Effect of H2S pre-treatment on structure and activity of Ni2P/SiO2 catalyst for hydrodechlorination of chlorobenzene

doi:10.1016/S1872-2067(12)60595-6

Abstract

Abstract:

The effect of 10% H₂S/H₂ treatment on the structure of Ni₂P/SiO₂ and its activity for the hydrodechlorination of chlorobenzene was investigated using X-ray diffraction, inductively coupled plasma atomic emission spectroscopy, X-ray photoelectron spectroscopy, CO chemisorption, H₂ temperature-programmed desorption, NH₃ temperature-programmed desorption, and activity tests. The H₂S/H₂ treatment did not change the Ni₂P phase or crystallite size even at temperatures as high as 873 K. However, S species were incorporated in the surface of the Ni₂P crystallites to form surface phosphosulfide (NiP_xS_y) species, which blocked the Ni sites and induced their further electron-deficiency. H₂S/H₂ treatment also led to an increase of spilt-over hydrogen species. The treated Ni₂P/SiO₂ catalyst had higher turnover frequencies in the hydrodechlorination of chlorobenzene than the untreated catalyst. This was ascribed to the increased electron-deficiency of Ni site and a greater amount of spilt-over hydrogen species.

Key words: Nickel phosphide, Hydrogen sulfide, Electron structure, Spilt-over hydrogen, Chlorobenzene, Hydrodechlorination

YANG Qing, DAI Jicai, LI Kelun, CHEN Jixiang. Effect of H₂S pre-treatment on structure and activity of Ni₂P/SiO₂ catalyst for hydrodechlorination of chlorobenzene[J]. Chinese Journal of Catalysis, 2013, 34(6): 1201-1207.

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Effect of H₂S pre-treatment on structure and activity of Ni₂P/SiO₂ catalyst for hydrodechlorination of chlorobenzene

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