碳载体上银双原子与银纳米颗粒的耦合用于高效电还原氮气制氨

doi:10.1016/S1872-2067(25)64910-2

催化学报 ›› 2026, Vol. 82: 135-143.DOI: 10.1016/S1872-2067(25)64910-2

碳载体上银双原子与银纳米颗粒的耦合用于高效电还原氮气制氨

刘畅^a, 王梅^a^,^*(), 梁向明^b, 鲁统部^a^,^*()

^a天津理工大学材料科学与工程学院, 新能源材料与低碳技术研究所, 天津 300384
^b宁夏医科大学基础医学院, 宁夏银川 750004

收稿日期:2025-07-30 接受日期:2025-09-26 出版日期:2026-03-18 发布日期:2026-03-05
通讯作者: * 电子信箱: meiwang@email.tjut.edu.cn (王梅),lutongbu@tjut.edu.cn (鲁统部).
基金资助:
国家自然科学基金(22531007);国家自然科学基金(22375148);国家重点研发计划(2022YFA1502902)

Coupling silver dual atoms and nanoparticles on carbon support for efficient electroreduction N₂ to ammonia

Chang Liu^a, Mei Wang^a^,^*(), Xiangming Liang^b, Tongbu Lu^a^,^*()

^aInstitute for New Energy Materials and Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
^bSchool of Basic Medical Sciences, Ningxia Medical University, Yinchuan 750004, Ningxia, China

Received:2025-07-30 Accepted:2025-09-26 Online:2026-03-18 Published:2026-03-05
Contact: * E-mail: meiwang@email.tjut.edu.cn (M. Wang),lutongbu@tjut.edu.cn (T.-B. Lu).
Supported by:
National Natural Science Foundation of China(22531007);National Natural Science Foundation of China(22375148);National Key R&D Program of China(2022YFA1502902)

摘要/Abstract

摘要：

氨是工业与生活中的关键化学品, 可加工为硝酸、肥料等, 还能作为储氢介质, 比液态氢更易储运. 但氮气分子键能高, 活化难度大, 制约其高效利用. 工业制氨主要依赖哈伯-博施法, 该方法热力学转化效率低(约38GJ/t-NH₃), 且每产1吨氨排放约2.9吨二氧化碳, 加剧能源消耗与温室效应, 开发绿色可持续制氨技术迫在眉睫. 电催化氮气还原反应(eNRR)因反应条件温和、低碳排放、高选择性及长期成本优势, 成为潜在替代哈伯-博施法的理想方向. 在eNRR中, 贵金属银能促进氮气吸附活化、降低活化能和抑制析氢竞争反应, 且自然丰度相对较高, 极具潜力. 但当前eNRR催化剂存在选择性低、稳定性差等问题, 尤其*N₂→*NNH决速步活化能垒高, 制约该技术工业化, 因此, 研发高性能催化剂意义重大.

本文通过前驱体热解法, 实现了双原子银位点(Ag₂)和银纳米颗粒(Ag_NPs)在碳载体上的耦合, 合成了一种Ag₂-Ag_NPs@C催化剂, 并通过X射线衍射、高角环形暗场扫描透射电子显微镜和X射线光电子能谱等表征手段, 证实了Ag₂双原子位点与Ag_NPs的成功构筑. 电催化性能测试结果表明, 在0.1 mol/L Na₂SO₄电解质中该催化剂展现出优异的电催化氮气还原性能, 其氨产率高达139.9 μg h^-1 mg^-1_cat., 法拉第效率更是达到74.2%, 优于大多数已报道的电催化氮气还原催化剂, 且在循环电解30 h后, 氨产率与法拉第效率无明显下降, 表现出良好的稳定性. 为深入揭示催化剂的反应路径与活性来源, 通过原位衰减全反射表面增强红外光谱对催化过程中的中间体进行追踪分析, 与Ag_NPs@C和Ag₁-Ag_NPs@C (单原子银位点和Ag_NPs耦合)相比, 随着电位升高, Ag₂-Ag_NPs@C的氮气还原中间体的N-H摇摆振动、-NH₄⁺振动、H-N-H弯曲振动及N-H伸缩振动特征峰强度相对更高, 表明其具有更优异的eNRR催化活性; Ag_NPs与Ag₂双位点的协同作用使Ag_NPs成为优良的质子供体, 能高效地为Ag₂位点上吸附的N₂分子提供质子, 进而实现优异的eNRR制氨性能. 密度泛函理论计算和原位红外光谱分析表明, 在Ag₂-Ag_NPs@C催化剂中, 银纳米颗粒(Ag_NPs)有助于水的解离, 生成吸附态氢中间体(H*), 该中间体为吸附在Ag₂上的*N₂提供氢源, 从而促进关键中间体*NNH的形成, 该过程降低了决速步的吉布斯自由能, 显著提升了eNRR性能.

