表面增强振动光谱在电催化领域的运用: 基本原理、挑战和展望

doi:10.1016/S1872-2067(22)64157-3

催化学报 ›› 2022, Vol. 43 ›› Issue (11): 2757-2771.DOI: 10.1016/S1872-2067(22)64157-3

表面增强振动光谱在电催化领域的运用: 基本原理、挑战和展望

苏海胜, 常晓侠, 徐冰君^*()

北京大学化学与分子工程学院, 北京 100871

收稿日期:2022-06-01 接受日期:2022-07-28 出版日期:2022-11-18 发布日期:2022-10-20
通讯作者: 徐冰君
基金资助:
中国博士后科学基金(2022M710001);北京分子科学国家研究中心

Surface-enhanced vibrational spectroscopies in electrocatalysis: Fundamentals, challenges, and perspectives

Hai-Sheng Su, Xiaoxia Chang, Bingjun Xu^*()

College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Received:2022-06-01 Accepted:2022-07-28 Online:2022-11-18 Published:2022-10-20
Contact: Bingjun Xu
About author:Bingjun Xu is the Ge li and Ning Zhao Chair Professor at College of Chemistry and Molecular Engineering of the Peking University. Dr. Xu received his Ph.D. in Physical Chemistry from Harvard University in 2011, and then worked as a postdoctoral researcher at Caltech. Dr. Xu started his independent research career in the Department of Chemical & Biomolecular Engineering at University of Delaware in 2013 as an Assistant Professor, and was promoted to a Centennial Development Associate Professor in 2019. Dr. Xu joined the Peking University in 2020. The current research interest of the Xu lab spans heterogeneous catalysis, electrocatalysis and in-situ/operando spectroscopy. Dr. Xu is an awardee of US NSF Early Career Award (2017), US Air Force Office of Scientific Research Young Investigator Award (2016), ACS Petroleum Research Fund Doctoral New Investigator Award (2015), the I&EC Class 2018 Influential Researchers (2018), and was elected as an Early Career Fellow in the Industrial & Engineering Chemistry Division of ACS (2022). He has published more than 100 peer reviewed articles.
Supported by:
China Postdoctoral Science Foundation(2022M710001);Beijing National Laboratory for Molecular Science

摘要/Abstract

摘要：

随着全球能源结构从化石燃料向可再生能源的快速转变, 可再生电力的供应日益丰富. 电催化为化学反应提供了新的思路和途径. 大多数电催化反应发生在固液界面, 但由于溶剂、电解质和带电界面的存在, 电催化在本质上比热催化更复杂. 因此, 电化学界面的表征对于反应机理的研究至关重要. 具有表界面选择性的原位表征技术有助于揭示催化剂的构效关系, 解析反应机理. 其中, 表面增强振动光谱, 例如表面增强拉曼光谱(SERS)和表面增强红外吸收光谱(SEIRAS), 具有超高的表面选择性和化学灵敏度, 能够在反应条件下提供表界面物种的指纹信息, 原位研究电催化过程. SERS增强效应主要来源于电磁场增强机理和化学增强机理. 在电催化体系中, 主要以具有表面等离激元效应的SERS基底作为增强源, 增强催化剂表面物种的拉曼信号, 从而研究反应过程的物种变化. SEIRAS主要利用电磁场增强效应, 在电催化体系的运用以衰减全反射模式为主, 增强工作电极表面物种的红外吸收信号. 相较于SEIRAS, SERS信号不受水溶剂的干扰, 并且可以研究低波数区域的振动信号, 理解催化剂和吸附物的相互作用. 而SEIRAS受益于红外吸收光谱本身信号较强, 且增强效应不受限于金、银和铜等贵金属, 适用于研究过渡金属电极.

虽然SERS和SEIRAS已经被普遍用于分析电催化体系, 该领域仍存在着较多的挑战. 本文讨论了以下挑战并提出了可能的改进方法:(1)这两种技术可能对不同的表界面物种具有不同的敏感度, 因此单一技术不一定能全面反映表面物种组成; (2)反应中间物种表面覆盖度低、寿命短, 导致光谱信号弱, 难以监测, 且需进一步辨别光谱中的中间物种、毒化物种和不参与后续反应的物种; (3)对于复杂体系的谱峰指认较为困难; (4)理论计算难以精确模拟电催化表界面; (5)定量分析能力受限于均匀增强基底的制备; (6)需要进一步理解壳层隔绝粒子中壳层的作用. 为了进一步拓展表面增强光谱技术在电催化体系中的运用, 本文展望了其未来的发展方向及在电催化机理研究中的应用: (1)使用针尖增强拉曼光谱和纳米红外光谱, 提高空间分辨率, 获得纳米尺度下的构效关系; (2)提高时间分辨率, 研究电催化反应的动态变化; (3)实现多种电化学原位技术的联用, 多角度分析反应过程; (4)利用光谱信息进行反应动力学和热力学研究; (5)实现工况条件下的原位表征, 实时关联光谱信息和反应活性; (6)利用人工智能对实验数据进行分析, 高效提取关键信息. 综上, 本文介绍了SERS和SEIRAS技术的基本原理, 并对其在电催化领域所面临的挑战和存在的机遇进行了详细的讨论, 对该领域的研究人员具有重要的借鉴意义.

