Preparation of Nickel Phosphide/Mesoporous-TiO2 Catalyst and Its Hydrodesulfurization Performance

doi:10.1016/S1872-2067(11)60358-6

Abstract

Abstract: Using mesoporous TiO₂ (m-TiO₂) as the support, novel nickel phosphide/m-TiO₂ catalysts (Ni₂P/m-TiO₂) were prepared by a temperature-programmed reduction method. The influence of the Ni/P molar ratio and the amount of active component on the catalyst structure and the hydrodesulfurization (HDS) performance was investigated. The results indicated that the reduction of precursor with Ni/P = 1.25 yielded mainly Ni₂P, and the optimum loading of Ni was 10%. The influence of m-TiO₂ on the preparation and HDS performance of nickel phosphide catalysts was also evaluated by X-ray diffraction, N₂ physisorption, field-emission scanning electron microscopy, and temperature-programmed reduction. The results showed that m-TiO₂ with high crystallinity could dramatically decrease the reduction temperatures of Ni and P species. When the reduction temperatures were between 450 and 600°C, the textures of the Ni₂P/m-TiO₂ catalysts were very similar and the specific surface areas were about 90 m²/g. The effects of the support on the dibenzothiophene HDS performance of the nickel phosphide catalysts were also investigated. The results showed that the order of dibenzothiophene conversion was Ni₂P/m-TiO₂> Ni₂P/SiO₂> Ni₂P/P25.

Key words: mesoporous, titania, nickel phosphide, hydrodesulfuriztion, dibenzothiophene

YANG Zhu-Hong, LI Li-Cheng, WANG Yan-Fang, LIU Jin-Long, FENG Xin, LU Xiao-Hua. Preparation of Nickel Phosphide/Mesoporous-TiO₂Catalyst and Its Hydrodesulfurization Performance[J]. Chinese Journal of Catalysis, 2012, 33(3): 508-517.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60358-6

