·OH (d) and DMPO-·O2-(e) for Ni SAs/A-P0.09-N-NFO under AM 1.5G light irradiation. (f) LSV curves under dark and light reaction conditions of Ni SAs/A-P0.09-N-NFO. IR thermal images of Ni SAs/A-P0.09-N-NFO (g1-g4) and P-NFO (h1-h4) under 480 nm illumination with time keeping from 30 to 120 s, the intervals are 30 s.

Fig. 5. (a) ELF profile of (001) facet of Ni SAs/A-P-N-NFO, P-NFO and C-NFO (the color bar represents the degree of electronic localization). (b,c) The phonon density of state (PDOS) of Ni SAs/A-P-N-NFO, P-NFO and C-NFO for the active Ni and Fe sites, respectively. (d) Gibbs free energy diagrams for the electrooxidation of EG to formate on Ni SAs/A-P-N-NFO, P-NFO and C-NFO (0 V vs. RHE).

Fig. 6. (a) Schematic illustration of the Cu2O and Ag NPs@CuO/Cu2O NCs preparation process. SEM, TEM and HRTEM images of Cu2O (b-d) and Ag NPs@CuO/Cu2O NCs (e-f). (g) Atomic-resolution HAADF-STEM image of Ag NPs@CuO/Cu2O NCs. (h) STEM image and EDX mappings of Ag NPs@CuO/Cu2O.

Fig. 7. Photoelectrochemical performance of the Ag NPs@CuO/Cu2O NCs toward the CO2RR at the photocathode. (a) FEs of the Ag NPs@CuO/Cu2O NCs photocathode for the CO2RR at different potentials. (b) LSV curves of the Ag NPs@CuO/Cu2O NCs photocathode in CO2-saturated 1 mol L-1 NaHCO3 solutions. (c) The stability test for CO2RR over Ag NPs@CuO/Cu2O NCs photocathode. (d) Comparison of CO2RR product selectivity of dark and light conditions. (e) The free-energy diagram for the PEC CO2RR to C2H4 on Ag NPs@CuO/Cu2O NCs and Cu2O.

Fig. 8. (a) Digital photographs of Ni SAs/A-P-N-NFO||Ag NPs@CuO/Cu2O NCs PEC cells under AM 1.5G illumination imposed in the laboratory. Photoanode on the left is in PET hydrolysis solution and photocathode on the right is in NaHCO3 solution. (b) LSV curve of Ni SAs/A-P-N-NFO||Ag NPs@CuO/Cu2O NCs PEC cells under AM 1.5G illumination. (c) FEs of the products of CO2RR of the Ni SAs/A-P-N-NFO||Ag NPs@CuO/Cu2O NCs PEC cells under AM 1.5G illumination.