关键词: 表面增强拉曼光谱, 表面增强红外吸收光谱, 原位表征, 电催化, 构效关系, 反应机理

Abstract:

Electrocatalysis offers a promising approach towards chemical synthesis driven by renewable energy. Molecular level understanding of the electrochemical interface remains challenging due to its compositional and structural complexity. In situ interfacial specific characterization techniques could help uncover structure-function relationships and reaction mechanism. To this end, electrochemical surface-enhanced Raman spectroscopy (SERS) and surface-enhanced infrared absorption spectroscopy (SEIRAS) thrive as powerful techniques to provide fingerprint information of interfacial species at reaction conditions. In this review, we first introduce the fundamentals of SERS and SEIRAS, followed by discussion regarding the technical challenges and potential solutions. Finally, we highlight future directions for further development of surface-enhanced spectroscopic techniques for electrocatalytic studies.

Key words: Surface-enhanced Raman spectroscopy, Surface-enhanced infrared absorption spectroscopy, In situ characterization, Electrocatalysis, Structure-function relationship, Reaction mechanism

苏海胜, 常晓侠, 徐冰君. 表面增强振动光谱在电催化领域的运用: 基本原理、挑战和展望[J]. 催化学报, 2022, 43(11): 2757-2771.

Hai-Sheng Su, Xiaoxia Chang, Bingjun Xu. Surface-enhanced vibrational spectroscopies in electrocatalysis: Fundamentals, challenges, and perspectives[J]. Chinese Journal of Catalysis, 2022, 43(11): 2757-2771.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(22)64157-3

https://www.cjcatal.com/CN/Y2022/V43/I11/2757

图/表 8

Fig. 1. Schematic of surface plasmonic resonance (a) and the electromagnetic enhancement of SERS (b). (c) Transmission electron microscopy image of typical Au@SiO2 nanoparticles with 55 nm-Au core and 2 nm-SiO2 shell. Reprinted with permission from Ref. [28]. Copyright 2020, American Chemical Society.

Fig. 2. Schematics of SERS nanostructures to monitor in situ electrocatalytic reactions. (a) SERS core-shell; (b) SHINs-satellite; (c) SHINs on flat electrodes.

Fig. 3. Schematics of two typical electrochemical spectral cells for SERS experiments. (a) A home-built cell. Reprinted with permission from Ref. [51]. Copyright 2013, Nature America, Inc. (b) A commercial cell. Reprinted with permission from Ref. [28]. Copyright 2020, American Chemical Society.

Fig. 4. Schematic of internal (a) and external (b) reflection modes for in situ FTIR experiments.

Fig. 5. Schematics of electrochemical cells for in situ ATR-SEIRAS experiments. (a) A typical cell. Reprinted with permission from Ref. [55]. Copyright 2019, American Chemical Society. (b) A side-facing cell. Reprinted with permission from Ref. [64]. Copyright 2022, Springer Nature. (c) A side-facing sell with stirring. Reprinted with permission from Ref. [65]. Copyright, 2020 American Chemical Society. (d) A modified cell for both in situ SEIRAS and SERS measurements. Reprinted with permission from Ref. [64]. Copyright 2022, Springer Nature.

Table 1 Comparison of surface-enhanced Raman and infrared absorption spectroscopies. E represents the enhancement of electromagnetic field.

Characteristic	SERS	SEIRAS
Vibrational mode	Changing polarizability	Changing dipole moment
Optical cross-section	Raman scattering ~10^-30 cm² sr^-1	IR absorption ~10^-20 cm² sr^-1
Spectral range	~10-4000 cm^-1	~1000-4000 cm^-1 for conventional Si prisms (600-4000 cm^-1 with thin micromachined Si wafers)
Absorption of H₂O	Weak	Strong
Surface enhancement	Proportional to E⁴, routinely larger than 10⁶	Proportional to E², usually 10-10³
Irradiation source	Monochromatic laser, typically visible or near-IR laser	Continuum wavelength, typically in mid-IR region
Photo damage	Relatively high	Relatively low

Fig. 6. (a) In situ SEIRAS and SERS spectra on oxide-derived Cu film. (b) Plots of CO peak frequency as a function of potential. The Stark tuning rates were labeled. (c) In situ SEIRA spectra on oxide-derived Cu film at -0.7 VRHE with and without stirring. (d) Normalized peak area of COatop peaks (blue) and the current density (black) during the SEIRAS test in (c). Reprinted with permission from Ref. [74]. Copyright 2022, Springer Nature.