https://www.cjcatal.com/EN/Y2012/V33/I3/508

References

1 Oyama S T. J Catal, 2003, 216: 343
2 Nedeljkovic J M, Micic O I, Ahrenkiel S P, Miedaner A, Nozik A J. J Am Chem Soc, 2004, 126: 2632
3 Kashkarov P K, Obraztsov A N, Sorokin I N, Sosnovskikh Y N. Inorg Mater, 1986, 22: 1407
4 Hu X L, Yu J C. Chem Mater, 2008, 20: 6743
5 Phillips D C, Sawhill S J, Self R, Bussell M E. J Catal, 2002, 207: 266
6 Wang X Q, Clark P A, Oyama S T. J Catal, 2002, 208: 321
7 Clark P A, Oyama S T. J Catal, 2003, 218: 78
8 黄晓凡, 季生福, 吴平易, 刘倩倩, 刘辉, 朱吉钦, 李成岳. 物理化学学报 (Huang X F, Ji Sh F, Wu P Y, Liu Q Q, Liu H, Zhu J Q, Li Ch Y. Acta Phys-Chim Sin), 2008, 24: 1773
9 Kawai T, Sato S, Suzuki S, Chun W-J, Asakura K, Bando K K, Matsui T, Yoshimura Y, Kubota T, Okamoto Y, Lee Y K. Chem Lett, 2003, 32: 956
10 Shu Y Y, Oyama S T. Carbon, 2005, 43: 1517
11 Wang A J, Ruan L F, Teng Y, Li X, Lu M H, Ren J, Wang Y, Hu Y K. J Catal, 2005, 229: 314
12 刘理华, 李广慈, 刘迪, 柳云骐, 刘晨光. 化学进展 (Liu L H, Li G C, Liu D, Liu Y Q, Liu Ch G. Progr Chem), 2010, 22: 1701
13 Sawhill S J, Phillips D C, Bussell M E. J Catal, 2003, 215: 208
14 许建跃, 李凤艳, 赵天波, 赵志芳, 郭剑. 石油化工高等学校学报 (Xu J Y, Li F Y, Zhao T B, Zhao Zh F, Guo J. J Petrochem Univ), 2003, 16(4): 4
15 Tauster S J, Fung S C, Garten R L. J Am Chem Soc, 1978, 100: 170
16 Segawa K, Soeya T, Kim D S. Res Chem Intermed, 1991, 15: 129
17 Yoshinaka S, Segawa K. Catal Today, 1998, 45: 293
18 Wang K L, Yang B L, Liu Y, Yi C H. Energ Fuel, 2009, 23: 4209
19 Li X, Lu M H, Wang A J, Song C S, Hu Y K. J Phys Chem C, 2008, 112: 16584
20 Li X, Zhang Y L, Wang A J, Wang Y, Hu Y K. Catal Commun, 2010, 11: 1129
21 Vu V H, Belkouch J, Ould-Dris A, Taouk B. AIChE J, 2008, 54: 1585
22 Ma Z, Brown S, Overbury S H, Dai S. Appl Catal A, 2007, 327: 226
23 Zhang J, Li M J, Feng Z C, Chen J, Li C. J Phys Chem B, 2006, 110: 927
24 Li W, Dhandapani B, Oyama S T. Chem Lett, 1998, 27: 207
25 He M, Lu X H, Feng X, Yu L, Yang Z H. Chem Commun, 2004: 2202
26 Zhu Y H, Li W, Zhou Y X, Lu X H, Feng X, Yang Z H. Catal Lett, 2009, 127: 406
27 Li W, Bai Y, Liu C, Yang Z H, Feng X, Lu X H, van der Laak N K, Chan K-Y. Environ Sci Technol, 2009, 43: 5423
28 王海棠, 朱银华, 杨祝红, 刘金龙, 孙庆杰, 陆小华, 冯新. 催化学报 (Wang H T, Zhu Y H, Yang Zh H, Liu J L, Sun Q J, Lu X H, Feng X. Chin J Catal), 2009, 30: 414
29 陈闪山, 朱银华, 李伟, 刘维佳, 李力成, 杨祝红, 刘畅, 姚文俊, 陆小华, 冯新. 催化学报 (Chen Sh Sh, Zhu Y H, Li W, Liu W J, Li L Ch, Yang Zh H, Liu Ch, Yao W J, Lu X H, Feng X. Chin J Catal), 2010, 31: 605
30 于荟, 朱银华, 刘畅, 杨祝红, 陆小华, 冯新. 催化学报 (Yu H, Zhu Y H, Liu Ch, Yang Zh H, Lu X H, Feng X. Chin J Catal), 2009, 30: 265
31 丁玉兰, 柏扬, 李伟, 陈闪山, 朱育丹, 朱银华, 杨祝红, 陆小华. 催化学报 (Ding Y L, Bai Y, Li W, Chen Sh Sh, Zhu Y D, Zhu Y H, Yang Zh H, Lu X H. Chin J Catal), 2010, 31: 1271
32 Bai Y, Li W, Liu C, Yang Zh H, Feng X, Lu X H, Chan K-Y. J Mater Chem, 2009, 19: 7055
33 刘金龙, 朱银华, 杨祝红, 王海棠, 陆小华, 冯新, 汪怀远. 过程工程学报 (Liu J L, Zhu Y H, Yang Zh H, Wang H T, Lu X H, Feng X, Wang H Y. Chin J Process Eng), 2009, 9: 882
34 Stinner C, Tang Z, Haouas M, Weber T, Prins R. J Catal, 2002, 208: 456
35 李冬燕, 余夕志, 陈长林, 徐南平, 王延儒. 高校化学工程学报 (Li D Y, Yu X Zh, Chen Ch L, Xu N P, Wang Y R. J Chem Eng Chin Univ), 2006, 20: 825
36 Chen J X, Chen Y, Yang Q, Li K L, Yao C C. Catal Commun, 2010, 11: 571
37 鲁墨弘, 王安杰, 李翔, 单玉华, 胡永康. 石油学报 (石油加工). (Lu M H, Wang A J, Li X, Shan Y H, Hu Y K. Acta Petrol Sin (Petrol Proc Sect)), 2009, 25: 522
38 Bao N Z, Feng X, Lu X H, Shen L M, Yanagisawa K. AIChE J, 2004, 50: 1568