综上, 本文提出的双原子银-纳米银颗粒协同设计策略, 为eNRR催化剂研发提供新范式, 证实活性位点功能分区可突破性能瓶颈. 未来可将该策略拓展至过渡金属体系, 优化催化剂结构. 此工作推动eNRR从单一活性位点设计向多活性位点协同设计发展, 助力绿色制氨技术进步, 其思路也可为CO₂还原等多步电催化反应提供借鉴, 助力绿色催化技术发展.

关键词: 电催化氮气还原反应, 合成氨, 双原子, Ag₂-Ag_NPs@C, 协同效应

Abstract:

Electrocatalytic N₂ reduction reaction (eNRR) is a green and sustainable approach for producing ammonia. Herein, we synthesized a Ag_2-Ag_NPs@C catalyst by coupling dual-atom Ag sites (Ag₂) and Ag nanoparticle (Ag_NPs) on the carbon support, which exhibits excellent eNRR performance, with a high NH₃ yield rate of 139.9 μg h^-1 mg^-1_cat. and an outstanding Faradaic Efficiency of 74.2%, which are superior to those of most reported eNRR catalysts. Density functional thoery calculations and in-situ infrared spectroscopy analysis demonstrate that in Ag₂-Ag_NPs@C catalyst, Ag_NPs facilitate water dissociation to produce H* intermediate that supplies to adsorbed *N₂ on the Ag₂ site for promoting the formation of *NNH key intermediate, thus lowering the Gibbs free energy of rate-determining step and substantially enhancing the eNRR performance. This work opens up new avenues for developing efficient electrocatalytic nitrogen reduction catalysts via synergistic effect.

Key words: Electrocatalytic N₂ reduction reaction, NH₃ production, Dual-atoms, Ag₂-Ag_NPs@C, Synergistic effect

刘畅, 王梅, 梁向明, 鲁统部. 碳载体上银双原子与银纳米颗粒的耦合用于高效电还原氮气制氨[J]. 催化学报, 2026, 82: 135-143.

Chang Liu, Mei Wang, Xiangming Liang, Tongbu Lu. Coupling silver dual atoms and nanoparticles on carbon support for efficient electroreduction N₂ to ammonia[J]. Chinese Journal of Catalysis, 2026, 82: 135-143.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(25)64910-2

https://www.cjcatal.com/CN/Y2026/V82/I3/135

图/表 4

Fig. 1. (a) XRD pattern of Ag2-AgNPs@C. (b) HAADF-HRTEM image of Ag1-AgNPs@C. (c) HAADF-STEM image of Ag2-AgNPs@C. (d) HAADF-STEM image of Ag2-AgNPs@C. (e-g) HADDF-STEM elemental mapping images of Ag2-AgNPs@C.

Fig. 2. (a) XPS spectrum for Ag 3d of Ag2-AgNPs@C. (b) Ag K-edge XANES spectra of Ag2-AgNPs@C and reference samples. (c) FT-EXAFS curves, in which R and χ(k) denote the radial distance and the EXAFS oscillation function, respectively. (d-f) WT-EXAFS plots, in which k and (R + α) represent the electron wave vector and the interatomic distance without phase correction, respectively.

Fig. 3. (a) LSV curves of Ag2-AgNPs@C under Ar/N2. (b) Yields and FEs of Ag2-AgNPs@C at different applied potentials in 0.1 mol/L Na2SO4 solution. (c) 1H NMR spectra with 15N2 reaction. Yields and EFs of Ag1-AgNPs@C (d) and AgNPs@C (e) at different applied potentials in 0.1 mol/L Na2SO4 solution. (f) A comparison of the Yields and FEs of AgNPs@C, Ag1-AgNPs@C, and Ag2-AgNPs@C based on mg-1Ag. (g) Cycling tests of Ag2-AgNPs@C catalyst at -0.5 V vs. RHE. (h) A comparison of the Yields and FEs for Ag2-AgNPs@C with those of reported catalysts (see Table S3).

Fig. 4. The in-situ ATR-SEIRAS spectra of Ag2-AgNPs@C (a) and AgNPs@C (b) under different applied potentials with nitrogen as the feed gas. (c) Calculated free energy diagrams for N2 reduction on Ag2-AgNPs@C, Ag1-AgNPs@C, and AgNPs@C. (d) Calculated free energy diagrams for water dissociation on Ag2@C, Ag1@C, and AgNPs@C.

参考文献

[1]	V. Rosca, M. Duca, M. T. de Groot, M. T. M. Koper, Chem. Rev., 2009, 109, 2209-2244.
[2]	R. F. Service, Science, 2014, 345, 610.
[3]	N. Gruber, J. N. Galloway, Nature, 2008, 451, 293-296.
[4]	J. G. Chen, R. M. Crooks, L. C. Seefeldt, K. L. Bren, R. M. Bullock, M. Y. Darensbourg,P. L. Holland, B. Hoffman, M. J. Janik, A. K. Jones, M. G. Kanatzidis, P. King, K. M. Lancaster, S. V. Lymar, P. Pfromm, W. F. Schneider, R. R. Schrock, Science, 2018, 360, eaar6611.
[5]	D. E. Canfield, A. N. Glazer, P. G. Falkowski, Science, 2010, 330, 192-196.
[6]	H.-P. Jia, E. A. Quadrelli, Chem. Soc. Rev., 2014, 43, 547-564.
[7]	C. Tang, S.-Z. Qiao, Chem. Soc. Rev., 2019, 48, 3166-3180.
[8]	L. Wang, M. Xia, H. Wang, K. Huang, C. Qian, C. T. Maravelias, G. A. Ozin, Joule, 2018, 2, 1055-1074.
[9]	C. J. Pickett, J. Talarmin, Nature, 1985, 317, 652-653.
[10]	L. Ouyang, J. Liang, Y. Luo, D. Zheng, S. Sun, Q. Liu, M. S. Hamdy, X. Sun, B. Ying, Chin. J. Catal., 2023, 50, 6-44.
[11]	H.-L. Du, M. Chatti, R. Y. Hodgetts, P. V. Cherepanov, C. K. Nguyen, K. Matuszek, D. R. MacFarlane, A. N. Simonov, Nature, 2022, 609, 722-727.
[12]	Y. Ren, C. Yu, X. Tan, H. Huang, Q. Wei, J. Qiu, Energy Environ. Sci., 2021, 14, 1176-1193.
[13]	G. Qing, R. Ghazfar, S. T. Jackowski, F. Habibzadeh, M. M. Ashtiani, C.-P. Chen, M. R. Smith III, T. W. Hamann, Chem. Rev., 2020, 120, 5437-5516.
[14]	J. Choi, H.-L. Du, M. Chatti, B. H. R. Suryanto, A. N. Simonov, D. R. MacFarlane, Nat. Catal., 2022, 5, 382-384.
[15]	L. Li, H. Chen, L. Li, B. Li, Q. Wu, C. Cui, B. Deng, Y. Luo, Q. Liu, T. Li, F. Zhang, A. M. Asiri, Z.-S. Feng, Y. Wang, X. Sun, Chin. J. Catal., 2021, 42, 1755-1762.
[16]	S. Zhao, X. Lu, L. Wang, J. Gale, R. Amal, Adv. Mater., 2019, 31, 1805367.
[17]	W. Tong, B. Huang, P. Wang, Q. Shao, X. Huang, Natl. Sci. Rev., 2021, 8, nwaa088.
[18]	X. Wang, M. Luo, J. Lan, M. Peng, Y. Tan, Adv. Mater., 2021, 33, 2007733.
[19]	W. Tong, B. Huang, P. Wang, L. Li, Q. Shao, X. Huang, Angew. Chem. Int. Ed., 2020, 59, 2649-2653.
[20]	W. Xu, G. Fan, J. Chen, J. Li, L. Zhang, S. Zhu, X. Su, F. Cheng, J. Chen, Angew. Chem. Int. Ed., 2020, 59, 3511-3516.
