Hydrogenolysis of Glycerol to 1,2-Propanediol over Ru/TiO2 Catalyst

doi:10.3724/SP.J.1088.2011.10534

Abstract

Abstract: The supported Ru/TiO₂ catalyst was prepared by the impregnation method. The physicochemical properties of the catalyst were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy, N₂ adsorption, and inductively coupled plasma-atomic emission spectroscopy. The effects of reaction temperature, hydrogen pressure, glycerol concentration, catalyst amount, and base additives on the catalytic performance of Ru/TiO₂ in the glycerol hydrogenolysis reaction were investigated. Under mild reaction conditions (170 ^oC, 3 MPa), using LiOH as additive, the conversion of glycerol and the selectivity for 1,2-propanediol were as high as 89.6% and 86.8%, respectively.

Key words: ruthenium, titania, glycerol, hydrogenolysis, 1,2-propanediol

FENG Jian, XIONG Wei, JIA Yun, WANG Jin-Bo, LIU De-Rong, CHEN Hua, LI Xian-Jun. Hydrogenolysis of Glycerol to 1,2-Propanediol over Ru/TiO2 Catalyst[J]. Chinese Journal of Catalysis, 2011, 32(9): 1545-1549.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.3724/SP.J.1088.2011.10534

https://www.cjcatal.com/EN/Y2011/V32/I9/1545

References

1 闵恩泽. 化学进展 (Min E Z. Progr Chem), 2006, 18: 131

2 冯建, 袁茂林, 陈华, 李贤均. 化学进展 (Feng J, Yuan M L, Chen H, Li X J. Progr Chem), 2007, 19: 651

3 Feng J, Wang J B, Zhou Y F, Fu H Y, Chen H, Li X J. Chem Lett, 2007, 36: 1274

4 Feng J, Fu H Y, Wang J B, Li R X, Chen H, Li X J. Catal Commun, 2008, 9: 1458

5 Miyazawa T, Kusunoki Y, Kunimori K, Tomishige K. J Catal, 2006, 240: 213

6 Miyazawa T, Koso S, Kunimori K, Tomishige K. Appl Catal A, 2007, 329: 30

7 马兰, 贺德华. 催化学报 (Ma L, He D H. Chin J Catal), 2009, 30: 471

8 Ma L, He D H. Catal Today, 2010, 149: 148

9 Wang J, Shen S H, Li B D, Lin H Q, Yuan Y Z. Chem Lett, 2009, 38: 572

10 Balaraju M, Rekha V, Prabhavathi-Devi B L A, Prasad R B N, Sai-Prasad P S, Lingaiah N. Appl Catal A, 2010, 384: 107

11 龚磊峰, 吕元, 丁云杰, 林荣和, 李经伟, 董文达, 王涛, 陈维苗. 催化学报 (Gong L F, Lü Y, Ding Y J, Lin R H, Li J W, Dong W D, Wang T, Chen W M. Chin J Catal), 2009, 30: 1189

12 Gandarias I, Arias P L, Requies J, Güemez M B, Fierro J L G. Appl Catal B, 2010, 97: 248

13 Wang S, Zhang Y C, Liu H C. Chem Asian J, 2010, 5: 1100

14 Huang Z W, Cui F, Kang H X, Chen J, Zhang X Z, Xia C G. Chem Mater, 2008, 20: 5090

15 左建良, 黄志威, 崔芳, 陈静, 夏春谷. 分子催化 (Zuo J L, Huang Zh W, Cui F, Chen J, Xia Ch G. J Mol Catal (China)), 2010, 24: 195