参考文献

[1]	R. C. Armstrong, C. Wolfram, K. P. de Jong, R. Gross, N. S. Lewis, B. Boardman, A. J. Ragauskas, K. Ehrhardt-Martinez, G. Crabtree, M. V. Ramana, Nat. Energy, 2016, 1, 15020.
[2]	A. Yazdani, G. G. Botte, Curr. Opin. Chem. Eng., 2020, 29, 89-95.
[3]	T. Hartman, R. G. Geitenbeek, C. S. Wondergem, W. van der Stam, B. M. Weckhuysen, ACS Nano, 2020, 14, 3725-3735.
[4]	J. Timoshenko, B. Roldan Cuenya, Chem. Rev., 2021, 121, 882-961.
[5]	X. Wang, Y.-Q. Wang, Y.-C. Feng, D. Wang, L.-J. Wan, Chem. Soc. Rev., 2021, 50, 5832-5849.
[6]	G. H. Simon, C. S. Kley, B. Roldan Cuenya, Angew. Chem. Int. Ed., 2021, 60, 2561-2568.
[7]	T. Sun, Y. Yu, B. J. Zacher, M. V. Mirkin, Angew. Chem. Int. Ed., 2014, 53, 14120-14123.
[8]	Y. Liang, J. H. K. Pfisterer, D. McLaughlin, C. Csoklich, L. Seidl, A. S. Bandarenka, O. Schneider, Small Methods, 2019, 3, 1800387.
[9]	J.-C. Dong, X.-G. Zhang, V. Briega-Martos, X. Jin, J. Yang, S. Chen, Z.-L. Yang, D.-Y. Wu, J. M. Feliu, C. T. Williams, Z.-Q. Tian, J.-F. Li, Nat. Energy, 2019, 4, 60-67.
[10]	B. J. Trześniewski, O. Diaz-Morales, D. A. Vermaas, A. Longo, W. Bras, M. T. M. Koper, W. A. Smith, J. Am. Chem. Soc., 2015, 137, 15112-15121.
[11]	H.-Q. Chen, H. Ze, M.-F. Yue, D.-Y. Wei, Y.-L. A, Y.-F. Wu, J.-C. Dong, Y.-J. Zhang, H. Zhang, Z.-Q. Tian, J.-F. Li, Angew. Chem. Int. Ed., 2022, 61, e202117834.
[12]	Y.-H. Wang, X.-T. Wang, H. Ze, X.-G. Zhang, P. M. Radjenovic, Y.-J. Zhang, J.-C. Dong, Z.-Q. Tian, J.-F. Li, Angew. Chem. Int. Ed., 2020, 60, 5708-5711.
[13]	M. Yoshida, A. Yamakata, K. Takanabe, J. Kubota, M. Osawa, K. Domen, J. Am. Chem. Soc., 2009, 131, 13218-13219.
[14]	A. S. Malkani, J. Li, N. J. Oliveira, M. He, X. Chang, B. Xu, Q. Lu, Sci. Adv., 2020, 6, eabd2569.
[15]	Y. Meng, S. Kuang, H. Liu, Q. Fan, X. Ma, S. Zhang, Acta Phys.-Chim. Sin., 2021, 37, 2006034.
[16]	R. Kas, O. Ayemoba, N. J. Firet, J. Middelkoop, W. A. Smith, A. Cuesta, ChemPhysChem., 2019, 20, 2904-2925.
[17]	C. M. Gunathunge, J. Li, X. Li, M. M. Waegele, ACS Catal., 2020, 10, 11700-11711.
[18]	Y. Yao, S. Zhu, H. Wang, H. Li, M. Shao, J. Am. Chem. Soc., 2018, 140, 1496-1501.
[19]	Y. Yao, H. Wang, X.-z. Yuan, H. Li, M. Shao, ACS Energy Lett., 2019, 4, 1336-1341.
[20]	H. Li, T.-W. Jiang, X. Qin, J. Chen, X.-Y. Ma, K. Jiang, X.-G. Zhang, W.-B. Cai, ACS Catal., 2021, 11, 6846-6856.
[21]	Z. Xu, Z. Liang, W. Guo, R. Zou, Coord. Chem. Rev., 2021, 436, 213824.
[22]	Y. Wang, D. Chen, ACS Appl. Mater. Interfaces, 2022, 14, 23033-23055.
[23]	H.-Q. Chen, L. Zou, D.-Y. Wei, L.-L. Zheng, Y.-F. Wu, H. Zhang, J.-F. Li, Chin. J. Catal., 2022, 43, 33-46.
[24]	H. Liu, Z. Qi, L. Song, J. Phys. Chem. C, 2021, 125, 24289-24300.
[25]	H. Wang, Y.-W. Zhou, W.-B. Cai, Curr. Opin. Electrochem., 2017, 1, 73-79.
[26]	K. J. S.-Z. Z,. W.-B. C. Hong Li, Chin. J. Catal., 2022, 43, 1-1.
[27]	A. I. Pérez-Jiménez, D. Lyu, Z. Lu, G. Liu, B. Ren, Chem. Sci., 2020, 11, 4563-4577.
[28]	Y. Zhao, X. Chang, A. S. Malkani, X. Yang, L. Thompson, F. Jiao, B. Xu, J. Am. Chem. Soc., 2020, 142, 9735-9743.
[29]	M. Fleischmann, P. J. Hendra, A. J. McQuillan, Chem. Phys. Lett., 1974, 26, 163-166.
[30]	D. L. Jeanmaire, R. P. Van Duyne, J. Electroanal. Chem., 1977, 84, 1-20.
[31]	M. Moskovits, J. Chem. Phys., 1978, 69, 4159-4161.
[32]	S. Nie, S. R. Emory, Science, 1997, 275, 1102-1106.
[33]	K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, M. S. Feld, Phys. Rev. Lett., 1997, 78, 1667-1670.