参考文献

[1]	R. Geyer, J. R. Jambeck, K. L. Law, Sci. Adv., 2017, 3, e1700782.
[2]	S. Oh, E. E. Stache, Chem. Soc. Rev., 2024, 53, 7309-7327.
[3]	A. Robles-Martín, R. Amigot-Sánchez, L. Fernandez-Lopez, J. L. Gonzalez-Alfonso, S. Roda, V. Alcolea-Rodriguez, D. Heras-Márquez, D. Almendral, C. Coscolín, F. J. Plou, R. Portela, M. A. Bañares, Á. Martínez-del-Pozo, S. García-Linares, M. Ferrer, V. Guallar, Nat. Catal., 2023, 6, 1174-1185.
[4]	T. Uekert, M. F. Kuehnel, D. W. Wakerley, E. Reisner, Energy Environ. Sci., 2018, 11, 2853-2857.
[5]	Y. Chen, B. Liu, X. Liu, J. Ye, K. Deng, C. Wu, Q. Niu, T. Yang, W. Tian, J. Ji, Green Chem., 2024, 26, 12043-12052.
[6]	X. Zhang, T. Chen, N. Lu, F. Jian, B. Zhu, Y. Zhang, L. He, H. Tang, J. Mater. Chem. A, 2024, 12, 2036-2043.
[7]	T. Shuai, Q. Zhan, H. Xu, Z. Zhang, G. Li, Green Chem., 2023, 25, 1749-1789.
[8]	J. Zhao, K. Yue, H. Zhang, S. Wei, J. Zhu, D. Wang, J. Chen, V. Y. Fominski, G. Li, Nat. Commun., 2024, 15, 2928.
[9]	X. Lou, X. Gao, Y. Liu, M. Chu, C. Zhang, Y. Qiu, W. Yang, M. Cao, G. Wang, Q. Zhang, J. Chen, Chin. J. Catal., 2023, 49, 113-122.
[10]	J. Wang, F. Lin, J. Chen, M. Wang, X. Ge, J. Mater. Chem. B, 2015, 3, 9186-9193.
[11]	X. Lou, P. Yan, B. Jiao, Q. Li, P. Xu, L. Wang, L. Zhang, M. Cao, G. Wang, Z. Chen, Q. Zhang, J. Chen, Nat. Commun., 2024, 15, 2730.
[12]	J. Wang, X. Li, M. Wang, T. Zhang, X. Chai, J. Lu, T. Wang, Y. Zhao, D. Ma, ACS Catal., 2022, 12, 6722-6728.
[13]	F. Ma, Z. Li, R. Hu, Z. Wang, J. Wang, J. Li, Y. Nie, Z. Zheng, X. Jiang, ACS Catal., 2023, 13, 14163-14172.
[14]	F. Liu, X. Gao, R. Shi, Z. Guo, E. C. M. Tse, Y. Chen, Angew. Chem. Int. Ed., 2023, 62, e202300094
[15]	H. Zhou, Y. Ren, Z. Li, M. Xu, Y. Wang, R. Ge, X. Kong, L. Zheng, H. Duan, Nat. Commun., 2021, 12, 4679.
[16]	J. Wang, X. Li, T. Zhang, Y. Chen, T. Wang, Y. Zhao, J. Phys. Chem. Lett., 2022, 13, 622-627.
[17]	S. Zhang, W. Ruan, J. Guan, Adv. Energy Mater., 2025, 15, 2404057.
[18]	J. Zhang, K. Zhao, Y. Ma, W. Chen, X. Shi, C. Sun, Q. Zhang, J. Niu, Small Struct., 2024, 5, 2300323.
[19]	X. Xu and J. Guan, Adv. Funct. Mater., 2025, 35, 2505823.
[20]	M. Huang, B. Deng, X. Zhao, Z. Zhang, F. Li, K. Li, Z. Cui, L. Kong, J. Lu, F. Dong, L. Zhang, P. Chen, ACS Nano, 2022, 16, 2110-2119.
[21]	A. Husile, Z. Wang, J. Guan, Chem. Sci., 2025, 16, 5413-5446.
[22]	F. Ma, Y. Wen, P. Fu, J. Zhang, Q. Tang, T. Chen, W. Luo, Y. Zhou, J. Wang, Small, 2024, 20, 2305767.
