Oxidation of dibenzothiophene using oxygen and a vanadophosphate catalyst for ultra-deep desulfurization of diesels

doi:10.1016/S1872-2067(14)60194-7

Chinese Journal of Catalysis ›› 2014, Vol. 35 ›› Issue (9): 1433-1437.DOI: 10.1016/S1872-2067(14)60194-7

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Oxidation of dibenzothiophene using oxygen and a vanadophosphate catalyst for ultra-deep desulfurization of diesels

Nanfang Tang^a,b, Xiaoping Zhao^c, Zongxuan Jiang^a, Can Li^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c Shaanxi Yanchang Petroleum (Group) Co., Ltd., Xi'an 710075, Shaanxi, China

Received:2014-05-30 Revised:2014-07-18 Online:2014-08-19 Published:2014-08-22
Supported by:
This work was supported by the National Natural Science Foundation of China (21173214).

Abstract

Abstract:

A bicapped Keggin structure vanadophosphate showed high catalytic activity in the oxidation of dibenzothiophene (DBT) to sulfone using molecular oxygen as oxidant under mild reaction conditions. This is a promising approach to the ultra-deep desulfurization of fuels (e.g. diesel) as sulfones can be removed from the fuel by extraction or selective adsorption.

Key words: Oxidative desulfurization, Molecular oxygen, Vanadophosphate, Dibenzothiophene

Nanfang Tang, Xiaoping Zhao, Zongxuan Jiang, Can Li. Oxidation of dibenzothiophene using oxygen and a vanadophosphate catalyst for ultra-deep desulfurization of diesels[J]. Chinese Journal of Catalysis, 2014, 35(9): 1433-1437.

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Oxidation of dibenzothiophene using oxygen and a vanadophosphate catalyst for ultra-deep desulfurization of diesels

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