Effect of supports on the structure and activity of vanadium-chromium oxide catalysts for ammoxidation of 3-picoline

doi:10.1016/S1872-2067(12)60650-0

Chinese Journal of Catalysis ›› 2013, Vol. 34 ›› Issue (10): 1833-1838.DOI: 10.1016/S1872-2067(12)60650-0

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Effect of supports on the structure and activity of vanadium-chromium oxide catalysts for ammoxidation of 3-picoline

Feng Jiang^a, Shengcai Deng^b, Lei Niu^a, Guomin Xiao^a

a School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu, China;
b Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Provincial Key Laboratory of Nanotechnology, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, Jiangsu, China

Received:2013-06-07 Revised:2013-07-02 Online:2013-09-29 Published:2013-09-29
Contact: Guomin Xiao
Supported by:
This work was supported by the National Natural Science Foundation of China (21276050) and the National Key Technology R&D Program (2012BAD32B03).

Abstract

Abstract:

Bulk and Nb₂O₅-, MgF₂-, TiO₂-, and SiO₂-supported vanadium-chromium oxide catalysts were prepared by the incipient wetness impregnation method and investigated for the ammoxidation of 3-picoline to nicotinonitrile at 310-400 ℃. The physical and chemical properties of the catalysts were assessed by X-ray diffraction, N₂ adsorption-desorption, H₂-temperature-programmed reduction, and NH₃-temperature-programmed desorption. The surface area of the supports influenced the formation of the active components of the catalysts: high surface area encouraged the formation of monoclinic CrVO₄ whereas low surface area favored the formation of orthorhombic CrVO₄. The high reducibility of vanadium in the catalyst and the large number of surface active sites resulted in higher 3-picoline conversion efficiencies. The high selectivity was attributed to the low surface acidity of the catalysts. Reaction temperature showed a positive effect on the catalytic performance for it could increase 3-picoline conversion and maintain nicotinonitrile selectivity.

Key words: Ammoxidation, 3-Picoline, Nicotinonitrile, Support, Vanadium-chromium oxide

Feng Jiang, Shengcai Deng, Lei Niu, Guomin Xiao. Effect of supports on the structure and activity of vanadium-chromium oxide catalysts for ammoxidation of 3-picoline[J]. Chinese Journal of Catalysis, 2013, 34(10): 1833-1838.

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Effect of supports on the structure and activity of vanadium-chromium oxide catalysts for ammoxidation of 3-picoline

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