[23]	A. Husile, Z. Wang, J. Guan, Coord. Chem. Rev., 2025, 533, 216546.
[24]	Y. Zhou, J. Li, X. Gao, W. Chu, G. Gao, L.-W. Wang, J. Mater. Chem. A, 2021, 9, 9979-9999.
[25]	H. Xie, F. Wang, T. Liu, Y. Wu, C. Lan, B. Chen, J. Zhou, B. Chen, Electrochim. Acta, 2021, 380, 138188.
[26]	H. Dong, H. Zhu, Q. Li, M. Zhou, X. Ren, T. Ma, J. Liu, Z. Zeng, X. Luo, S. Li, C. Cheng, Adv. Funct. Mater., 2023, 33, 2300294.
[27]	J. Gao, Q. Jiang, Y. Liu, W. Liu, W. Chu, D.-S. Su, Nanoscale, 2018, 10, 14207-14219.
[28]	L. Shi, J. Song, Y. Yang, L. Yang, Z. Dai, L. Yao, W. Jiang, J. Mater. Chem. A, 2025, 13, 2478-2504.
[29]	C. Liang, B. Kim, S. Yang, Y. Liu, C. Francisco Woellner, Z. Li, R. Vajtai, W. Yang, J. Wu, P. J. A. Kenis, P. M. Ajayan, J. Mater. Chem. A, 2018, 6, 10313-10319.
[30]	X. Lu, Y. Wu, X. Yuan, L. Huang, Z. Wu, J. Xuan, Y. Wang, H. Wang, ACS Energy Lett., 2018, 3, 2527-2532.
[31]	J. Li, P. Yan, K. Li, J. You, H. Wang, W. Cui, W. Cen, Y. Chu, F. Dong, J. Mater. Chem. A, 2019, 7, 17014-17021.
[32]	J. Ma, Q. Jiang, Y. Zhou, W. Chu, S. Perathoner, C. Jiang, K.-H. Wu, G. Centi, Y. Liu, Small, 2021, 17, 2007509.
[33]	Z. Chen, G. Ding, Z. Wang, Y. Xiao, X. Liu, L. Chen, C. Li, H. Huang, G. Liao, Adv. Funct. Mater., 2025, 35, 2423213.
[34]	P. Li, J. Liu, Y. Wang, X.-D. Zhang, Y. Hou, Y. Zhang, X. Sun, X. Kang, Q. Zhu, B. Han, J. Am. Chem. Soc., 2024, 146, 26525-26533.
[35]	X. Li, L. Li, X. Chu, X. Liu, G. Chen, Q. Guo, Z. Zhang, M. Wang, S. Wang, A. Tahn, Y. Sun, X. Feng, Nat. Commun., 2024, 15, 5639.
[36]	C. Yang, Y. Gao, T. Ma, M. Bai, C. He, X. Ren, X. Luo, C. Wu, S. Li, C. Cheng, Adv. Mater., 2023, 35, 2301836.
[37]	X. Xu, J. Guan, Mater. Sci. Eng. R Rep., 2025, 162, 100886.
[38]	S. Yang, R. Xiao, T. Hu, X. Fan, R. Xu, Z. Sun, B. Zhong, X. Guo, F. Li, Nano Energy, 2021, 90, 106584.
[39]	L. Qi, J. Guan, Sci. Bull., 2025, 70, 1856-1871.
[40]	S. Gao, A. Zavabeti, B. Wang, R. Ren, C. Yang, Z. Liu, Y. Wang, ACS Appl. Nano Mater., 2021, 4, 4542-4551.
[41]	B. Zhang, Y. Zhang, M. Hou, W. Wang, S. Hu, W. Cen, X. Cao, S. Qiao, B.-H. Han, J. Mater. Chem. A, 2021, 9, 10146-10159.
[42]	S. Li, Z. Zhao, T. Ma, P. Pachfule, A. Thomas, Angew. Chem. Int. Ed., 2022, 61, e202112298.
[43]	Y. Zhang, L. Hu, H. Zhou, H. Wang, Y. Zhang, ACS Appl. Nano Mater., 2022, 5, 391-400.
[44]	P. Zeng, B. Su, X. Wang, X. Li, C. Yuan, G. Liu, K. Dai, J. Mao, D. Chao, Q. Wang, L. Zhang, Adv. Funct. Mater., 2023, 33, 2301743.
