多相/均相TiO2/N-羟酰亚胺混合体系中可见光诱导分子氧可控光催化氧化苄基反应

doi:10.1016/S1872-2067(21)63831-7

摘要/Abstract

摘要：

均相催化和多相催化通常被认为是独立甚至相互对立的学科. 本文提出了一种新型的用于分子氧选择性氧化烷基苯的杂多酸/均相混合催化体系. 该催化体系由N-羟基邻苯二甲酰亚胺(NHPI, 用于自由基链式反应的均相有机催化剂)和纳米TiO₂(多相紫外光活性光氧化催化剂)两种组分组成. NHPI与TiO₂的协同作用使光氧化活性从紫外光转移到可见光, 并产生邻苯二甲酰亚胺-N-氧基(PINO)自由基. NHPI/PINO催化的自由基链式反应能够在没有额外光输入的情况下进行, 从而从根本上提高能源效率. 通过控制NHPI/TiO₂比率优化产物选择性, 进而使烷基芳烃优先形成过氧化氢或酮.

关键词: TiO₂, 光氧化还原催化, N-羟基邻苯二甲酰亚胺, N-氧自由基, 需氧氧化

Abstract:

Homogeneous and heterogeneous types of catalysis are frequently considered as separate disciplines or even opposed to each other. In the present work, a new type of mixed hetero-/homogeneous catalysis was demonstrated for the case of selective alkylarene oxidation by molecular oxygen. The proposed catalytic system consists of two widely available components: N-hydroxyphthalimide (NHPI, a homogeneous organocatalyst for free-radical chain reactions) and nanosized TiO₂ (heterogeneous UV-active photoredox catalyst). The interaction of NHPI with TiO₂ allows for a shift from UV to visible light photoredox activity and generation of phthalimide-N-oxyl (PINO) radicals that diffuse into the solution where NHPI/PINO-catalyzed free-radical chain reaction can proceed without the additional light input providing a fundamental increase in energy efficiency. The NHPI/TiO₂ ratio controls the selectivity of oxidation affording preferential formation of hydroperoxide or ketone from alkylarene.

Key words: TiO₂, Photoredox catalysis, N-hydroxyphthalimide, N-oxyl radicals, Aerobic oxidation

Igor B. Krylov, Elena R. Lopat’eva, Irina R. Subbotina, Gennady I. Nikishin, Bing Yu, Alexander O. Terent’ev. 多相/均相TiO₂/N-羟酰亚胺混合体系中可见光诱导分子氧可控光催化氧化苄基反应[J]. 催化学报, 2021, 42(10): 1700-1711.

Igor B. Krylov, Elena R. Lopat’eva, Irina R. Subbotina, Gennady I. Nikishin, Bing Yu, Alexander O. Terent’ev. Mixed hetero-/homogeneous TiO₂/N-hydroxyimide photocatalysis in visible-light-induced controllable benzylic oxidation by molecular oxygen[J]. Chinese Journal of Catalysis, 2021, 42(10): 1700-1711.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(21)63831-7