16 Huang L, Zhu Y L, Zheng H Y, Ding G Q, Li Y W. Catal Lett, 2009, 131: 312

17 Yuan Z L, Wang J H, Wang L N, Xie W H, Chen P, Hou Z Y, Zheng X M. Bioresour Technol, 2010, 101: 7088

18 Vasiliadou E S, Lemonidou A A. Appl Catal A, 2011, 396: 177

19 Perosa A, Tundo P. Ind Eng Chem Res, 2005, 44: 8535

20 Yin A Y, Guo X Y, Dai W L, Fan K N. Green Chem, 2009, 11: 1514

21 Yu W Q, Xu J, Ma H, Chen C, Zhao J, Miao H, Song Q. Catal Commun, 2010, 11: 493

22 Zhao J, Yu W Q, Chen C, Miao H, Ma H, Xu J. Catal Lett, 2010, 134: 184

23 Lahr D G, Shanks B H. Ind Eng Chem Res, 2003, 42: 5467

24 Dasari M A. [PhD Dissertation]. Missouri: University of Missouri-Columbia, 2006

25 Balaraju M, Rekha V, Sai-Prasad P S, Prabhavathi-Devi B L A, Prasad R B N, Lingaiah N. Appl Catal A, 2009, 354: 82

26 Bolado S, Treviño R E, García-Cubero M T, González- Benito G. Catal Commun, 2010, 12: 122

27 Maris E P, Davis R J. J Catal, 2007, 249: 328

[1]	Kai Shi, Di Si, Xue Teng, Lisong Chen, Jianlin Shi. Enhanced electrocatalytic glycerol oxidation on CuCoN_0.6/CP at significantly reduced potentials [J]. Chinese Journal of Catalysis, 2023, 53(10): 143-152.
[2]	Qing Yao, Jiabo Le, Shize Yang, Jun Cheng, Qi Shao, Xiaoqing Huang. A trace of Pt can significantly boost RuO₂ for acidic water splitting [J]. Chinese Journal of Catalysis, 2022, 43(6): 1493-1501.
[3]	Yu Ding, Kai-Wen Cao, Jia-Wei He, Fu-Min Li, Hao Huang, Pei Chen, Yu Chen. Nitrogen-doped graphene aerogel-supported ruthenium nanocrystals for pH-universal hydrogen evolution reaction [J]. Chinese Journal of Catalysis, 2022, 43(6): 1535-1543.
[4]	Jianxiang Wu, Xuejing Yang, Ming Gong. Recent advances in glycerol valorization via electrooxidation: Catalyst, mechanism and device [J]. Chinese Journal of Catalysis, 2022, 43(12): 2966-2986.
[5]	Rui Huang, Yunzhou Wen, Huisheng Peng, Bo Zhang. Improved kinetics of OER on Ru-Pb binary electrocatalyst by decoupling proton-electron transfer [J]. Chinese Journal of Catalysis, 2022, 43(1): 130-138.
[6]	Fangjun Shao, Zihao Yao, Yijing Gao, Qiang Zhou, Zhikang Bao, Guilin Zhuang, Xing Zhong, Chuan Wu, Zhongzhe Wei, Jianguo Wang. Geometric and electronic effects on the performance of a bifunctional Ru₂P catalyst in the hydrogenation and acceptorless dehydrogenation of N-heteroarenes [J]. Chinese Journal of Catalysis, 2021, 42(7): 1185-1194.
[7]	Dawang Chu, Yingying Xin, Chen Zhao. Production of bio-ethanol by consecutive hydrogenolysis of corn-stalk cellulose [J]. Chinese Journal of Catalysis, 2021, 42(5): 844-854.
[8]	Steffen Cychy, Sebastian Lechler, Zijian Huang, Michael Braun, Ann Cathrin Brix, Peter Blümler, Corina Andronescu, Friederike Schmid, Wolfgang Schuhmann, Martin Muhler. Optimizing the nickel boride layer thickness in a spectroelectrochemical ATR-FTIR thin-film flow cell applied in glycerol oxidation [J]. Chinese Journal of Catalysis, 2021, 42(12): 2206-2215.
[9]	Yuanyuan Jiang, Ruru Zhou, Huaiyuan Zhao, Boyong Ye, Yihua Long, Zhengbao Wang, Zhaoyin Hou. A highly active and stable organic-inorganic combined solid acid for the transesterification of glycerol under mild conditions [J]. Chinese Journal of Catalysis, 2021, 42(10): 1772-1781.
[10]	Jia Wang, Man Yang, Aiqin Wang. Selective hydrogenolysis of glycerol to 1,3-propanediol over Pt-W based catalysts [J]. Chinese Journal of Catalysis, 2020, 41(9): 1311-1319.
[11]	Yizhi Wen, Tao Yang, Chuanqi Cheng, Xueru Zhao, Enzuo Liu, Jing Yang. Engineering Ru(IV) charge density in Ru@RuO₂ core-shell electrocatalyst via tensile strain for efficient oxygen evolution in acidic media [J]. Chinese Journal of Catalysis, 2020, 41(8): 1161-1167.
[12]	Nian Lei, Zhili Miao, Fei Liu, Hua Wang, Xiaoli Pan, Aiqin Wang, Tao Zhang. Understanding the deactivation behavior of Pt/WO₃/Al₂O₃ catalyst in the glycerol hydrogenolysis reaction [J]. Chinese Journal of Catalysis, 2020, 41(8): 1261-1267.
[13]	Juhong Lian, Yuchao Chai, Yu Qi, Xiangyang Guo, Naijia Guan, Landong Li, Fuxiang Zhang. Unexpectedly selective hydrogenation of phenylacetylene to styrene on titania supported platinum photocatalyst under 385 nm monochromatic light irradiation [J]. Chinese Journal of Catalysis, 2020, 41(4): 598-603.
[14]	Lihua Yang, Tianqu He, Chujun Lai, Ping Chen, Zhaoyin Hou. Selective oxidation of glycerol with oxygen in base-free solution over N-doped-carbon-supported Sb@PtSb₂ hybrid [J]. Chinese Journal of Catalysis, 2020, 41(3): 494-502.
[15]	Xiaolong Wang, Guojun Lan, Zaizhe Cheng, Wenfeng Han, Haodong Tang, Huazhang Liu, Ying Li. Carbon-supported ruthenium catalysts prepared by a coordination strategy for acetylene hydrochlorination [J]. Chinese Journal of Catalysis, 2020, 41(11): 1683-1691.