[34]	A. B. Zrimsek, N. Chiang, M. Mattei, S. Zaleski, M. O. McAnally, C. T. Chapman, A.-I. Henry, G. C. Schatz, R. P. Van Duyne, Chem. Rev., 2017, 117, 7583-7613.
[35]	J.-F. Li, Y.-J. Zhang, S.-Y. Ding, R. Panneerselvam, Z.-Q. Tian, Chem. Rev., 2017, 117, 5002-5069.
[36]	S. Y. Ding, E. M. You, Z. Q. Tian, M. Moskovits, Chem. Soc. Rev., 2017, 46, 4042-4076.
[37]	S.-Y. Ding, J. Yi, J.-F. Li, B. Ren, D.-Y. Wu, R. Panneerselvam, Z.-Q. Tian, Nat. Rev. Mater., 2016, 1, 16021.
[38]	X. Wang, G. Liu, R. Hu, M. Cao, S. Yan, Y. Bao, B. Ren, in: Principles and Clinical Diagnostic Applications of Surface-Enhanced Raman Spectroscopy, Y. Wang Eds., Elsevier, Netherlands, 2022, 1-32.
[39]	X. Wang, S.-C. Huang, S. Hu, S. Yan, B. Ren, Nat. Rev. Phys., 2020, 2, 253-271.
[40]	Z.-Q. Tian, B. Ren, J.-F. Li, Z.-L. Yang, Chem. Commun., 2007, 3514-3534.
[41]	J. F. Li, Y. F. Huang, Y. Ding, Z. L. Yang, S. B. Li, X. S. Zhou, F. R. Fan, W. Zhang, Z. Y. Zhou, D. Y. Wu, B. Ren, Z. L. Wang, Z. Q. Tian, Nature, 2010, 464, 392-395.
[42]	D. Y. Wu, J. F. Li, B. Ren, Z. Q. Tian, Chem. Soc. Rev., 2008, 37, 1025-41.
[43]	H.-S. Su, H.-S. Feng, X. Wu, J.-J. Sun, B. Ren, Nanoscale, 2021, 13, 13962-13975.
[44]	T. Hartman, R. G. Geitenbeek, G. T. Whiting, B. M. Weckhuysen, Nat. Catal., 2019, 2, 986-996.
[45]	Y.-F. Huang, P. J. Kooyman, M. T. M. Koper, Nat. Commun., 2016, 7, 12440.
[46]	Y.-H. Wang, S. Zheng, W.-M. Yang, R.-Y. Zhou, Q.-F. He, P. Radjenovic, J.-C. Dong, S. Li, J. Zheng, Z.-L. Yang, G. Attard, F. Pan, Z.-Q. Tian, J.-F. Li, Nature, 2021, 600, 81-85.
[47]	H.-S. Su, X.-G. Zhang, J.-J. Sun, X. Jin, D.-Y. Wu, X.-B. Lian, J.-H. Zhong, B. Ren, Angew. Chem. Int. Ed., 2018, 57, 13177-13181.
[48]	Y.-H. Wang, M.-M. Liang, Y.-J. Zhang, S. Chen, P. Radjenovic, H. Zhang, Z.-L. Yang, X.-S. Zhou, Z.-Q. Tian, J.-F. Li, Angew. Chem. Int. Ed., 2018, 57, 11257-11261.
[49]	Y. J. Zhang, P. M. Radjenovic, X. S. Zhou, H. Zhang, J. L. Yao, J. F. Li, Adv. Mater., 2021, 33, 2005900.
[50]	X.-G. Zhang, S. Feng, C. Zhan, D.-Y. Wu, Y. Zhao, Z.-Q. Tian, J. Phys. Chem. Lett., 2020, 11, 6593-6599.
[51]	J. F. Li, X. D. Tian, S. B. Li, J. R. Anema, Z. L. Yang, Y. Ding, Y. F. Wu, Y. M. Zeng, Q. Z. Chen, B. Ren, Z. L. Wang, Z. Q. Tian, Nat. Protoc., 2013, 8, 52-65.
[52]	M. Milosevic, in: Internal Reflection and ATR Spectroscopy, John Wiley & Sons, New Jersey, 2012, 55-60.
[53]	M. Osawa, in: Near-Field Optics and Surface Plasmon Polaritons, S. Kawata Eds., Springer Berlin Heidelberg: Berlin, Heidelberg, 2001, 163-187.
[54]	M. Dunwell, Q. Lu, J. M. Heyes, J. Rosen, J. G. Chen, Y. Yan, F. Jiao, B. Xu, J. Am. Chem. Soc., 2017, 139, 3774-3783.
[55]	K. Yang, R. Kas, W. A. Smith, J. Am. Chem. Soc., 2019, 141, 15891-15900.
[56]	F. Faisal, C. Stumm, M. Bertram, F. Waidhas, Y. Lykhach, S. Cherevko, F. Xiang, M. Ammon, M. Vorokhta, B. Šmíd, T. Skála, N. Tsud, A. Neitzel, K. Beranová, K. C. Prince, S. Geiger, O. Kasian, T. Wähler, R. Schuster, M. A. Schneider, V. Matolín, K. J. J. Mayrhofer, O. Brummel, J. Libuda, Nat. Mater., 2018, 17, 592-598.
[57]	Y. Yao, L. Chen, X. Mao, Y. Yang, J. Chen, L. Zhou, J. Phys. Chem. C, 2021, 125, 8606-8619.
[58]	S. Sadhu, T. Buffeteau, S. Sandrez, L. Hirsch, D. M. Bassani, J. Am. Chem. Soc., 2020, 142, 10431-10437.
[59]	A. Hartstein, J. R. Kirtley, J. C. Tsang, Phys. Rev. Lett., 1980, 45, 201-204.
[60]	M. Moskovits, J. Chem. Phys., 1982, 77, 4408-4416.
[61]	W.-B. Cai, T. Amano, M. Osawa, J. Electroanal. Chem., 2001, 500, 147-155.
[62]	J.-J. Sun, H.-S. Su, H.-L. Yue, S.-C. Huang, T.-X. Huang, S. Hu, M. M. Sartin, J. Cheng, B. Ren, J. Phys. Chem. Lett., 2019, 10, 2306-2312.