[1]	Chao Nie, Xiangdong Long, Qi Liu, Jia Wang, Fei Zhan, Zelun Zhao, Jiong Li, Yongjie Xi, Fuwei Li. Facile fabrication of atomically dispersed Ru-P-Ru ensembles for efficient hydrogenations beyond isolated single atoms [J]. Chinese Journal of Catalysis, 2023, 45(2): 107-119.
[2]	Wenhao Cui, Dali Zhu, Juan Tan, Nan Chen, Dong Fan, Juan Wang, Jingfeng Han, Linying Wang, Peng Tian, Zhongmin Liu. Synthesis of mesoporous high-silica zeolite Y and their catalytic cracking performance [J]. Chinese Journal of Catalysis, 2022, 43(7): 1945-1954.
[3]	Bo Zhou, Mengyu Li, Yingying Li, Yanbo Liu, Yuxuan Lu, Wei Li, Yujie Wu, Jia Huo, Yanyong Wang, Li Tao, Shuangyin Wang. Cobalt-regulation-induced dual active sites in Ni₂P for hydrazine electrooxidation [J]. Chinese Journal of Catalysis, 2022, 43(4): 1131-1138.
[4]	Huapeng Li, Bin Sun, Tingting Gao, Huan Li, Yongqiang Ren, Guowei Zhou. Ti₃C₂ MXene co-catalyst assembled with mesoporous TiO₂ for boosting photocatalytic activity of methyl orange degradation and hydrogen production [J]. Chinese Journal of Catalysis, 2022, 43(2): 461-471.
[5]	Chao Wang, Wei Jiang, Hanxiang Chen, Linhua Zhu, Jing Luo, Wenshu Yang, Guangying Chen, Zhigang Chen, Wenshuai Zhu, Huaming Li. Pt nanoparticles encapsulated on V₂O₅ nanosheets carriers as efficient catalysts for promoted aerobic oxidative desulfurization performance [J]. Chinese Journal of Catalysis, 2021, 42(4): 557-562.
[6]	Min Wang, Qi Xie, Huimin Chen, Guangbo Liu, Xuejing Cui, Luhua Jiang. Surface regulated Ni nanoparticles on N-doped mesoporous carbon as an efficient electrocatalyst for CO₂ reduction [J]. Chinese Journal of Catalysis, 2021, 42(12): 2306-2312.
[7]	Chengbin Li, He Li, Chunzhi Li, Xiaomin Ren, Qihua Yang. One-pot synthesis of mesosilica/nano covalent organic polymer composites and their synergistic effect in photocatalysis [J]. Chinese Journal of Catalysis, 2021, 42(10): 1821-1830.
[8]	Wenhua Xue, Wenxi Chang, Xiaoyun Hu, Jun Fan, Enzhou Liu. 2D mesoporous ultrathin Cd_0.5Zn_0.5S nanosheet: Fabrication mechanism and application potential for photocatalytic H₂ evolution [J]. Chinese Journal of Catalysis, 2021, 42(1): 152-163.
[9]	Junxiong Guo, Yiyi Li, Shangdong Li, Xumei Cui, Yu Liu, Wen Huang, Linna Mao, Xiongbang Wei, Xiaosheng Zhang. One-step fabrication of TiO₂/graphene hybrid mesoporous film with enhanced photocatalytic activity and photovoltaic performance [J]. Chinese Journal of Catalysis, 2020, 41(8): 1208-1216.
[10]	Jiajia Xu, Zhiguo Zhu, Ting Su, Weiping Liao, Changliang Deng, Dongmei Hao, Yuchao Zhao, Wanzhong Ren, Hongying Lü. Green aerobic oxidative desulfurization of diesel by constructing an Fe-Anderson type polyoxometalate and benzene sulfonic acid-based deep eutectic solvent biomimetic cycle [J]. Chinese Journal of Catalysis, 2020, 41(5): 868-876.
[11]	Juhong Lian, Yuchao Chai, Yu Qi, Xiangyang Guo, Naijia Guan, Landong Li, Fuxiang Zhang. Unexpectedly selective hydrogenation of phenylacetylene to styrene on titania supported platinum photocatalyst under 385 nm monochromatic light irradiation [J]. Chinese Journal of Catalysis, 2020, 41(4): 598-603.
[12]	Hui Zhao, Zhong-Pan Hu, Yun-Pei Zhu, Li Ge, Zhong-Yong Yuan. P-doped mesoporous carbons for high-efficiency electrocatalytic oxygen reduction [J]. Chinese Journal of Catalysis, 2019, 40(9): 1366-1374.
[13]	Zhong-Pan Hu, Jin-Tao Ren, Dandan Yang, Zheng Wang, Zhong-Yong Yuan. Mesoporous carbons as metal-free catalysts for propane dehydrogenation: Effect of the pore structure and surface property [J]. Chinese Journal of Catalysis, 2019, 40(9): 1385-1394.
[14]	Jiahua Zhao, Yuan Shu, Pengfei Zhang. Solid-state CTAB-assisted synthesis of mesoporous Fe₃O₄ and Au@Fe₃O₄ by mechanochemistry [J]. Chinese Journal of Catalysis, 2019, 40(7): 1078-1084.
[15]	Jun Yang, Yuxi Liu, Jiguang Deng, Xingtian Zhao, Kunfeng Zhang, Zhuo Han, Hongxing Dai. AgAuPd/meso-Co₃O₄:High-performance catalysts for methanol oxidation [J]. Chinese Journal of Catalysis, 2019, 40(6): 837-848.

Preparation of Nickel Phosphide/Mesoporous-TiO₂Catalyst and Its Hydrodesulfurization Performance

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics