由M0.02Cu0.4Mg5.6Al1.98(OH)16CO3 (M=Ru, Re)水滑石为前驱体制备的双金属固体碱催化甘油氢解

doi:10.1016/S1872-2067(11)60505-6

催化学报 ›› 2013, Vol. 34 ›› Issue (5): 986-992.DOI: 10.1016/S1872-2067(11)60505-6

由M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ (M=Ru, Re)水滑石为前驱体制备的双金属固体碱催化甘油氢解

夏水鑫, 郑丽萍, 聂仁峰, 陈平, 楼辉, 侯昭胤

浙江大学化学系催化研究所, 浙江杭州 310028

收稿日期:2012-10-31 修回日期:2013-05-20 出版日期:2013-05-06 发布日期:2013-05-06
通讯作者: 侯昭胤
基金资助:
国家自然科学基金(21273198,21073159);浙江省自然科学基金(LZ12B030001).

Trivalent metal ions M³⁺ in M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ layered double hydroxide as catalyst precursors for the hydrogenolysis of glycerol

XIA Shuixin, ZHENG Liping, NIE Renfeng, CHEN Ping, LOU Hui, HOU Zhaoyin

Institute of Catalysis, Department of Chemistry, Zhejiang University, Hangzhou, 310028, Zhejiang, China

Received:2012-10-31 Revised:2013-05-20 Online:2013-05-06 Published:2013-05-06
Supported by:
This work was supported by the National Natural Science Foundation of China (21273198, 21075139) and Zhejiang Provincial Natural Science Foundation (LZ12B03001).

摘要/Abstract

摘要：

采用共沉淀法合成了M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ (M = Ru,Re)水滑石前驱体,然后经焙烧和还原制备了铜分散度较高的双功能M-Cu/固体碱催化剂.这些双功能催化剂在粗甘油氢解制备丙二醇反应中表现出了很好的催化活性.表征结果证明,M的加入增强了催化剂表面氢的吸附和活化,进而促进了甘油的转化.

关键词: 水滑石, 双金属, 固体碱, 甘油, 氢解, 丙二醇

Abstract:

Trivalent metal ions M³⁺ in M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ (M = Ru, Re) layered double hydroxides (LDHs) were successfully synthesized by coprecipitation. Bimetallic M-Cu/solid base catalysts with high metal dispersion were obtained after calcination and H₂ reduction of these LDH precursors. These catalysts exhibited excellent performances for the hydrogenolysis of biomass-derived glycerol under mild conditions. The catalysts were stable when recycled five times. Characterizations indicated that the addition of Ru or Re enhanced the adsorption and activation of hydrogen on the surface of catalysts, which contributed to the high conversion of glycerol.

Key words: Layered double hydroxide, Bimetallic, Solid base, Glycerol, Hydrogenolysis, Propanediol

夏水鑫, 郑丽萍, 聂仁峰, 陈平, 楼辉, 侯昭胤. 由M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ (M=Ru, Re)水滑石为前驱体制备的双金属固体碱催化甘油氢解[J]. 催化学报, 2013, 34(5): 986-992.

XIA Shuixin, ZHENG Liping, NIE Renfeng, CHEN Ping, LOU Hui, HOU Zhaoyin. Trivalent metal ions M³⁺ in M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ layered double hydroxide as catalyst precursors for the hydrogenolysis of glycerol[J]. Chinese Journal of Catalysis, 2013, 34(5): 986-992.

