Application of sodium titanate nanotubes doped with vanadium (VNaTNT) as a heterogeneous catalyst for oxidation of sulfides at room temperature

doi:10.1016/S1872-2067(15)61056-7

Abstract

Abstract:

A heterogeneous titanate nanotube (TNT) catalyst containing TiO₂, Na, and V has been synthesized and used in the chemoselective oxidation of sulfides to the corresponding sulfoxides in the presence of 30% H₂O₂ in water. Some of the advantages of our method include excellent yields, heterogeneous conditions, simplicity, compatibility with a variety of functionalities, and ease of isolation of the products. Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and N₂ adsorption were used for structural and textural characterization of the catalyst (VNaTNT).

Key words: Sulfide, Sulfoxide, Sulfone, Supported vanadia catalyst, Nanotube

Mohammad Ali Dadvar, Razieh Fazaeli. Application of sodium titanate nanotubes doped with vanadium (VNaTNT) as a heterogeneous catalyst for oxidation of sulfides at room temperature[J]. Chinese Journal of Catalysis, 2016, 37(4): 494-501.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61056-7

https://www.cjcatal.com/EN/Y2016/V37/I4/494

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