[63]	E. Stavitski, B. M. Weckhuysen, Chem. Soc. Rev., 2010, 39, 4615-4625.
[64]	H.-F. Wang, Y.-G. Yan, S.-J. Huo, W.-B. Cai, Q.-J. Xu, M. Osawa, Electrochim. Acta, 2007, 52, 5950-5957.
[65]	H. Miyake, S. Ye, M. Osawa, Electrochem. Commun., 2002, 4, 973-977.
[66]	S.-J. Huo, X.-K. Xue, Q.-X. Li, S.-F. Xu, W.-B. Cai, J. Phys. Chem. B, 2006, 110, 25721-25728.
[67]	A. Rodes, J. M. Orts, J. M. Pérez, J. M. Feliu, A. Aldaz, Electrochem. Commun., 2003, 5, 56-60.
[68]	Yan Q.-X., Li S.-J., Huo M,. Ma W.-B., Cai, M. Osawa, J. Phys. Chem. B, 2005, 109, 7900-7906.
[69]	S. Pronkin, T. Wandlowski, Surf. Sci., 2004, 573, 109-127.
[70]	K.-i. Ataka, T. Yotsuyanagi, M. Osawa, J. Phys. Chem., 1996, 100, 10664-10672.
[71]	M. F. Delley, E. M. Nichols, J. M. Mayer, J. Am. Chem. Soc., 2021, 143, 10778-10792.
[72]	Y.-G. Yan, B.-B. Huang, J.-Y. Wang, H.-F. Wang, W.-B. Cai, J. Catal., 2007, 249, 311-317.
[73]	C. Tang, L. Chen, H. Li, L. Li, Y. Jiao, Y. Zheng, H. Xu, K. Davey, S.-Z. Qiao, J. Am. Chem. Soc., 2021, 143, 7819-7827.
[74]	X. Chang, S. Vijay, Y. Zhao, N. J. Oliveira, K. Chan, B. Xu, Nat. Commun., 2022, 13, 2656.
[75]	M. Dunwell, X. Yang, B. P. Setzler, J. Anibal, Y. Yan, B. Xu, ACS Catal., 2018, 8, 3999-4008.
[76]	A. S. Malkani, J. Anibal, B. Xu, ACS Catal., 2020, 10, 14871-14876.
[77]	X. Wang, P. Ou, A. Ozden, S.-F. Hung, J. Tam, C. M. Gabardo, J. Y. Howe, J. Sisler, K. Bertens, F. P. García de Arquer, R. K. Miao, C. P. O’Brien, Z. Wang, J. Abed, A. S. Rasouli, M. Sun, A. H. Ip, D. Sinton, E. H. Sargent, Nat. Energy, 2022, 7, 170-176.
[78]	T. A. Morhart, B. Unni, M. J. Lardner, I. J. Burgess, Anal. Chem., 2017, 89, 11818-11824.
[79]	X.-Y. Ma, C. Ding, H. Li, K. Jiang, S. Duan, W.-B. Cai, J. Phys. Chem. Lett., 2020, 11, 8727-8734.
[80]	C. Lang, J. Li, K. R. Yang, Y. Wang, D. He, J. E. Thorne, S. Croslow, Q. Dong, Y. Zhao, G. Prostko, G. W. Brudvig, V. S. Batista, M. M. Waegele, D. Wang, Chem, 2021, 7, 2101-2117.
[81]	M. Osawa, in: Compendium of Surface and Interface Analysis, The Surface Science Society of Japan, Eds., Springer: Singapore, 2018, 697-706.
[82]	X.-M. Lin, Y. Cui, Y.-H. Xu, B. Ren, Z.-Q. Tian, Anal. Bioanal. Chem., 2009, 394, 1729-1745.
[83]	X.-G. Zhang, X. Jin, D.-Y. Wu, Z.-Q. Tian, J. Phys. Chem. C, 2018, 122, 25447-25455.
[84]	H. Zhang, C. Wang, H.-L. Sun, G. Fu, S. Chen, Y.-J. Zhang, B.-H. Chen, J. R. Anema, Z.-L. Yang, J.-F. Li, Z.-Q. Tian, Nat. Commun., 2017, 8, 15447.
[85]	P. Z. El-Khoury, Z. D. Schultz, J. Phys. Chem. C, 2020, 124, 27267-27275.
[86]	H. Wang, K. Yao, J. A. Parkhill, Z. D. Schultz, Phys. Chem. Chem. Phys., 2017, 19, 5786-5796.
[87]	D. A. Nelson, Z. D. Schultz, J. Phys. Chem. C, 2019, 123, 20639-20648.
[88]	Z. Q. Tian, B. Ren, D. Y. Wu, J. Phys. Chem. B, 2002, 106, 9463-9483.
[89]	C.-F. Wang, Z. Cheng, B. T. O’Callahan, K. T. Crampton, M. R. Jones, P. Z. El-Khoury, J. Phys. Chem. Lett., 2020, 11, 2464-2469.
[90]	K. Ikeda, N. Fujimoto, H. Uehara, K. Uosaki, Chem. Phys. Lett., 2008, 460, 205-208.
[91]	W. Ma, S. Xie, T. Liu, Q. Fan, J. Ye, F. Sun, Z. Jiang, Q. Zhang, J. Cheng, Y. Wang, Nat. Catal., 2020, 3, 478-487.
[92]	C. S. Wondergem, T. Hartman, B. M. Weckhuysen, ACS Catal., 2019, 9, 10794-10802.
[93]	X. Chang, Y. Zhao, B. Xu, ACS Catal., 2020, 10, 13737-13747.
[94]	M. Valenti, N. P. Prasad, R. Kas, D. Bohra, M. Ma, V. Balasubramanian, L. Chu, S. Gimenez, J. Bisquert, B. Dam, W. A. Smith, ACS Catal., 2019, 9, 3527-3536.
