Research Progress on Solid Superbase Catalysts in the Last Decade

doi:10.3724/SP.J.1088.2011.10206

Abstract

Abstract: This review focuses on the research progress on solid superbase catalysts in recent decade, including the type and preparation of superbases, the mechanism for basic site generation, and the application of superbases in catalysis. It is pointed out that only several kinds of superbases have been reported so far, and the majority of solid superbases are generated using metal oxides as supports. The reported superbases are very sensitive to H₂O and CO₂, and rigorous conditions are required for their preparation and utilization. As a consequence, the development and application of solid superbases are restricted. Despite the understanding of the formation mechanism of superbasic sites is essential for the design of solid superbases, reports on this aspect are few. It is necessary to develop new support materials or modifying agents to generate solid superbases of novelty. Efforts should be devoted to the study of the generation mechanism of superbasic sites by adopting advanced characterization techniques and new methods for theoretical investigation. Moreover, it can be predicted that solid superbases will find new application in catalysis, especially in reactions that require high temperatures for desorption of acidic substances from the surface of superbases.

Key words: solid superbase, calcium oxide, potassium nitride, alumina, zirconia, potassium hydroxide, calcium nitride, SBA-15 zeolite

WEI Yu-Dan, ZHANG Shu-Guo, LI Gui-Sheng, YIN Shuang-Feng, QU Ze-Tang. Research Progress on Solid Superbase Catalysts in the Last Decade[J]. Chinese Journal of Catalysis, 2011, 32(6): 891-898.

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References

1Tanabe K, Misono M, Ono Y, Hattori H. Stud Surf Sci Catal, 1989, 51: 1
2Hattori H. Appl Catal A, 2001, 222: 247
3Suzukamo G, Fukao M, Minobe M, Sakamoto A. EP 0 211 448. 1990
4王亚红, 曲小姝, 祝波, 刘立业, 崔昌亿. 化学世界 (Wang Y H, Qu X Sh, Zhu B, Liu L Y, Cui Ch Y. Chem World), 2004: 563
5丁元生, 罗志臣, 王浔, 韩笑言. 精细石油化工 (Ding Y Sh, Luo Zh Ch, Wang X, Han X Y. Speciality Petrochem), 2004, 21(1): 31
6Kijeński J, Radomski P, Fedoryńska E. J Catal, 2001, 203: 407
7Sun N J, Klabunde K J. J Catal, 1999, 185: 506.
8Gorzawski H, Hoelderich W F. J Mol Catal A, 1999, 144: 181
9魏彤, 王谋华, 魏伟, 孙予罕, 钟炳. 化学通报 (Wei T, Wang M H, Wei W, Sun Y H, Zhong B. Chemistry), 2002: 594
10Ono Y. J Catal, 2003, 216: 406
11高智勤, 江琦, 李向召. 精细石油化工 (Gao Zh Q, Jiang Q, Li X Zh. Speciality Petrochem), 2006, 23(4): 62
12肖晓明. 石油化工 (Xiao X M. Petrochem Ind), 1994, 23: 342
13林棋, 林瑜, 陈伟松. 福州师专学报 (自然科学版) (Lin Q, Lin Y, Chen W S. J Fuzhou Teachers College (Natur Sci Ed)), 1998, 18: 43
14袁传敏, 王亚明. 云南化工 (Yuan Ch M, Wang Y M. Yunnan Chem Technol), 2000, 27(2): 20
15朱华平, 吴宗斌, 陈元雄, 张萍, 段世杰, 刘晓华, 毛宗强. 催化学报 (Zhu H P, Wu Z B, Chen Y X, Zhang P, Duan Sh J, Liu X H, Mao Z Q. Chin J Catal), 2006, 27: 391
16Wang Y, Zhu J H, Huang W Y. Phys Chem Chem Phys, 2001, 3: 2537
17Sun L B, Yang J, Kou J H, Gu F N, Chun Y, Wang Y, Zhu J H, Zou Z G. Angew Chem, Int Ed, 2008, 47: 3418
18Li X, Lu G Z, Guo Y L, Guo Y, Wang Y Q, Zhang Z G, Liu X H, Wang Y S. Catal Commun, 2007, 8: 1969
19Kabashima H, Tsuji H, Nakatab S, Tanaka Y, Hattori H. Appl Catal A, 2000, 194-195: 227
20Bota R M, Houthoofd K, Grobet P J, Jacobs P A. Catal Today, 2010, 152: 99
21Wang Y, Huang W Y, Wu Z, Chun Y, Zhu J H. Mater Lett, 2000, 46: 198
22Wang Y, Huang W Y, Chun Y, Xia J R, Zhu J H. Chem Mater, 2001, 13: 670
23王英, 朱建华, 淳远, 吴振, 何永刚. 石油学报 (石油加工) (Wang Y, Zhu J H, Chun Y, Wu Zh, He Y G. Acta Petrol Sin (Petrol Process Sect)), 2000, 16: 1
24Kaskel S, Schlichte K. J Catal, 2001, 201: 270
25Wu Z Y, Jiang Q, Wang Y M, Wang H J, Sun L B, Shi L Y, Xu J H, Wang Y, Chun Y, Zhu J H. Chem Mater, 2006, 18: 4600
26Sun Y H, Sun L B, Li T T, Liu X Q. J Phys Chem C, 2010, 114: 18988
27Sun L B, Kou J H, Chun Y, Yang J, Gu F N, Wang Y, Zhu J H, Zou Z G. Inorg Chem, 2008, 47: 4199
28Zahouilya M, Mounira B, Rayadha A, Bahlaouib M A, Sebtic S. Arabian J Chem, 2008, 1: 145
29Yin S F, Xu B Q, Wang S J, Au C T. Appl Catal A, 2006, 301: 202
30Zhang S G, Wei Y D, Yin S F, Au C T. Catal Commun, 2011, 12: 12
31Matsuhashi H, Oikawa M, Arata K. Langmuir, 2000, 16: 8201
32Gorzawski H, Hoelderich W F. Appl Catal A, 1999, 179: 131
33Zhu J H, Wang Y, Chun Y, Wang X S. J Chem Soc, Faraday Trans, 1998, 94: 1163
34Wang Y, Ji A, Han X W, Huang W Y, Liu J, Zhou Z P. Stud Surf Sci Catal, 2004, 154: 2899
35Zhu J H, Chun Y, Wang Y, Xu Q H. Mater Lett, 1997, 33: 207
36Baba T, Handa H, Ono Y. J Chem Soc, Faraday Trans, 1994, 90: 187
37Meyer U, Gorzawski H, Hölderich W F. Catal Lett, 1999, 59: 201
38Kabashima H, Tsuji H, Shibuya T, Hattori H. J Mol Catal A, 2000, 155: 23.
39周玉杰, 张建安, 武海棠, 刘宏娟, 程可可, 戴玲妹, 刘德华, 刘建. 化学工程 (Zhou Y J, Zhang J A, Wu H T, Liu H J, Cheng K K, Dai L M, Liu D H, Liu J. Chem Eng (China)), 2009, 37(7): 59
40Ma H B, Li S F, Wang B Y, Wang R H, Tian S J. J Am Oil Chem Soc, 2008, 85: 263
41刘洪润, 顾珊珊, 李修刚, 高根之. 化学试剂 (Liu H R, Gu Sh Sh, Li X G, Gao G Zh. Chem Reagents), 2009, 31: 55
42Handa H, Baba T, Sugisawa H, Ono Y. J Mol Catal A, 1998, 134: 171

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