[45]	H. Xu, K. Yue, L. Song, H. Zhang, H. Zhu, Z. Zhang, G. Li, Angew. Chem. Int. Ed., 2024, 63, e202412025.
[46]	T. Shuai, Q. Zhan, H. Xu, C. Huang, Z. Zhang, G. Li, Chem. Commun., 2023, 59, 3968-3999.
[47]	C. Huang, H. Xu, T. Shuai, Q. Zhan, Z. Zhang, G. Li, Small, 2023, 19, 2301130.
[48]	S. Zheng, H. Xu, H. Zhu, T. Shuai, Q. Zhan, C. Huang, G. Li, J. Mater. Chem. A, 2024, 12, 18832-18865.
[49]	H. Xu, H. Zhu, CJ. Huang, Z. Zhang, T. Shuai, Q. Zhan, G. Li, Sci. China Chem., 2024, 67, 1137-1160.
[50]	C. Huang, Q. Zhan, H. Xu, H. Zhu, T. Shuai, G. Li, Inorg. Chem., 2024, 63, 8925-8937.
[51]	H. Xu, H. Zhu, Z. Zhang, C. Huang, T. Shuai, Q. Zhan, G. Li, Inorg. Chem., 2024, 63, 3702-3711.
[52]	Q. Zhan, H. Zhang, C. Huang, H. Xu, T. Shuai, H. Zhu, G. Li, Small, 2025, 21, 2410723.
[53]	W. Wang, Q. Luo, L. Li, Y. Wang, X. Huo, S. Chen, X. Du, N. Wang, Adv. Funct. Mater., 2023, 33, 2302913.
[54]	K. Liu, X. Wang, S. Gu, H. Yuan, F. Jiang, Y. Li, W. Tan, Q. Long, J. Chen, Z. Xu, Z. Lu, Small, 2022, 18, 2204707.
[55]	T. Liu, A. Li, C. Wang, W. Zhou, S. Liu, L. Guo, Adv. Mater., 2018, 30, 1803590.
[56]	Y. Li, Z. Zhang, Z. Zhang, J. He, M. Xie, C. Li, H. Lu, Z. Shi, S. Feng, Appl. Catal. B, 2023, 339, 123141.
[57]	R. Chen, Z. Wang, S. Chen, W. Wu, Y. Zhu, J. Zhong, N. Cheng, ACS Energy Lett., 2023, 8, 3504-3511.
[58]	J. Ran, H. Zhang, S. Fu, M. Jaroniec, J. Shan, B. Xia, Y. Qu, J. Qu, S. Chen, L. Song, J. M. Cairney, L. Jing, S.-Z. Qiao, Nat. Commun., 2022, 13, 4600.
[59]	S. Mo, X. Zhao, S. Li, L. Huang, X. Zhao, Q. Ren, M. Zhang, R. Peng, Y. Zhang, X. Zhou, Y. Fan, Q. Xie, Y. Guo, D. Ye, Y. Chen, Angew. Chem. Int. Ed., 2023, 62, e202313868.
[60]	P. V. Shinde, P. Mane, B. Chakraborty, C. Sekhar Rout, J. Colloid Interface Sci., 2021, 602, 232-241.
[61]	J. Choi, D. Kim, W. Zheng, B. Yan, Y. Li, L. Y. S. Lee, Y. Piao, Appl. Catal. B, 2021, 286, 119857.
[62]	M. Karpuraranjith, Y. Chen, B. Wang, J. Ramkumar, D. Yang, K. Srinivas, W. Wang, W. Zhang, R. Manigandan, J. Colloid Interface Sci., 2021, 592, 385-396.
[63]	W. Ding, D. Ji, K. Wang, Y. Li, Q. Luo, R. Wang, L. Li, X. Qin, S. Peng, Angew. Chem. Int. Ed., 2025, 64, e202418640.
[64]	S. K. Kumar, R. D. Kaushik, L. P. Purohit, J. Hazard. Mater., 2022, 424, 127332.
[65]	G. Wu, P. Zelenay, Nat. Rev. Mater., 2024, 9, 643-656.
[66]	T. N. Q. Trang, T. B. Phan, N. D. Nam, V. T. H. Thu, ACS Appl. Mater. Interfaces, 2020, 12, 12195-12206.
[67]	H. Zhu, L. Gou, C. Li, X. Fu, Y. Weng, L. Chen, B. Fang, L. Shuai, G. Liao, Device, 2024, 2, 100283.
[68]	H. Zhu, C. Zhang, K. Xie, X. Li, G. Liao, Chem. Eng. J., 2023, 453, 139775.
[69]	M. Xu, X. Ruan, D. Meng, G. Fang, D. Jiao, S. Zhao, Z. Liu, Z. Jiang, K. Ba, T. Xie, W. Zhang, J. Leng, S. Jin, S. K. Ravi, X. Cui, Adv. Funct. Mater., 2024, 34, 2402330.
[70]	M. Guo, Z. Xing, T. Zhao, Y. Qiu, B. Tao, Z. Li, W. Zhou, Appl. Catal. B, 2020, 272, 118978.
[71]	H. Yang, Y. Liu, Y. Ding, F. Li, L. Wang, B. Cai, F. Zhang, T. Liu, G. Boschloo, E. M. J. Johansson, L. Sun, Nat. Commun., 2023, 14, 5486.
[72]	X. Zhang, G. Cui, H. Feng, L. Chen, H. Wang, B. Wang, X. Zhang, L. Zheng, S. Hong, M. Wei, Nat. Commun., 2019, 10, 5812.
[73]	M. Song, Y. Wu, Z. Zhao, M. Zheng, C. Wang, J. Lu, Adv. Mater., 2024, 36, 2403234.
[74]	D. Du, P. Liu, Z. Teng, T. Chen, J. Zhu, B. Shao, J. Luo, ACS Catal., 2025, 15, 3038-3045.
[75]	X. Liu, X. He, D. Xiong, G. Wang, Z. Tu, D. Wu, J. Wang, J. Gu, Z. Chen, ACS Catal., 2024, 14, 5366-5376.
[76]	S. Han, L. Sun, D. Fan, B. Liu, Nat. Commun., 2025, 16, 3426.
[77]	M. Xia, L. Pan, Y. Liu, J. Gao, J. Li, M. Mensi, K. Sivula, S. M. Zakeeruddin, D. Ren, M. Grätzel, J. Am. Chem. Soc., 2023, 145, 27939-27949.
[78]	L. Pan, L. Dai, O. J. Burton, L. Chen, V. Andrei, Y. Zhang, D. Ren, J. Cheng, L. Wu, K. Frohna, A. Abfalterer, T. C. Yang, W. Niu, M. Xia, S. Hofmann, P. J. Dyson, E. Reisner, H. Sirringhaus, J. Luo, A. Hagfeldt, M. Grätzel, S. D. Stranks, Nature, 2024, 628, 765-770.
[79]	X. Guo, C. Wang, Z. Yang, Y. Yang, Chem. Eng. J., 2023, 471, 144539.
[80]	Z. Tang, W. He, Y. Wang, Y. Wei, X. Yu, J. Xiong, X. Wang, X. Zhang, Z. Zhao, J. Liu, Appl. Catal. B, 2022, 311, 121371.
[81]	A. Herzog, A. Bergmann, H. S. Jeon, J. Timoshenko, S. Kühl, C. Rettenmaier, M. Lopez Luna, F. T. Haase, B. Roldan Cuenya, Angew. Chem. Int. Ed., 2021, 60, 7426-7435.
[82]	Q. Wu, R. Du, P. Wang, G. I. N. Waterhouse, J. Li, Y. Qiu, K. Yan, Y. Zhao, W.-W. Zhao, H.-J. Tsai, M.-C. Chen, S.-F. Hung, X. Wang, G. Chen, ACS Nano, 2023, 17, 12884-12894.
[83]	Y. Fang, D. Luan, Y. Chen, S. Gao, X. W. D. Lou, Angew. Chem. Int. Ed., 2020, 59, 7178-7183.
[84]	H. Luo, B. Li, J. G. Ma, P. Cheng, Angew. Chem. Int. Ed., 2022, 61, e202116736.
[85]	Y. Zhu, J. Wang, G. Weiser, M. Klingenhof, T. Koketsu, S. Liu, Y. Pi, G. Henkelman, X. Shi, J. Li, C.-W. Pao, M.-H. Yeh, W.-H. Huang, P. Strasser, J. Ma, Adv. Energy Mater., 2025, 2500554.