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参考文献

[1] Marceau E, Carrier X, Che M, Clause O, Marcilly C. In: Ertl G, Knözinger H, Schűth F, Weitkamp J eds. Handbook of Heteroge-neous Catalysis. 2nd Ed. Vol II. Weinheim: Wiley-VCH, 2008. 467
[2] Liu H B, Jiao Q Z, Zhao Y, Li H S, Sun C B, Li X F. J Alloys Compd, 2010, 496: 317
[3] Yuan Z L, Wang L N, Wang J H, Xia S X, Chen P, Hou Z Y, Zheng X M. Appl Catal B, 2011, 101: 431
[4] Shao M F, Ning F Y, Zhao J W, Wei M, Evans D G, Duan X. J Am Chem Soc, 2012, 134: 1071
[5] Meher L C, Gopinath R, Naik S N, Dalai A K. Ind Eng Chem Res, 2009, 48: 1840
[6] Valente J S, Hernandez-Cortez J, Cantu M S, Ferrat G, López-Salinas E. Catal Today, 2010, 150: 340
[7] Guo X H, Li Y, Song W, Shen W J. Catal Lett, 2011, 141: 1458
[8] Takehira K, Shishido T, Wang P, Kosaka T, Takaki K. J Catal, 2004, 221: 43
[9] Tsyganok A I, Tsunoda T, Hamakawa S, Suzuki K, Takehira K, Hayakawa T. J Catal, 2003, 213: 191
[10] Morioka H, Shimizu Y, Sukenobu M, Ito K, Tanabe E, Shishido T, Takehira K. Appl Catal A, 2001, 215: 11
[11] Huang J H, Chen J X. Chin J Catal (黄金花, 陈吉祥. 催化学报), 2012, 33: 790
[12] Zope B N, Hibbitts D D, Neurock M, Davis R J. Science, 2010, 330: 74
[13] Villa A, Veith G M, Prati L. Angew Chem, Int Ed, 2010, 49: 4499
[14] Villa A, Gaiassi A, Rossetti I, Bianchi C L, Benthem K, Veith G M, Prati L. J Catal, 2010, 275: 108
[15] Liang D, Gao J, Wang J H, Chen P, Hou Z Y, Zheng X M. Catal Commun, 2009, 10: 1586
[16] Liang D, Cui S Y, Gao J, Wang J H, Chen P, Hou Z Y. Chin J Catal (梁丹, 崔世玉, 高静, 王军华, 陈平, 侯昭胤. 催化学报), 2011, 32: 1831
[17] Zhang M Y, Liang D, Nie R F, Lu X Y, Chen P, Hou Z Y. Chin J Catal (张梦媛, 梁丹, 聂仁峰, 吕秀阳, 陈平, 侯昭胤. 催化学报), 2012, 33: 1340
[18] Chai S H, Wang H P, Liang Y, Xu B Q. Green Chem, 2007, 9: 1130
[19] Cavani F, Guidetti S, Marinelli L, Piccinini M, Ghedini E, Signoretto M. Appl Catal B, 2010, 100: 197
[20] Wang F, Dubois J L, Ueda W. J Catal, 2009, 268: 260
[21] Katryniok B, Paul S, Capron M, Lancelot C, Bellière-Baca V, Rey P, Dumeignil F. Green Chem, 2010, 12: 1922
[22] Ma L, Li Y M, He D H. Chin J Catal (马兰, 李宇明, 贺德华. 催化学报), 2011, 32: 872
[23] Ma L, He D H. Catal Today, 2010, 149: 148.
[24] Miyazawa T, Koso S, Kunimori K, Tomishige K. Appl Catal A, 2007, 318: 244
[25] Maris E P, Davis R J. J Catal, 2007, 249: 328
[26] Oh J, Dash S, Lee H. Green Chem, 2011, 13: 2004
[27] Maris E P, Ketchie W C, Murayama M, Davis R J. J Catal, 2007, 251: 281
[28] Daniel O M, DeLaRiva A, Kunkes E L, Datye A K, Dumesic J A, Davis R J. ChemCatChem, 2010, 2: 1107
[29] Amada Y, Shinmi Y, Koso S, Kubotac T, Nakagawa Y, Tomishige K. Appl Catal B, 2011, 105: 117
[30] Zhou J, Zhang J, Guo X, Mao J, Zhang S. Green Chem, 2012, 14: 156
[31] Xia S X, Nie R F, Lu X Y, Wang L N, Chen P, Hou Z Y. J Catal, 2012, 296: 1
[32] Yuan Z L, Wu P, Gao J, Lu X Y, Hou Z Y, Zheng X M. Catal Lett, 2009, 130: 261
[33] Yuan Z L, Wang J H, Wang L N, Xie W H, Chen P, Hou Z Y, Zheng X M. Bioresour Technol, 2010, 101: 7088
[34] Wu Z, Mao Y, Wang X, Zhang M. Green Chem, 2011, 13: 1311
[35] Bienholz A, Schwab F, Claus P. Green Chem, 2010, 12: 290
[36] Bienholz A, Blume R, Knop-Gericke A, Girgsdies F, Behrens M, Claus P. J Phys Chem C, 2011, 115: 999
[37] Guo X H, Li Y, Liu Q Y, Shen W J. Chin J Catal (郭小惠, 李勇, 刘琪英, 申文杰. 催化学报), 2012, 33: 645
[38] Hu J Y, Liu X Y, Wang B, Pei Y, Qiao M H, Fan K N. Chin J Catal (胡基业, 刘晓钰, 王彬, 裴燕, 乔明华, 范康年. 催化学报), 2012, 33: 1266
[39] Xia S X, Yuan Z L, Wang L N, Chen P, Hou Z Y. Appl Catal A, 2011, 403: 173
[40] Musolino M G, Scarpino L A, Mauriello F, Pietropaolo R. ChemSusChem, 2011, 4: 1143
[41] Labajos F M, Rives V, Ulibarri M A. J Mater Sci, 1992, 27: 1546
[42] Liang J, Ma R, Iyi N, Ebina Y, Takada K, Sasaki T. Chem Mater, 2010, 22: 371
[43] Xia S X, Yuan Z L, Wang L N, Chen P, Hou Z Y. Bioresour Technol, 2012, 104: 814
[44] Li B D, Wang J, Yuan Y Z, Ariga H, Takakusagi S, Asakura K. ACS Catal, 2011, 1: 1521
[45] Genger T, Hinrichsen O, Muhker M. Catal Lett, 1999, 59: 137
[46] Wilmer H, Genger T, Hinrichesen O. J Catal, 2003, 215: 188
[47] Ahlers J A, Grasser J A, Loveless B T, Muggli D S. Catal Lett, 2007, 114: 185
[48] Arena F, Italiano G, Barbera K, Bordiga S, Bonura G, Spadaro L, Frusteri F. Appl Catal A, 2008, 350: 16
[49] Bienholz A, Schwab F, Claus P. Green Chem, 2010, 12: 290

由M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ (M=Ru, Re)水滑石为前驱体制备的双金属固体碱催化甘油氢解

Trivalent metal ions M³⁺ in M_0.02Cu_0.4Mg_5.6Al_1.98(OH)₁₆CO₃ layered double hydroxide as catalyst precursors for the hydrogenolysis of glycerol

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