Periodic Mesoporous Organogold(I)silica Catalysts for Hydration of Alkyne to Methyl Ketone in Water Medium

doi:10.3724/SP.J.1088.2012.20131

Abstract

Abstract: A novel periodic mesoporous Au(I) organometalsilica as an active and reusable catalyst for alkyne hydration reaction was synthesized by co-condensation of phenyl silane and organometal bridged silane. Compared with the Au-PPh₂-PMO(Ph)-G prepared by the grafting method, the Au-PPh₂-PMO(Ph) catalyst showed high dispersion of Au(I) active sites, straightway mesopore channels, and the reduced diffusion limit. During the hydration of terminal alkynes, the Au-PPh₂-PMO(Ph) catalyst not only exhibited higher catalytic efficiency than the un-immobilized Au(PPh₃)Cl catalyst but also could be used repetitively, showing good potential in industrial application.

Key words: heterogenized organometallic catalyst, gold, peroidic organogold(I)silica, phenyl-functionalization, alkyne hydration reaction, water medium

ZHU Feng-Xia, ZHOU Jian-Feng, ZHU Hui-Qin, LI He-Xing. Periodic Mesoporous Organogold(I)silica Catalysts for Hydration of Alkyne to Methyl Ketone in Water Medium[J]. Chinese Journal of Catalysis, 2012, 33(6): 1061-1066.

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URL: https://www.cjcatal.com/EN/10.3724/SP.J.1088.2012.20131

https://www.cjcatal.com/EN/Y2012/V33/I6/1061

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