[21]	D. Bao, Q. Zhang, F.-L. Meng, H.-X. Zhong, M.-M. Shi, Y. Zhang, J.-M. Yan, Q. Jiang, X.-B. Zhang, Adv. Mater., 2017, 29, 1604799.
[22]	M.-M. Shi, D. Bao, B.-R. Wulan, Y.-H. Li, Y.-F. Zhang, J.-M. Yan, Q. Jiang, Adv. Mater., 2017, 29, 1606550.
[23]	J. Zhang, Y. Ji, P. Wang, Q. Shao, Y. Li and X. Huang, Adv. Funct. Mater., 2020, 30, 1906579.
[24]	P. Wang, Y. Ji, Q. Shao, Y. Li, and X. Huang, Sci. Bull., 2020, 65, 350-358.
[25]	Q. Zhang, Y. Shen, Y. Hou, L. Yang, B. Chen, Z. Lei, W. Zhang, Electrochim. Acta, 2019, 321, 134691.
[26]	Y. Zhang, Q. Zhang, D.-X. Liu, Z. Wen, J.-X. Yao, M.-M. Shi, Y.-F. Zhu, J.-M. Yan, Q. Jiang, Appl. Catal. B Environ., 2021, 298, 120592.
[27]	Z. Geng, Y. Liu, X. Kong, P. Li, K. Li, Z. Liu, J. Du, M. Shu, R. Si, J. Zeng, Adv. Mater., 2018, 30, 1870301.
[28]	W. Peng, M. Luo, X. Xu, K. Jiang, M. Peng, D. Chen, T.-S. Chan, Y. Tan, Adv. Energy Mater., 2020, 10, 2001364.
[29]	H. K. Lee, C. S. L. Koh, Y. H. Lee, C. Liu, I. Y. Phang, X. Han, C.-K. Tsung, X.-Y. Ling, Sci. Adv., 2018, 4, eaar3208.
[30]	Q. Wang, H. Wei, P. Liu, Z. Su, X.-Q. Gong, Nano Res. Energy, 2024, 3, e9120112.
[31]	X. Fan, C. Liu, X. He, Z. Li, L. Yue, W. Zhao, J. Li, Y. Wang, T. Li, Y. Luo, D. Zheng, S. Sun, Q. Liu, L. Li, W. Chu, F. Gong, B. Tang, Y. Yao, X. Sun, Adv. Mater., 2024, 36, 2401221.
[32]	J. Yan, F. Ye, Q. Dai, X. Ma, Z. Fang, L. Dai, C. Hu, Nano Res. Energy, 2023, 2, e9120047.
[33]	S. Mou, T. Wu, J. Xie, Y. Zhang, L. Ji, H. Huang, T. Wang, Y. Luo, X. Xiong, B. Tang, X. Sun, Adv. Mater., 2019, 31, 1903499.
[34]	J. Zhang, H. Jiang, X. Zhao, Z. Liu, L. Li, W. Ding, M. Zhong, Angew. Chem. Int. Ed., 2025, 64, e202502690.
[35]	S. Chen, J. Guan, Chin. J. Catal., 2024, 66, 20-52.
[36]	L. Qi, J. Guan, Sci. Bull., 2025, 70, 1856-1871.
[37]	X. Xu, J. Guan, Mater. Sci. Eng. R Rep., 2025, 162, 100886.
[38]	L. Qi, J. Guan, Green Energy Environ., 2025, 10, 917-936.
[39]	Z. Wang, Y. Li, H. Yu, Y. Xu, H. Xue, X. Li, H. Wang, L. Wang, ChemSusChem, 2018, 11, 3480-3485.
[40]	B. H. R. Suryanto, H.-L. Du, D. Wang, J. Chen, A. N. Simonov, D. R. MacFarlane, Nat. Catal., 2019, 2, 290-296.
[41]	Q. Li, W. Li, D. Liu, Z. Ma, Y. Ye, Y. Zhang, Q. Chen, Z. Cheng, Y. Chen, R. Sa, J. Colloid Interface Sci., 2024, 668, 399-411.
[42]	W. Zhang, C. Li, Y. Cao, J.-Y. Ji, Z.-C. Li, Z. Niu, H. Gu, P. Braunstein, J.-P. Lang, Nano Res., 2024, 17, 3714-3723.
[43]	Y. Liang, D. Zhang, Y. Zhang, F. Yan, L. Sun, X. Jin, Q. Wang, L. Zheng, W. Li, Chem. Eng. J., 2025, 503, 158579.
