Chinese Journal of Catalysis ›› 2017, Vol. 38 ›› Issue (6): 1021-1027.DOI: 10.1016/S1872-2067(17)62811-0

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Hydrotalcite-wrapped Co-B alloy with enhanced oxygen evolution activity

Xue Lenga, Kuang-Hsu Wua, Bing-Jian Suc, Ling-Yun Jangc, Ian R. Gentleb, Da-Wei Wanga,b   

  1. a. School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane 4072, Australia;
    b. School of Chemical Engineering, University of New South Wales, Sydney, NSW 2052, Australia;
    c. Research Division, National Synchrotron Radiation Research Center, Hsinchu 300, Taiwan, China
  • Received:2017-02-08 Revised:2017-03-04 Online:2017-06-18 Published:2017-06-08
  • Supported by:

    This work was supported by the Australian Research Council Discovery Project (DP110100550)

Abstract:

Water oxidation is one of the most attractive techniques for intermittent renewable energy conversion and storage. The oxygen evolution electrocatalytic performance of an amorphous Co-B alloy and its derivatives were studied. These materials were chemically synthesized by reducing a Co salt with NaBH4. The amorphous Co-B alloy showed good electrocatalytic activity in oxygen evolution but its stability was poor. A hydrotalcite-wrapped Co-B alloy was synthesized by mild oxidation. The electrocatalytic activity of this material in the oxygen evolution reaction was better than that of a commercially available Ir/C catalyst.

Key words: Amorphous alloy, Oxygen evolution reaction, Electrocatalyst