https://www.cjcatal.com/CN/Y2021/V42/I10/1700

图/表 10

参考文献

[1]	H. Sterckx, B. Morel, B. U. W. Maes, Angew. Chem. Int. Ed., 2019,58, 7946-7970.
[2]	X. Zhang, K. P. Rakesh, L. Ravindar, H.-L. Qin, Green Chem., 2018,20, 4790-4833.
[3]	T. Punniyamurthy, S. Velusamy, J. Iqbal, Chem. Rev., 2005,105, 2329-2364.
[4]	Z. Shi, C. Zhang, C. Tang, N. Jiao, Chem. Soc. Rev., 2012,41, 3381-3430.
[5]	K. Chen, P. Zhang, Y. Wang, H. Li, Green Chem., 2014,16, 2344-2374.
[6]	X. Lang, J. Zhao, Chem. Asian J., 2018,13, 599-613.
[7]	F. Recupero, C. Punta, Chem. Rev., 2007,107, 3800-3842.
[8]	L.-Y. Xie, Y.-S. Liu, H.-R. Ding, S.-F. Gong, J.-X. Tan, J.-Y. He, Z. Cao, W.-M. He, Chin. J. Catal., 2020,41, 1168-1173.
[9]	W.-B. He, L.-Q. Gao, X.-J. Chen, Z.-L. Wu, Y. Huang, Z. Cao, X.-H. Xu, W.-M. He, Chin. Chem. Lett., 2020,31, 1895-1898.
[10]	L.-Y. Xie, Y.-S. Bai, X.-Q. Xu, X. Peng, H.-S. Tang, Y. Huang, Y.-W. Lin, Z. Cao, W.-M. He, Green Chem., 2020,22, 1720-1725.
[11]	S. S. Stahl, P. L. Alsters, Eds., Liquid Phase Aerobic Oxidation Catalysis: Industrial Applications and Academic Perspectives, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, 2016.
[12]	N. A. Romero, D. A. Nicewicz, Chem. Rev., 2016,116, 10075-10166.
[13]	S. Munir, D. D. Dionysiou, S. B. Khan, S. M. Shah, B. Adhikari, A. Shah, J. Photochem. Photobiol. B, 2015,148, 209-222.
[14]	M. Uygur, O. García Mancheño, Org. Biomol. Chem., 2019,17, 5475-5489.
[15]	Y. Qiao, E. J. Schelter, Acc. Chem. Res., 2018,51, 2926-2936.
[16]	M. N. Hopkinson, B. Sahoo, J.-L. Li, F. Glorius, Chem.-Eur. J., 2014,20, 3874-3886.
[17]	S. Fukuzumi, K. Ohkubo, Org. Biomol. Chem., 2014,12, 6059-6071.
[18]	D. A. Nicewicz, T. M. Nguyen, ACS Catal., 2014,4, 355-360.
[19]	C. K. Prier, D. A. Rankic, D. W. C. MacMillan, Chem. Rev., 2013,113, 5322-5363.
[20]	X. Cao, T. Han, Q. Peng, C. Chen, Y. Li, Chem. Commun., 2020,56, 13918-13932.
[21]	D.-Q. Dong, L.-X. Li, G.-H. Li, Q. Deng, Z.-L. Wang, S. Long, Chin. J. Catal., 2019,40, 1494-1498.
[22]	L.-Y. Xie, S. Peng, L.-H. Yang, C. Peng, Y.-W. Lin, X. Yu, Z. Cao, Y.-Y. Peng, W.-M. He, Green Chem., 2021,23, 374-378.
[23]	Q.-W. Gui, F. Teng, Z.-C. Li, Z.-Y. Xiong, X.-F. Jin, Y.-W. Lin, Z. Cao, W.-M. He, Chin. Chem. Lett., 2021, doi: 10.1016/j.cclet.2021.01.021.
[24]	G.-H. Li, Q.-Q. Han, Y.-Y. Sun, D.-M. Chen, Z.-L. Wang, X.-M. Xu, X.-Y. Yu, Chin. Chem. Lett., 2020,31, 3255-3258.
[25]	B. Mühldorf, R. Wolf, Angew. Chem. Int. Ed., 2016,55, 427-430.
[26]	M. Lesieur, C. Genicot, P. Pasau, Org. Lett., 2018,20, 1987-1990.
[27]	G. Tang, Z. Gong, W. Han, X. Sun, Tetrahedron Lett., 2018,59, 658-662.
[28]	B. Mühldorf, R. Wolf, Chem. Commun., 2015,51, 8425-8428.
[29]	I. Itoh, Y. Matsusaki, A. Fujiya, N. Tada, T. Miura, A. Itoh, Tetrahedron Lett., 2014,55, 3160-3162.
[30]	Y. Zhang, D. Riemer, W. Schilling, J. Kollmann, S. Das, ACS Catal., 2018,8, 6659-6664.
[31]	H. Yi, C. Bian, X. Hu, L. Niu, A. Lei, Chem. Commun., 2015,51, 14046-14049.
[32]	M. Kojima, K. Oisaki, M. Kanai, Tetrahedron Lett., 2014,55, 4736-4738.
[33]	L. C. Finney, L. J. Mitchell, C. J. Moody, Green Chem., 2018,20, 2242-2249.
[34]	F. Rusch, J.-C. Schober, M. Brasholz, ChemCatChem, 2016,8, 2881-2884.
[35]	D. Pan, Y. Wang, M. Li, X. Hu, N. Sun, L. Jin, B. Hu, Z. Shen, Synlett, 2019,30, 218-224.
[36]	K. C. C. Aganda, B. Hong, A. Lee, Adv. Synth. Catal., 2018,361, 1124-1129.
[37]	S. Li, B. Zhu, R. Lee, B. Qiao, Z. Jiang, Org. Chem. Front., 2018,5, 380-385.
[38]	J. Chen, J. Cen, X. Xu, X. Li, Catal. Sci. Technol., 2016,6, 349-362.
[39]	L. Chen, J. Tang, L.-N. Song, P. Chen, J. He, C.-T Au, S.-F. Yin, Appl. Catal. B, 2019,242, 379-388.
[40]	S. Gisbertz, B. Pieber, ChemPhotoChem, 2020,4, 456-475.
[41]	H. Cheng, W. Xu, Org. Biomol. Chem., 2019,17, 9977-9989.
[42]	D. Ma, A. Liu, S. Li, C. Lu, C. Chen, Catal. Sci. Technol., 2018,8, 2030-2045.
[43]	Y. Wang, A. Liu, D. Ma, S. Li, C. Lu, T. Li, C. Chen, Catalysts, 2018,8, 355.
[44]	P. Riente, T. Noël, Catal. Sci. Technol., 2019,9, 5186-5232.
[45]	Y. Fu, J. Li, J. Li, Nanomaterials, 2019,9, 359.
[46]	X. Lang, W. Ma, C. Chen, H. Ji, J. Zhao, Acc. Chem. Res., 2014,47, 355-363.
[47]	X. Lang, X. Chen, J. Zhao, Chem. Soc. Rev., 2014,43, 473-486.
[48]	M. Tomás-Gamasa, J. L. Mascareñas, ChemBioChem, 2020,21, 294-309.
[49]	M. Jafarpour, F. Feizpour, A. Rezaeifard, RSC Adv., 2016,6, 54649-54660.
[50]	S. Li, Z.-J. Li, H. Yu, M. R. Sytu, Y. Wang, D. Beeri, W. Zheng, B. D. Sherman, C. G. Yoo, G. Leem, ACS Energy Lett., 2020,5, 777-784.
[51]	I. B. Krylov, E. R. Lopat’eva, A. S. Budnikov, G. I. Nikishin, A. O. Terent’ev, J. Org. Chem., 2020,85, 1935-1947.
[52]	I. B. Krylov, S. A. Paveliev, B. N. Shelimov, B. V. Lokshin, I. A. Garbuzova, V. A. Tafeenko, V. V. Chernyshev, A. S. Budnikov, G. I. Nikishin, A. O. Terent’ev, Org. Chem. Front., 2017,4, 1947-1957.
[53]	A. O. Terent’ev, I. B. Krylov, V. P. Timofeev, Z. A. Starikova, V. M. Merkulova, A. I. Ilovaisky, G. I. Nikishin, Adv. Synth. Catal., 2013,355, 2375-2390.
[54]	A. S. Budnikov, I. B. Krylov, Chem. Heterocycl. Compd., 2020,56, 36-38.
[55]	S. G. Kumar, L. G. Devi, J. Phys. Chem. A, 2011,115, 13211-13241.
[56]	D. Chen, Y. Cheng, N. Zhou, P. Chen, Y. Wang, K. Li, S. Huo, P. Cheng, P. Peng, R. Zhang, L. Wang, H. Liu, Y. Liu, R. Ruan, J. Cleaner Prod., 2020,268, 121725.
[57]	C. H. A. Tsang, K. Li, Y. Zeng, W. Zhao, T. Zhang, Y. Zhan, R. Xie, D. Y. C. Leung, H. Huang, Environ. Int., 2019,125, 200-228.
[58]	S. Gunti, A. Kumar, M. K. Ram, Int. Mater. Rev., 2018,63, 257-282.
[59]	Z. Shayegan, C.-S. Lee, F. Haghighat, Chem. Eng. J., 2018,334, 2408-2439.
[60]	V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, S. C. Pillai, J. Photochem. Photobiol. C, 2015,25, 1-29.
[61]	A. H. Mamaghani, F. Haghighat, C.-S. Lee, Appl. Catal. B, 2017,203, 247-269.
[62]	K. P. Gopinath, N. V. Madhav, A. Krishnan, R. Malolan, G. Rangarajan, J. Environ. Manage., 2020,270, 110906.
[63]	J. Chen, F. Qiu, W. Xu, S. Cao, H. Zhu, Appl. Catal. A, 2015,495, 131-140.
[64]	D.V. Barsukov, A. N. Pershin, I. R. Subbotina, J. Photochem. Photobiol. A, 2016,324, 175-183.
[65]	I. R. Subbotina, D. V. Barsukov, Phys. Chem. Chem. Phys., 2020,22, 2200-2211.
[66]	D. V. Barsukov, A. V. Saprykin, I. R. Subbotina, N. Ya. Usachev, Mendeleev Commun., 2017,27, 248-250.
[67]	Y. Akila, N. Muthukumarasamy, D. Velauthapillai, in T. Sabu, E. H. M. Sakho, S. O. Oluwafemi, N. Kalarikkal, J. Wu eds., Nanomaterials for Solar Cell Applications, Elsevier, 2019, 127-144.
[68]	M. Ge, J. Cai, J. Iocozzia, C. Cao, J. Huang, X. Zhang, J. Shen, S. Wang, S. Zhang, K.-Q. Zhang, Y. Lai, Z. Lin, Int. J. Hydrogen Energy, 2017,42, 8418-8449.
[69]	M. Yasuda, T. Matsumoto, T. Yamashita, Renew. Sustain. Energy Rev., 2018,81, 1627-1635.
[70]	R. Singh, S. Dutta, Fuel, 2018,220, 607-620.
[71]	A. Miyoshi, S. Nishioka, K. Maeda, Chem. Eur. J., 2018,24, 18204-18219.
[72]	N. Fajrina, M. Tahir, Int. J. Hydrogen Energy, 2019,44, 540-577.
[73]	L. Wei, C. Yu, Q. Zhang, H. Liu, Y. Wang, J. Mater. Chem. A, 2018,6, 22411-22436.
[74]	Z. Xiong, Z. Lei, Y. Li, L. Dong, Y. Zhao, J. Zhang, J. Photochem. Photobiol. C, 2018,36, 24-47.
[75]	S. Remiro-Buenamañana, H. García, ChemCatChem, 2019,11, 342-356.
[76]	S. Nahar, M. F. M. Zain, A. A. H. Kadhum, H. Abu Hasan, Md. R. Hasan, Materials, 2017,10, 629.
[77]	P. V. Laxma Reddy, B. Kavitha, P. A. Kumar Reddy, K.-H. Kim, Environ. Res., 2017,154, 296-303.
[78]	Z. Zhu, H. Cai, D.-W. Sun, Trends Food Sci. Technol., 2018,75, 23-35.
[79]	C. S. Uyguner Demirel, N. C. Birben, M. Bekbolet, Chemosphere, 2018,211, 420-448.
[80]	C. Liao, Y. Li, S. C. Tjong, Nanomaterials, 2020,10, 124.
[81]	H. Rezala, H. Khalaf, J. L. Valverde, A. Romero, A. Molinari, A. Maldotti, Appl. Catal. A, 2009,352, 234-242.
[82]	S. Yurdakal, G. Palmisano, V. Loddo, V. Augugliaro, L. Palmisano, J. Am. Chem. Soc., 2008,130, 1568-1569.
[83]	J. A. Pincock, A. L. Pincock, M. A. Fox, Tetrahedron, 1985,41, 4107-4117.
[84]	D. Franchi, Z. Amara, ACS Sustain. Chem. Eng., 2020,8, 15405-15429.
[85]	M. Zhang, C. Chen, W. Ma, J. Zhao, Angew. Chem. Int. Ed., 2008,47, 9730-9733.
[86]	Z. Wang, X. Lang, Appl. Catal. B, 2018,224, 404-409.
[87]	L. Ren, H. Cong, Org. Lett., 2018,20, 3225-3228.
[88]	H. Hao, Z. Wang, J.-L. Shi, X. Li, X. Lang, ChemCatChem, 2018,10, 4545-4554.
[89]	L. Ren, M.-M. Yang, C.-H. Tung, L.-Z. Wu, H. Cong, ACS Catal., 2017,7, 8134-8138.
[90]	X. Li, J.-L. Shi, H. Hao, X. Lang, Appl. Catal. B, 2018,232, 260-267.
[91]	M. Koohgard, Z. Hosseinpour, A. M. Sarvestani, M. Hosseini-Sarvari, Catal. Sci. Technol., 2020,10, 1401-1407.
[92]	N. Wang, J.-L. Shi, H. Hao, H. Yuan, X. Lang, Sustainable Energy Fuels, 2019,3, 1701-1712.
[93]	X. Lang, J. Zhao, X. Chen, Angew. Chem. Int. Ed., 2016,55, 4697-4700.
[94]	C. Zhang, Z. Huang, J. Lu, N. Luo, F. Wang, J. Am. Chem. Soc., 2018,140, 2032-2035.
[95]	L.-Y. Jiang, J.-J. Ming, L.-Y. Wang, Y.-Y. Jiang, L.-H. Ren, Z.-C. Wang, W.-C. Cheng, Green Chem., 2020,22, 1156-1163.
[96]	G. Zhao, B. Hu, G. W. Busser, B. Peng, M. Muhler, ChemSusChem, 2019,12, 2795-2801.
[97]	P. Zhang, Y. Wang, J. Yao, C. Wang, C. Yan, M. Antonietti, H. Li, Adv. Synth. Catal., 2011,353, 1447-1451.
[98]	I. A. Yaremenko, P. S. Radulov, Y. Y. Belyakova, A. A. Demina, D. I. Fomenkov, D. V. Barsukov, I. R. Subbotina, F. Fleury, A. O. Terent’ev, Chem. Eur. J., 2020,26, 4734-4751.
[99]	T. Moriai, T. Tsukamoto, M. Tanabe, T. Kambe, K. Yamamoto, Angew. Chem. Int. Ed., 2020,59, 23051-23055.
[100]	L. Melone, P. Franchi, M. Lucarini, C. Punta, Adv. Synth. Catal., 2013,355, 3210-3220.
[101]	H. Hao, J.-L. Shi, H. Xu, X. Li, X. Lang, Appl. Catal. B, 2019,246, 149-155.
[102]	V. V. Kachala, L. L. Khemchyan, A. S. Kashin, N. V. Orlov, A. A. Grachev, S. S. Zalesskiy, V. P. Ananikov, Russ. Chem. Rev., 2013,82, 648-685.
[103]	Y. Li, J. Zhang, D. Li, Y. Chen, Org. Lett., 2018,20, 3296-3299.
[104]	I. B. Krylov, M. O. Kompanets, K. V. Novikova, I. O. Opeida, O. V. Kushch, B. N. Shelimov, G. I. Nikishin, D. O. Levitsky, A. O. Terent’ev, J. Phys. Chem. A, 2016,120, 68-73.
[105]	H. E. Gottlieb, V. Kotlyar, A. Nudelman, J. Org. Chem., 1997,62, 7512-7515.
[106]	Y. Hou, J. Hu, R. Xu, S. Pan, X. Zeng, G. Zhong, Org. Lett., 2019,21, 4428-4432.
[107]	T. E. Anderson, K. A. Woerpel, Org. Lett., 2020,22, 5690-5694.
[108]	A. Rahimi Niaraki, M. R. Saraee, F. Kazemi, B. Kaboudin, Org. Biomol. Chem., 2020,18, 2326-2330.
[109]	X. Li, C. Chen, J. Zhao, Langmuir, 2001,17, 4118-4122.
[110]	X. Roohi, M. Rajabi, Org. Process Res. Dev., 2018,22, 136-146.
[111]	S. Lyu, H. Hao, X. Li, X. Lang, Chemosphere, 2021,262, 127873.
[112]	A. O. Terent’ev, I. B. Krylov, M. Y. Sharipov, Z. M. Kazanskaya, G. I. Nikishin, Tetrahedron, 2012,68, 10263-10271.
[113]	I. B. Krylov, A. S. Budnikov, A. V. Lastovko, Y. A. Ibatov, G. I. Nikishin, A. O. Terent′ev, Russ. Chem. Bull., 2019,68, 1454-1457.
[114]	I. Hermans, J. Peeters, P. A. Jacobs, J. Org. Chem., 2007,72, 3057-3064.