[44]	W. Li, H. Jiang, X. Zhang, B. Lei, L. Li, H. Zhou, M. Zhong, J. Am. Chem. Soc., 2024, 146, 21968-21976.
[45]	X. Zhang, W. Li, J. Zhang, H. Zhou, M. Zhong, Chin. J. Catal., 2025, 68, 404-413.
[46]	L. Hu, Y. Guo, Y. Lu, J. Chang, X. Su, X. Zhang, T. Wei, H. Zhang, J. Feng, J. Power Sources, 2024, 607, 234621.
[47]	C. Lei, Y. Wang, Y. Hou, P. Liu, J. Yang, T. Zhang, X. Zhuang, M. Chen, B. Yang, L. Lei, C. Yuan, M. Qiu, X. Feng, Energy Environ. Sci., 2019, 12, 149-156.
[48]	J. N. Tiwari, A. M. Harzandi, M. Ha, S. Sultan, C. W. Myung, H. J. Park, D. Y. Kim, P. Thangavel, A. N. Singh, P. Sharma, S. S. Chandrasekaran, F. Salehnia, J.-W. Jang, H. S. Shin, Z. Lee, K. S. Kim, Adv. Energy Mater., 2019, 9, 1970101.
[49]	P. Liu, Z. Huang, X. Gao, X. Hong, J. Zhu, G. Wang, Y. Wu, J. Zeng, X. Zheng, Adv. Mater., 2022, 34, 2200057.
[50]	J.-M. Chen, W. Wei, X.-L. Feng, T.-B. Lu, Chem., 2007, 2, 710-719.
[51]	M. A. Hossain, J. A. Liljegren, D. Powell, K. Bowman-James, Inorg. Chem., 2004, 43, 3751-3755.
[52]	J. Chen, Y. Gao, Y. Fu, S. Pan, Nano, 2019, 14, 1950095.
[53]	S. Liu, T. Qian, M. Wang, H. Ji, X. Shen, C. Wang, C. Yan, Nat. Catal., 2021, 4, 322-331.
[54]	L. Zhang, H. Zhou, X. Yang, S. Zhang, H. Zhang, X. Yang, X. Su, J. Zhang, Z. Lin, Angew. Chem. Int. Ed., 2023, 62, e202217473.
[55]	L. Wen, X. Liu, X. Li, H. Zhang, S. Zhong, P. Zeng, S. S. A. Shab, X. Hu, W. Cai, Y. Li, Adv. Sci., 2024, 11, 2405210.
[56]	D. Chen, J. Lan, F. Xie, J. Peng, M. Peng, C. Sun, Z. Wei, S. Zhao, M. Wang, P. Liu, L. Han, Y. Tan, Chem. Eng. J., 2023, 475, 146137.
[57]	C. Kim, J.-Y. Song, C. Choi, J. P. Ha, W. Lee, Y. T. Nam, D.-M. Lee, G. Kim, I. Gereige, W.-B. Jung, H. Lee, Y. Jung, H. Jeong, H.-T. Jung, Adv. Mater., 2022, 34, 2205270.
[58]	Y. Ma, T. Yang, H. Zou, W. Zang, Z. Kou, L. Mao, Y. Feng, L. Shen, S. J. Pennycook, L. Duan, X. Li, J. Wang, Adv. Mater., 2020, 32, 2002177.
[59]	J. Chen, Y. Kang, W. Zhang, Z. Zhang, Y. Chen, Y. Yang, L Duan, Y. Li, W. Li, Angew. Chem. Int. Ed., 2022, 61, e202203022.
[60]	Y. Li, J. Li, J. Huang, J. Chen, Y. Kong, B. Yang, Z. Li, L. Lei, G. Chai, Z. Wen, L. Dai, Y. Hou, Angew. Chem. Int. Ed., 2021, 60, 9078-9085.
[61]	Y. Yang, H. Wang, X. Tan, K. Jiang, S. Zhai, Y. Li, X. Xie, N. Chen, H. Zhang, Z. Li, Adv. Funct. Mater., 2024, 34, 2403535.
[62]	B. Jiang, H. Xue, P. Wang, H. Du, Y. Kang, J. Zhao, S. Wang, W. Zhou, Z. Bian, H. Li, J. Henzie, Y. Yamauchi, J. Am. Chem. Soc., 2023, 145, 6079-6086.

碳载体上银双原子与银纳米颗粒的耦合用于高效电还原氮气制氨

Coupling silver dual atoms and nanoparticles on carbon support for efficient electroreduction N₂ to ammonia

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 4

参考文献

相关文章 15

编辑推荐

Metrics

[1]	高杰, 刘静, 王梦迪, 孙诺, 胡皓, 崔学晶, 周新, 姜鲁华. 构建锐钛矿-金红石TiO₂异质结构调控竞争吸附以缓解Ru在碱性氢氧化反应中的羟基毒化效应[J]. 催化学报, 2026, 82(3): 74-83.
[2]	马毅, 葛欢, 章勇, 简宁, 唐嘉陵, 胡宗坤, 于静, 李灿煌, 李露明, 李军山. 基于Ag与NiFe-LDH协同作用实现电催化PET碱性水解产物选择性制备甲酸盐与乙醇酸盐[J]. 催化学报, 2026, 80(1): 282-292.
[3]	时文博, 朱凯, 付小刚, 刘陈红, 原洋, 潘家梁, 张庆, 白正宇. 双位点限域策略调控Fe-N-C电子结构提升质子交换膜燃料电池氧还原性能[J]. 催化学报, 2026, 80(1): 293-303.
[4]	朱晓辉, 邢浩然, 何光裕, 肖海, 陈银娟, 李隽. 石墨二炔负载的d⁸态Fe双原子催化剂耦合-解耦自旋态转换机制研究[J]. 催化学报, 2025, 74(7): 411-424.
[5]	梁婉滢, 许光月, 傅尧. 分子筛限域铜基催化剂上糠醛的精确受限过渡态构型选择性加氢[J]. 催化学报, 2025, 74(7): 71-81.
[6]	凌云, 苏慧, 周如玉, 封清运, 郑轩, 汤儆, 李奕, 张茂升, 汪庆祥, 李剑锋. PtCuSnCo合金催化剂中邻近效应精确调控NO₃⁻吸附与脱氧实现合成氨100%法拉第效率[J]. 催化学报, 2025, 73(6): 347-357.
[7]	胡呈弘, 张悦, 张仪, 黄沁彤, 沈葵, 陈立宇, 李映伟. Sn电子调节器增强Fe位点电催化CO₂还原性能[J]. 催化学报, 2025, 72(5): 222-229.
[8]	詹钰捷, 钟承钦, 毕明莉, 梁亚飞, 祁玉基, 陈家琪, 刘家旭, 张新党, 张帅, 王业红, 王峰. 催化甲醇选择性氧化制甲醛的铁钒催化剂活性位点的识别[J]. 催化学报, 2025, 72(5): 334-343.
[9]	冯超, 邵佳新, 吴汉洋, 杨恒攀, 蔚佳莹, 胡琪, 何传新. 超高过电位诱导NiS₂深度重构显著提高HER性能[J]. 催化学报, 2025, 72(5): 230-242.
[10]	刘奕, 周树清, 牛成功, 塔伊尔詹•泰勒•伊西姆詹, 朱永法, 王定胜, 杨秀林, 邱介山, 武斌. 稀CuRu合金与Cu/Ru双单原子的协同耦合加速碱性氢氧化的Volmer动力学[J]. 催化学报, 2025, 72(5): 266-276.
[11]	李彦琴, 汪文龙, 田俊奇, 崔丹, 袁军, 方彬, 尹年良, 李泽龙, 于锋. Fe₂O₃/TiO₂催化剂高效催化NO加氢制NH₃[J]. 催化学报, 2025, 71(4): 330-339.
[12]	成雪峰, 刘青, 孙启孟, 董慧龙, 陈冬赟, 郑莹, 徐庆锋, 路建美. 相邻Ni位点近邻电子效应增强Cu位点加氢和脱氧匹配度促进硝酸盐电还原产氨[J]. 催化学报, 2025, 70(3): 285-298.
[13]	陈羲, 金伟, 钟信宇, 林虹巧, 丁俊杰, 刘欣予, 王慧, 陈法升, 熊衍, 丁长春, 金钟, 江明航. 优化Cu₂O/Cu异质结界面处活性氢产生的动力学路径用于增强硝酸盐电还原产氨[J]. 催化学报, 2025, 79(12): 78-90.
[14]	郭璞, 杨绍雪, 井会娟, 栾东, 龙军, 肖建平. 电催化硝酸盐与一氧化氮还原合成氨: 计算见解与策略选择[J]. 催化学报, 2025, 77(10): 220-226.
[15]	刘洁宇, 郭海强, 熊钰林, 陈星, 于一夫, 王长洪. 基于DFT和机器学习的Pt单原子合金电催化剂的理性设计: 应用于NO至NH₃的转化[J]. 催化学报, 2024, 62(7): 243-253.

碳载体上银双原子与银纳米颗粒的耦合用于高效电还原氮气制氨

Coupling silver dual atoms and nanoparticles on carbon support for efficient electroreduction N2 to ammonia

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 4

参考文献

相关文章 15

编辑推荐

Metrics

Coupling silver dual atoms and nanoparticles on carbon support for efficient electroreduction N₂ to ammonia