[95]	M. Su, J. C. Dong, J. B. Le, Y. Zhao, W. M. Yang, Z. L. Yang, G. Attard, G. K. Liu, J. Cheng, Y. M. Wei, Z. Q. Tian, J. F. Li, Angew. Chem. Int. Ed., 2020, 59, 23554-23558.
[96]	C. Yang, X. Yu, S. Heißler, A. Nefedov, S. Colussi, J. Llorca, A. Trovarelli, Y. Wang, C. Wöll, Angew. Chem. Int. Ed., 2017, 56, 375-379.
[97]	C. Yang, M. Capdevila-Cortada, C. Dong, Y. Zhou, J. Wang, X. Yu, A. Nefedov, S. Heißler, N. López, W. Shen, C. Wöll, Y. Wang, J. Phys. Chem. Lett., 2020, 11, 7925-7931.
[98]	N. Bodappa, M. Su, Y. Zhao, J.-B. Le, W.-M. Yang, P. Radjenovic, J.-C. Dong, J. Cheng, Z.-Q. Tian, J.-F. Li, J. Am. Chem. Soc., 2019, 141, 12192-12196.
[99]	B. D. Smith, D. E. Irish, P. Kedzierzawski, J. Augustynski, J. Electrochem. Soc., 1997, 144, 4288-4296.
[100]	J.-H. Zhong, X. Jin, L. Meng, X. Wang, H.-S. Su, Z.-L. Yang, C. T. Williams, B. Ren, Nat. Nanotechnol., 2017, 12, 132-136.
[101]	A. Kubas, J. Noak, A. Trunschke, R. Schlögl, F. Neese, D. Maganas, Chem. Sci., 2017, 8, 6338-6353.
[102]	J. Gao, Y. Zheng, J.-M. Jehng, Y. Tang, I. E. Wachs, S. G. Podkolzin, Science, 2015, 348, 686-690.
[103]	A. Holewinski, S. Linic, J. Electrochem. Soc., 2012, 159, H864-H870.
[104]	A. Baz, S. T. Dix, A. Holewinski, S. Linic, J. Catal., 2021, 404, 864-872.
[105]	J. Resasco, F. Abild-Pedersen, C. Hahn, Z. Bao, M. T. M. Koper, T. F. Jaramillo, Nat. Catal., 2022, 5, 374-381.
[106]	M. Xiong, J. Ye, J. Shanghai Jiao Tong Univ. (Sci.), 2014, 19, 681-690.
[107]	E. Borguet, H. L. Dai, J. Chem. Phys., 1994, 101, 9080-9095.
[108]	J. M. Marr, Z. D. Schultz, J. Phys. Chem. Lett., 2013, 4, 3268-3272.
[109]	Y. Han, R. Lupitskyy, T.-M. Chou, C. M. Stafford, H. Du, S. Sukhishvili, Anal. Chem., 2011, 83, 5873-5880.
[110]	M. Erol, Y. Han, S. K. Stanley, C. M. Stafford, H. Du, S. Sukhishvili, J. Am. Chem. Soc., 2009, 131, 7480-7481.
[111]	H. Zhang, J. Wei, X.-G. Zhang, Y.-J. Zhang, P. M. Radjenovica, D.-Y. Wu, F. Pan, Z.-Q. Tian, J.-F. Li, Chem, 2020, 6, 689-702.
[112]	W. Xie, B. Walkenfort, S. Schlucker, J. Am. Chem. Soc., 2013, 135, 1657-60.
[113]	N. Kumar, B. Stephanidis, R. Zenobi, A. J. Wain, D. Roy, Nanoscale, 2015, 7, 7133-7137.
[114]	H. Robatjazi, H. Zhao, D. F. Swearer, N. J. Hogan, L. Zhou, A. Alabastri, M. J. McClain, P. Nordlander, N. J. Halas, Nat. Commun., 2017, 8, 27.
[115]	H.-S. Feng, F. Dong, H.-S. Su, M. M. Sartin, B. Ren, J. Appl. Phys., 2020, 128, 173105.
[116]	Y. Zhao, L. Du, H. Li, W. Xie, J. Chen, J. Phys. Chem. Lett., 2019, 10, 1286-1291.
[117]	D. Kurouski, A. Dazzi, R. Zenobi, A. Centrone, Chem. Soc. Rev., 2020, 49, 3315-3347.
[118]	X. Wang, S.-C. Huang, T.-X. Huang, H.-S. Su, J.-H. Zhong, Z.-C. Zeng, M.-H. Li, B. Ren, Chem. Soc. Rev., 2017, 46, 4020-4041.
[119]	M. Richard-Lacroix, Y. Zhang, Z. Dong, V. Deckert, Chem. Soc. Rev., 2017, 46, 3922-3944.
[120]	R. Zhang, Y. Zhang, Z. C. Dong, S. Jiang, C. Zhang, L. G. Chen, L. Zhang, Y. Liao, J. Aizpurua, Y. Luo, J. L. Yang, J. G. Hou, Nature, 2013, 498, 82-86.
[121]	Y. Zhang, B. Yang, A. Ghafoor, Y. Zhang, Y.-F. Zhang, R.-P. Wang, J.-L. Yang, Y. Luo, Z.-C. Dong, J. G. Hou, Natl. Sci. Rev., 2019, 6, 1169-1175.
[122]	J. Lee, K. T. Crampton, N. Tallarida, V. A. Apkarian, Nature, 2019, 568, 78-82.
[123]	J. Xu, X. Zhu, S. Tan, Y. Zhang, B. Li, Y. Tian, H. Shan, X. Cui, A. Zhao, Z. Dong, J. Yang, Y. Luo, B. Wang, J. G. Hou, Science, 2021, 371, 818-822.
[124]	F. Benz, M. K. Schmidt, A. Dreismann, R. Chikkaraddy, Y. Zhang, A. Demetriadou, C. Carnegie, H. Ohadi, B. de Nijs, R. Esteban, J. Aizpurua, J. J. Baumberg, Science, 2016, 354, 726-729.