Consumed power (W)	Irradiance * (W/m²)	Relative irradiated power
10	1165	1
5	700	0.6
2.5	407	0.35
1	203	0.17

Consumed power (W)	Irradiance * (W/m²)	Relative irradiated power
10	1165	1
5	700	0.6
2.5	407	0.35
1	203	0.17

多相/均相TiO₂/N-羟酰亚胺混合体系中可见光诱导分子氧可控光催化氧化苄基反应

Mixed hetero-/homogeneous TiO₂/N-hydroxyimide photocatalysis in visible-light-induced controllable benzylic oxidation by molecular oxygen

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 10

参考文献

相关文章 15

编辑推荐

Metrics

Run	Deviation from general conditions ^a	X (%)	S_2a (%)	S_3a (%)	S_4a (%)
1	None	40	39	5	48
1	None	(43)	(40)		(44)
2	TiO₂without NHPI	—	—	—	—
3	NHPI without TiO₂	<5	80	—	—
4	TiO₂ was filtered before irradiation	<5	76	—	—
5	No irradiation (in dark)	<5	50	—	—
6	Irradiation by 10 W violet LED (λ_max = 405 nm)	44	22	6	65
7	Irradiation by 10 W UV LED (λ_max = 373 nm)	27	51	4	28
12	5 W blue LED	39	44	3	45
12	5 W blue LED	(41)	(44)		(49)
13	1 W blue LED	31	55	3	32
14	NHSI instead of NHPI	21	8	9	28
15	Cl₄-NHPI instead of NHPI	28	40	8	52
16	NHNPI instead of NHPI	26	3	11	53
17	TiO₂ anatase nanopowder	25	62	4	21
18	TiO₂ P25 Aeroxide	26	59	5	24
19	C₂H₄Cl₂ as solvent	19	14	5	70
20	PhCl as solvent	13	6	8	85
20	PhCl as solvent	(18)	(13)		(60)
21	MeNO₂ as solvent	57	12	9	75
22	AcOH as solvent	(33)	(17)		(48)
23	40 °C	55	15	4	66
23	40 °C	(56)	(18)		(60)
24	60 °C	66	2	2	85
25	Reaction under air	32	29	4	59
26	Reaction under argon	<5	—	—	87
27	Reaction time 24 h	65	4	2	85

Run	NHPI (mol%)	TiO₂ (mg)	X (%)	S_2a (%)	S_3a (%)	S_4a (%)
1	10	10	40	39	5	48
2	10	5	36	54	5	35
3	10	2.5	31	67	3	23
4 ^b	10	2.5	13	90	—	2
5 ^c	10	2.5	18	79	—	16
6 ^d	10	2.5	37	55	5	37
7 ^e	40	2.5	32	76	—	15
8 ^e	10	10	30	34	6	49
8 ^e	10	10	(31)	(39)		(53)
9	5	10	28	28	6	62
10	2.5	10	24	14	6	67
11	10	20	43	23	4	67
12	10	40	44	19	5	71

