Catalytic activity of immobilized Ru nanoparticles in a porous metal-organic framework using supercritical fluid

doi:10.1016/S1872-2067(11)60475-0

Abstract

Abstract: A Zr-based metal-organic framework (Zr-MOF) with both micropores and mesopores was prepared by the reaction of 1,4-benzenedicarboxylic acid (H₂BDC) and ZrOCl₂·8H₂O with the aid of a citric acid (CA) chelating agent and a cetyltrimethylammonium bromide (CTAB) surfactant. This was followed by formation of a Ru@Zr-MOF catalyst from RuCl₃·3H₂O in a supercritical CO₂-methanol solution. The catalyst was characterized by Fourier transform infrared spectroscopy, power X-ray diffraction, transmission electron microscopy, thermo-gravimetric analysis, N₂ adsorption-desorption, X-ray photoelectron spectroscopy, and inductively coupled plasma-atomic emission spectroscopy. Ru particles with an average diameter of 2.3 nm were uniformly supported in the Zr-MOF. The catalytic performance of Ru@Zr-MOF for the hydrogenation of benzene and its derivatives was investigated and was found to be active and stable.

Key words: Metal-organic framework, Ruthenium, Supercritical fluid, Benzene and derivatives, Hydrogenation

WU Tian-Bin, ZHANG Peng, MA Jun, FAN Hong-Lei, WANG Wei-Tao, JIANG Tao, HAN Bu-Xing. Catalytic activity of immobilized Ru nanoparticles in a porous metal-organic framework using supercritical fluid[J]. Chinese Journal of Catalysis, 2013, 34(1): 167-175.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60475-0

https://www.cjcatal.com/EN/Y2013/V34/I1/167

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