Synthesis of the Novel Ligand Tris-(3,4-dimethoxylphenyl)phosphine and Its Catalytic Performance in 1-Dodecene Hydroformylation

doi:10.1016/S1872-2067(10)60105-2

Chinese Journal of Catalysis ›› 2010, Vol. 31 ›› Issue (9): 1093-1097.DOI: 10.1016/S1872-2067(10)60105-2

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Synthesis of the Novel Ligand Tris-(3,4-dimethoxylphenyl)phosphine and Its Catalytic Performance in 1-Dodecene Hydroformylation

YUAN Maolin, FU Haiyan, LI Ruixiang, CHEN Hua*, LI Xianjun

College of Chemistry, Sichuan University, Key Laboratory of Green Chemistry and Technology of Ministry of Education, Chengdu 610064, Sichuan, China

Received:2010-09-30 Online:2010-09-30 Published:2014-01-25

Abstract

Abstract: Tris-(3,4-dimethoxylphenyl)phosphine (TDMOPP) was synthesized and used as a ligand for the homogenous hydroformylation of 1-dodecene. The effects of the P/Rh molar ratio and reaction temperature on the activity and regioselectivity were investigated. The results showed that the activity of TDMOPP was about two times higher than that of the traditional triphenylphosphine at a low P/Rh and tempera-ture.

Key words: tris-(3,4-dimethoxylphenyl)phosphine, rhodium complex, 1-dodecene, hydroformylation

YUAN Maolin, FU Haiyan, LI Ruixiang, CHEN Hua*, LI Xianjun. Synthesis of the Novel Ligand Tris-(3,4-dimethoxylphenyl)phosphine and Its Catalytic Performance in 1-Dodecene Hydroformylation[J]. Chinese Journal of Catalysis, 2010, 31(9): 1093-1097.

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Synthesis of the Novel Ligand Tris-(3,4-dimethoxylphenyl)phosphine and Its Catalytic Performance in 1-Dodecene Hydroformylation

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