Synergistic effect of hydrogen bonding mediated selective synthesis of benzaldehyde in water

doi:10.1016/S1872-2067(14)60056-5

Abstract

Abstract:

β-cyclodextrin-functionalized cellulose was prepared from cellulose and β-cyclodextrin crosslinked with epichlorohydrin. The supramolecular polymer has been used as a heterogeneous catalyst for the synthesis of benzaldehyde under mild reaction conditions with high activity and yield. The catalyst was easily recovered and reused without significant activity loss. The β-cyclodextrin in the polymer formed host-guest complexes with cinnamaldehyde via noncovalent bonding. In addition, multiple interactions were observed between β-cyclodextrin and the substrate via intermolecular O-H…O hydrogen bonding. The significant promotion for the catalytic performance could be attributed to the synergistic effects of hydrogen bonding.

Key words: β-cyclodextrin-functionalized cellulose, Hydrogen bonding, Synergistic effect, Cinnamaldehyde oxidation, Benzaldehyde

Zujin Yang, Hongbing Ji. Synergistic effect of hydrogen bonding mediated selective synthesis of benzaldehyde in water[J]. Chinese Journal of Catalysis, 2014, 35(4): 590-598.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60056-5

https://www.cjcatal.com/EN/Y2014/V35/I4/590

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