[125]	Z. C. Zeng, S. C. Huang, D. Y. Wu, L. Y. Meng, M. H. Li, T. X. Huang, J. H. Zhong, X. Wang, Z. L. Yang, B. Ren, J. Am. Chem. Soc., 2015, 137, 11928-11931.
[126]	G. Kang, M. Yang, M. S. Mattei, G. C. Schatz, R. P. Van Duyne, Nano Lett., 2019, 19, 2106-2113.
[127]	J. H. K. Pfisterer, M. Baghernejad, G. Giuzio, K. F. Domke, Nat. Commun., 2019, 10, 5702.
[128]	S.-C. Huang, X. Wang, Q.-Q. Zhao, J.-F. Zhu, C.-W. Li, Y.-H. He, S. Hu, M. M. Sartin, S. Yan, B. Ren, Nat. Commun., 2020, 11, 4211.
[129]	Z. Chen, S. Jiang, G. Kang, D. Nguyen, G. C. Schatz, R. P. Van Duyne, J. Am. Chem. Soc., 2019, 141, 15684-15692.
[130]	S.-C. Huang, Y.-F. Bao, S.-S. Wu, T.-X. Huang, M. M. Sartin, X. Wang, B. Ren, Annu. Rev. Phys. Chem., 2021, 72, 213-234.
[131]	C. Y. Wu, W. J. Wolf, Y. Levartovsky, H. A. Bechtel, M. C. Martin, F. D. Toste, E. Gross, Nature, 2017, 541, 511-515.
[132]	T.-X. Qin, E.-M. You, J.-Y. Zhang, H.-L. Wang, K. H. L. Zhang, B.-W. Mao, Z.-Q. Tian, Nano Lett., 2022, 22, 2755-2761.
[133]	A. Dazzi, C. B. Prater, Chem. Rev., 2017, 117, 5146-5173.
[134]	A. A. Sifat, J. Jahng, E. O. Potma, Chem. Soc. Rev., 2022, 51, 4208-4222.
[135]	L. Wang, H. Wang, M. Wagner, Y. Yan, D. S. Jakob, X. G. Xu, Sci. Adv., 2017, 3, e1700255.
[136]	H. Wang, J. M. González-Fialkowski, W. Li, Q. Xie, Y. Yu, X. G. Xu, Anal. Chem., 2021, 93, 3567-3575.
[137]	M. Jin, F. Lu, M. A. Belkin, Light Sci. Appl., 2017, 6, e17096.
[138]	A. Cuesta, Curr. Opin. Electrochem., 2022, 35, 101041.
[139]	N. Kong, J. Guo, S. Chang, J. Pan, J. Wang, J. Zhou, J. Liu, H. Zhou, F. M. Pfeffer, J. Liu, C. J. Barrow, J. He, W. Yang, J. Am. Chem. Soc., 2021, 143, 9781-9790.
[140]	C. Zong, C.-J. Chen, M. Zhang, D.-Y. Wu, B. Ren, J. Am. Chem. Soc., 2015, 137, 11768-11774.
[141]	E.-M. You, Y. Chen, J. Yi, Z.-D. Meng, Q. Chen, S.-Y. Ding, H. Duan, M. Moskovits, Z.-Q. Tian, Opto-Electron. Adv., 2021, 4, 210076.
[142]	M. Okada, N. I. Smith, A. F. Palonpon, H. Endo, S. Kawata, M. Sodeoka, K. Fujita, Proc. Natl. Acad. Sci. U. S. A., 2012, 109, 28-32.
[143]	S. E. Bohndiek, A. Wagadarikar, C. L. Zavaleta, D. Van de Sompel, E. Garai, J. V. Jokerst, S. Yazdanfar, S. S. Gambhir, Proc. Natl. Acad. Sci. U. S. A., 2013, 110, 12408-12413.
[144]	Q. Ding, T. Chen, Z. Li, Z. Feng, X. Wang, Chin. J. Catal., 2021, 42, 808-816.
[145]	N. L. Gruenke, M. F. Cardinal, M. O. McAnally, R. R. Frontiera, G. C. Schatz, R. P. Van Duyne, Chem. Soc. Rev., 2016, 45, 2263-2290.
[146]	J. P. Kraack, P. Hamm, Chem. Rev., 2017, 117, 10623-10664.
[147]	Y. Yao, S. Zhu, H. Wang, H. Li, M. Shao, Angew. Chem. Int. Ed., 2020, 59, 10479-10483.
[148]	J. Wei, S.-N. Qin, J. Yang, H.-L. Ya, W.-H. Huang, H. Zhang, B. J. Hwang, Z.-Q. Tian, J.-F. Li, Angew. Chem. Int. Ed., 2021, 60, 9306-9310.
[149]	X. Chang, J. Li, H. Xiong, H. Zhang, Y. Xu, H. Xiao, Q. Lu, B. Xu, Angew. Chem. Int. Ed., 2022, 61, e202111167.
[150]	J. Li, X. Chang, H. Zhang, A. S. Malkani, M.-J. Cheng, B. Xu, Q. Lu, Nat. Commun., 2021, 12, 3264.
[151]	D. Wakerley, S. Lamaison, J. Wicks, A. Clemens, J. Feaster, D. Corral, S. A. Jaffer, A. Sarkar, M. Fontecave, E. B. Duoss, S. Baker, E. H. Sargent, T. F. Jaramillo, C. Hahn, Nat. Energy, 2022, 7, 130-143.
[152]	Y. C. Tan, W. K. Quek, B. Kim, S. Sugiarto, J. Oh, D. Kai, ACS Energy Lett., 2022, 7, 2012-2023.
[153]	H. Zhang, L. Osmieri, J. H. Park, H. T. Chung, D. A. Cullen, K. C. Neyerlin, D. J. Myers, P. Zelenay, Nat. Catal., 2022, 5, 455-462.
[154]	J. Yang, J. Xu, X. Zhang, C. Wu, T. Lin, Y. Ying, Anal. Chim. Acta, 2019, 1081, 6-17.

