半导体/石墨烯复合光催化剂的制备及应用

doi:10.1016/S1872-2067(12)60530-0

催化学报 ›› 2013, Vol. 34 ›› Issue (4): 621-640.DOI: 10.1016/S1872-2067(12)60530-0

半导体/石墨烯复合光催化剂的制备及应用

陈建炜, 石建稳, 王旭, 崔浩杰, 付明来

中国科学院城市环境研究所城市环境与健康重点实验室, 福建厦门361021

收稿日期:2012-10-11 修回日期:2012-12-26 出版日期:2013-04-23 发布日期:2013-04-24
通讯作者: 石建稳,付明来
基金资助:
国家自然科学基金(41001139); 国家高技术研究与发展计划(863计划, 2012AA062606); 福建省科技计划重点项目(2012Y0066); 高性能陶瓷和超微结构国家重点实验室开放课题基金(SKL201107SIC).

Recent progress in the preparation and application of semiconductor/graphene composite photocatalysts

CHEN Jianwei, SHI Jianwen, WANG Xu, CUI Haojie, FU Minglai

Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, Fujian, China

Received:2012-10-11 Revised:2012-12-26 Online:2013-04-23 Published:2013-04-24
Supported by:
This work was supported by the National Nature Science Foundation of China (41001139), the National High Technology Research and Development Program of China (863 Program, 2012AA062606), the Key Project of Science and Technology Plan of Fujian Province (2012Y0066), and Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure (SKL201107SIC).

摘要/Abstract

摘要：

首先分析了石墨烯和半导体光催化剂的特点,以及二者复合后可能具有的优越性质,接着介绍了石墨烯和半导体复合光催化剂的制备方法,归纳了石墨烯增强半导体光催化的机理,然后阐述了复合光催化剂在降解有机污染物、光催化分解水产氢、光催化还原CO₂制有机燃料和光催化灭菌四个典型的应用,最后对半导体/石墨烯复合光催化剂未来的发展趋势提出了展望.

关键词: 石墨烯, 半导体, 光催化, 复合, 制备, 应用

Abstract:

Graphene is a new material with a single-layer laminar structure of carbon atoms that possesses favorable physical and chemical properties such as high electrical conductivity, high chemical stability, and large specific surface area. Combining graphene with semiconductors to form composite photocatalysts can extend its light absorption edge, improve the migration rate of charge carriers, and enhance the adsorption capacity of contaminants. The unique two-dimensional planar structure of graphene endows composite photocatalysts with many excellent properties. Herein, the properties of graphene, semiconductor, and composite photocatalysts are first introduced. The various preparation methods of semiconductor/graphene composite photocatalysts are then presented, and the mechanisms behind enhanced photocatalysis are summarized. Four typical applications of composite photocatalysts: elimination of organic pollutants, hydrogen production, organic fuel production via CO₂ reduction, and photocatalytic sterilization, are described in detail. Finally, the direction of future research on semiconductor/graphene composite photocatalysts is explored.

Key words: Grapheme, Semiconductor, Photocatalysis, Composite, Preparation, Application

陈建炜, 石建稳, 王旭, 崔浩杰, 付明来. 半导体/石墨烯复合光催化剂的制备及应用[J]. 催化学报, 2013, 34(4): 621-640.

CHEN Jianwei, SHI Jianwen, WANG Xu, CUI Haojie, FU Minglai. Recent progress in the preparation and application of semiconductor/graphene composite photocatalysts[J]. Chinese Journal of Catalysis, 2013, 34(4): 621-640.

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半导体/石墨烯复合光催化剂的制备及应用

Recent progress in the preparation and application of semiconductor/graphene composite photocatalysts

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