[1]	李嘉明, 李源, 王小田, 杨直雄, 张高科. TiO₂上原子分散的Fe位点促进光催化CO₂还原: 增强的催化活性、 DFT计算和机制洞察[J]. 催化学报, 2023, 51(8): 145-156.
[2]	袁鑫, 范海滨, 刘杰, 覃龙州, 王剑, 段秀, 邱江凯, 郭凯. 连续流技术在光氧化还原催化转化的最新进展[J]. 催化学报, 2023, 50(7): 175-194.
[3]	刘德法, 孙彬, 白硕杰, 高婷婷, 周国伟. 双助催化剂Ag/Ti₃C₂/TiO₂分层花状微球用于增强光催化产氢活性[J]. 催化学报, 2023, 50(7): 273-283.
[4]	杨成功, 王冬娥, 黄蓉, 韩健强, 塔娜, 马怀军, 曲炜, 潘振栋, 王从新, 田志坚. 高效稳定的MoS₂-TiO₂纳米复合催化剂用于浆态床菲催化加氢[J]. 催化学报, 2023, 46(3): 125-136.
[5]	钱秀, 魏艳娇, 孙梦洁, 韩野, 张晓俐, 田健, 邵敏华. 在Ti₃C₂T_x MXene上原位生长2D TiO₂纳米片的异质结构用于改善电催化氮气还原[J]. 催化学报, 2022, 43(7): 1937-1944.
[6]	李垒, 欧阳汶俊, 郑泽锋, 叶凯航, 郭禹希, 秦延林, 伍珍珍, 林展, 王铁军, 张山青. 基于Pt@TiO₂催化剂光-热协同催化甲醇-水液相重整甲醇制氢[J]. 催化学报, 2022, 43(5): 1258-1266.
[7]	王芃梓, 肖文精, 陈加荣. 基于1,3-二烯的自由基反应的近期研究进展[J]. 催化学报, 2022, 43(3): 548-557.
[8]	李金懋, 吴聪聪, 李矜, 董兵海, 赵丽, 王世敏. 1D/2D TiO₂/ZnIn₂S₄ S型异质结光催化剂及其高效制氢性能[J]. 催化学报, 2022, 43(2): 339-349.
[9]	李华鹏, 孙彬, 高婷婷, 李欢, 任永强, 周国伟. Ti₃C₂ MXene助催化剂组装的介孔TiO₂用以增强光催化甲基橙降解和产氢活性[J]. 催化学报, 2022, 43(2): 461-471.
[10]	王可, 何仕辉, 林云志, 陈旬, 戴文新, 付贤智. 氧空位修饰的暴露TiO₂{001}的Ru/TiO₂增强光热协同CO₂甲烷化活性和稳定性[J]. 催化学报, 2022, 43(2): 391-402.
[11]	朱玉坤, 庄严, 王乐乐, 唐华, 孟献丰, 佘希林. 构建0D/1D Ag₃PO₄/TiO₂ S型异质结以实现高效光降解和析氧[J]. 催化学报, 2022, 43(10): 2558-2568.
[12]	薛超, 安华, 邵国胜, 杨贵东. 源于功函数差异的界面内建电场调控载流子定向分离的作用机制研究[J]. 催化学报, 2021, 42(4): 583-594.
[13]	贾爱平, 张云尚, 宋通洋, 胡一鸣, 郑万彬, 罗孟飞, 鲁继青, 黄伟新. TiO₂晶面依赖的Ir-TiO_x相互作用对Ir/TiO₂催化剂巴豆醛选择性加氢性能的影响[J]. 催化学报, 2021, 42(10): 1742-1754.
[14]	李莉, 陈海军, 李磊, 李白海, 吴千宝, 崔春华, 邓彪, 罗永岚, 刘倩, 李廷帅, 张芳, Abdullah M. Asiri, 冯哲圣, 王焱, 孙旭平. La掺杂的TiO₂纳米棒在常温常压下可促进电催化的N₂转化为NH₃[J]. 催化学报, 2021, 42(10): 1755-1762.
[15]	刘晶, 盖瑞侯得, 闫俊青, 刘生忠. 金属(Fe, Co, Ni, Cu)掺杂的Mo₂C催化剂在TiO₂表面用于中性条件光催化分解水产氢[J]. 催化学报, 2021, 42(1): 205-216.