基于Ni单原子/P,N掺杂非晶态NiFe₂O₄作为阳极和Ag@CuO/Cu₂O纳米立方体作为阴极组成的高效光电化学系统用于微塑料氧化和二氧化碳还原

Efficient photoelectrochemical cell composed of Ni single atoms/P, N-doped amorphous NiFe₂O₄ as anode catalyst and Ag NPs@CuO/Cu₂O nanocubes as cathode catalyst for microplastic oxidation and CO₂ reduction

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 8

参考文献

相关文章 15

编辑推荐

Metrics

[1]	王刚, Imran Muhammad, 阎慧敏, 李隽, 王阳刚. 用杂原子调控Ni单原子催化剂的局部环境以实现高效CO₂电还原[J]. 催化学报, 2025, 74(7): 120-129.
[2]	潘嘉宁, 李敏, 王瑛琦, 谢文富, 张天雨, 王强. 先进的光电催化耦合反应[J]. 催化学报, 2025, 73(6): 99-145.
[3]	唐江渔, 王啸, 王云发, 石敏, 霍彭, 吴建祥, 李巧霞, 徐群杰. 活性非键合氧介导NiFe₂O₄晶格氧氧化以实现高效稳定水氧化[J]. 催化学报, 2025, 72(5): 164-175.
[4]	贾萁森, 王雅楠, 赵艳, 田圳铭, 任璐瑶, 崔学晶, 刘光波, 陈鑫, 李文震, 姜鲁华. 通过调节钛氧化物界面水结构驱动光电催化海水选择性氧化产氧[J]. 催化学报, 2025, 72(5): 154-163.
[5]	黄渝, 邹磊, 黄远标, 曹荣. 光、电、光电催化甲烷转化至醇类物质[J]. 催化学报, 2025, 70(3): 207-229.
[6]	蒋元元, 张妍, 刘梦梦, 刘璐璐, 陈红, 叶盛. 双电荷传输媒介促进赤铁矿光阳极的电荷转移实现高效光电催化水分解[J]. 催化学报, 2025, 69(2): 75-83.
[7]	Athira Krishnan, K. Archana, A. S. Arsha, Amritha Viswam, M. S. Meera. 宽带隙半导体在电催化和光催化水分解绿色制氢中的潜在作用[J]. 催化学报, 2025, 68(1): 103-145.
[8]	邵磊, 胡博琛, 郝金辉, 荆俊杰, 施伟东, 陈敏. 具有高曲率结构的枝晶状Cu/Cu₂O在H型电解池中实现二氧化碳到C₂产物的快速高效还原[J]. 催化学报, 2024, 63(8): 144-153.
[9]	朱鸿睿, 徐慧民, 黄陈金, 张志杰, 詹麒尼, 帅婷玉, 李高仁. 光电催化析氧和CO₂还原反应催化剂的研究进展[J]. 催化学报, 2024, 62(7): 53-107.
[10]	魏艳, 段睿智, 张巧兰, 曹有智, 王金圆, 王冰, 万雯瑞, 刘春燕, 陈加藏, 高红, 景欢旺. TiO₂/TiN纳米管异质结用于光电催化CO₂还原: 氮辅助活性氢机制[J]. 催化学报, 2023, 47(4): 243-253.
[11]	池海波, 王旺银, 马江平, 段睿智, 丁春梅, 宋睿, 李灿. 光电催化脱氟-氧化过程实现氟芳烃污染物的高效矿化[J]. 催化学报, 2023, 55(12): 171-181.
[12]	申珅玉, 郭庆丰, 武甜甜, 苏亚琼. 电催化CO₂还原过程中非均相界面的动态行为[J]. 催化学报, 2023, 53(10): 52-71.
[13]	张鹏, 李佑稷, 李鑫. 太阳能驱动H₂O₂的原位生产与利用: 自循环光催化芬顿系统[J]. 催化学报, 2023, 44(1): 4-6.
[14]	孟翔宇, 李睿, 杨峻懿, 许世明, 张辰晨, 尤可嘉, 马宝春, 管红霞, 丁勇. 六核环状钴配合物用于光催化CO₂到CO转化[J]. 催化学报, 2022, 43(9): 2414-2424.
[15]	徐志莹, 郭春雨, 刘欣, 李苓, 王亮, 徐浩兰, 张东柯, 李春虎, 李勤, 王文泰. Ag纳米粒子修饰有机/无机Z型3DOMM-TiO_2‒_x异质结的构建及高效光催化和光电催化分解水制氢[J]. 催化学报, 2022, 43(5): 1360-1370.