表面增强振动光谱在电催化领域的运用: 基本原理、挑战和展望

Surface-enhanced vibrational spectroscopies in electrocatalysis: Fundamentals, challenges, and perspectives

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 8

参考文献

相关文章 15

编辑推荐

Metrics

[1]	唐小龙, 李锋, 李方, 江燕斌, 余长林. 单原子催化剂在光催化和电催化合成过氧化氢中的研究进展[J]. 催化学报, 2023, 52(9): 79-98.
[2]	张季, 俞爱民, 孙成华. 非金属掺杂石墨烯异核双原子催化剂氮还原特性研究[J]. 催化学报, 2023, 52(9): 263-270.
[3]	胡金念, 田玲婵, 王海燕, 孟洋, 梁锦霞, 朱纯, 李隽. MXene负载3d金属单原子高效氮还原电催化剂的理论筛选[J]. 催化学报, 2023, 52(9): 252-262.
[4]	洪岩, 王琦, 阚子旺, 张禹烁, 郭晶, 李思琦, 刘松, 李斌. 电化学氮还原氨反应催化剂的最新研究进展[J]. 催化学报, 2023, 52(9): 50-78.
[5]	刘勇, 赵晓丽, 隆昶, 王晓艳, 邓邦为, 李康璐, 孙艳娟, 董帆. 原位构筑动态Cu/Ce(OH)_x界面用于高活性、高选择性和高稳定性硝酸盐还原合成氨[J]. 催化学报, 2023, 52(9): 196-206.
[6]	高晖, 张恭, 程东方, 王永涛, 赵静, 李晓芝, 杜晓伟, 赵志坚, 王拓, 张鹏, 巩金龙. 构建Cu台阶位促进电催化CO₂还原制醇类化学品的研究[J]. 催化学报, 2023, 52(9): 187-195.
[7]	邹心仪, 顾均. 酸性条件下二氧化碳高效电还原策略[J]. 催化学报, 2023, 52(9): 14-31.
[8]	周波, 石建巧, 姜一民, 肖磊, 逯宇轩, 董帆, 陈晨, 王特华, 王双印, 邹雨芹. 强化脱氢动力学实现超低电池电压和大电流密度下抗坏血酸电氧化[J]. 催化学报, 2023, 50(7): 372-380.
[9]	王元男, 王立娜, 张可新, 徐靖尧, 武倩楠, 谢周兵, 安伟, 梁宵, 邹晓新. 钙钛矿氧化物在水裂解反应中的电催化研究[J]. 催化学报, 2023, 50(7): 109-125.
[10]	周纳, 王家志, 张宁, 王志, 王恒国, 黄岗, 鲍迪, 钟海霞, 张新波. 富含缺陷的Cu@CuTCNQ复合材料增强电催化硝酸盐还原成氨[J]. 催化学报, 2023, 50(7): 324-333.
[11]	李轩, 蒋兴星, 孔艳, 孙建桔, 胡琪, 柴晓燕, 杨恒攀, 何传新. GaN/In₂O₃的界面工程用于高效电催化CO₂还原制备甲酸[J]. 催化学报, 2023, 50(7): 314-323.
[12]	Sang Eon Jun, Sungkyun Choi, Jaehyun Kim, Ki Chang Kwon, Sun Hwa Park, Ho Won Jang. 用于电化学能量转换反应的非贵金属单原子催化剂[J]. 催化学报, 2023, 50(7): 195-214.
[13]	牛青, 米林华, 陈玮, 李秋军, 钟升红, 于岩, 李留义. 基于共价有机框架的单位点光(电)催化材料的研究进展[J]. 催化学报, 2023, 50(7): 45-82.
[14]	欧阳玲, 梁杰, 罗永嵩, 郑冬冬, 孙圣钧, 刘倩, Mohamed S. Hamdy, 孙旭平, 应斌武. 电催化合成氨的研究进展[J]. 催化学报, 2023, 50(7): 6-44.
[15]	李静静, 张锋伟, 詹新雨, 郭河芳, 张涵, 昝文艳, 孙振宇, 张献明. 酞菁镍分子结构的精确设计: 优化电子和空间效应用于CO₂电还原[J]. 催化学报, 2023, 48(5): 117-126.