柠檬酸的定向配位用于高效光合成过氧化氢以及高附加值β-酮戊二酸

doi:10.1016/S1872-2067(25)64885-6

催化学报 ›› 2026, Vol. 82: 201-211.DOI: 10.1016/S1872-2067(25)64885-6

柠檬酸的定向配位用于高效光合成过氧化氢以及高附加值β-酮戊二酸

张婧^a^,¹, 张锡东^a^,^b^,¹, 王开颜^a, 王雪飞^a^,^*(), 王苹^a, 陈峰^a, 余火根^b^,^*()

^a武汉理工大学化学化工与生命科学学院, 湖北武汉 430070
^b中国地质大学材料科学与化学学院, 太阳能燃料实验室, 湖北武汉 430074

收稿日期:2025-07-14 接受日期:2025-09-06 出版日期:2026-03-18 发布日期:2026-03-05
通讯作者: * 电子信箱: xuefei@whut.edu.cn (王雪飞),yuhuogen@cug.edu.cn (余火根).
作者简介:¹共同第一作者.
基金资助:
国家自然科学基金(22578342);国家自然科学基金(22178276);国家自然科学基金(22178275);国家自然科学基金(U22A20147);国家自然科学基金(22075220);湖北省自然科学基金(2022CFA001)

Citric directional coordination for efficient photocatalytic synthesis of H₂O₂ with high value-added β-Ketoglutaric acid

Jing Zhang^a^,¹, Xidong Zhang^a^,^b^,¹, Kaiyan Wang^a, Xuefei Wang^a^,^*(), Ping Wang^a, Feng Chen^a, Huogen Yu^b^,^*()

^aDepartment of Chemistry, School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, Hubei, China
^bLaboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, Hubei, China

Received:2025-07-14 Accepted:2025-09-06 Online:2026-03-18 Published:2026-03-05
Contact: * E-mail: xuefei@whut.edu.cn (X. Wang),yuhuogen@cug.edu.cn (H. Yu).
About author:¹ Contributed equally to this work.
Supported by:
National Natural Science Foundation of China(22578342);National Natural Science Foundation of China(22178276);National Natural Science Foundation of China(22178275);National Natural Science Foundation of China(U22A20147);National Natural Science Foundation of China(22075220);Natural Science Foundation of Hubei Province of China(2022CFA001)

摘要/Abstract

摘要：

过氧化氢(H₂O₂)是一种重要的绿色氧化剂和化工原料, 广泛应用于化学合成、纺织、环境净化和能源转化等领域. 目前工业上主要采用蒽醌法制备H₂O₂, 但该工艺需要高压氢气、贵金属催化剂和大量有机溶剂, 不仅能耗高、环境负担重, 也难以满足分布式和可持续发展的需求. 相比之下, 利用太阳能驱动的光催化H₂O₂合成具有绿色、低成本和可再生等优势. 然而, 现有光催化体系面临光生电子-空穴分离效率不足和光生空穴利用率低等问题, 导致H₂O₂产率有限. 此外, 光生空穴易引发副反应, 难以实现目标产物的高选择性氧化转化. 因此, 亟需设计一种新型光催化策略, 既能促进H₂O₂生成, 又能充分利用空穴驱动高值化学品的定向合成.

本研究旨在通过空间定向配位调控策略, 实现光催化H₂O₂高效生成与生物质衍生羟基酸的选择性氧化耦合. 一方面提升H₂O₂产率, 另一方面实现生物质资源高值化转化, 探索光催化剂-底物相互作用的机制, 并为太阳能驱动的绿色化工过程提供新的思路. 本文以BiVO₄为主体光催化剂, 通过构建各向异性结构实现不同晶面的功能分工. 具体而言, 在(010)晶面负载Au纳米颗粒, 以促进电子捕获与H₂O₂生成; 在(110)晶面保留未配位的Bi位点, 使其作为空穴氧化活性中心. 在柠檬酸(CA)的氧化过程中, CA的β-羟基和羧基与Bi位点形成稳定的五元螯合环, 从而实现定向配位. 这一结构不仅加速了空穴的有效提取, 而且引导了选择性脱羧反应途径, 最终生成β-酮戊二酸. 研究结果表明, 该双功能光催化剂实现了约0.6 mmol L^-1 h^-1的H₂O₂生成速率, 同时在柠檬酸转化中产物选择性高达99%. 该策略不仅显著提升了H₂O₂的产率, 还将传统副反应中消耗的空穴转化为选择性氧化反应, 极大提高了体系的整体能量利用效率. 此外, 该方法对其他羟基酸底物也表现出普适性, 验证了其在生物质高值化转化中的应用潜力.

综上, 本文提出的空间定向配位策略有效解决了光催化H₂O₂合成中电子-空穴利用不均衡的问题, 实现了“电子驱动H₂O₂生成-空穴驱动选择性氧化”的双通道耦合. 该设计不仅在实验中表现出高效与高选择性, 还揭示了光催化剂与底物间的分子相互作用机制. 研究结果为未来开发基于太阳能的H₂O₂分布式合成与高值化学品耦合生产提供了可推广的思路和方法, 对绿色化工和可再生能源利用具有重要意义.

关键词: 光催化过氧化氢合成, 选择性氧化, 空间电荷分离, 定向配位, 高附加值化学品

Abstract:

Photocatalytic hydrogen peroxide (H₂O₂) production offers a green alternative to the traditional anthraquinone process but remains limited by inefficient charge separation and underutilized photogenerated holes. Herein, we present a spatially resolved coordination strategy to couple efficient H₂O₂ generation with selective oxidation of biomass-derived hydroxy acids. Anisotropic Au-modified BiVO₄ photocatalysts were constructed, where Au nanoparticles on the (010) facet promoted H₂O₂ formation, while undercoordinated Bi atoms on the (110) facet selectively oxidized citric acid (CA). A five-membered chelate ring formed between β-hydroxyl and carboxyl groups of CA and surface Bi atoms, enabling directional coordination that enhanced hole extraction and guided a selective decarboxylation pathway to produce acetone dicarboxylic acid with 99% selectivity. This dual-functional design achieved a high H₂O₂ production rate (~0.6 mmol L^-1 h^-1) and exhibited broad applicability to other hydroxy acids. This work provides mechanistic insights into photocatalyst-substrate interactions and establishes a generalizable strategy for integrating H₂O₂ photosynthesis with value-added chemical production under solar irradiation.

Key words: Photocatalytic H₂O₂ production, Selective oxidation, Spatial charge separation, Directional coordination, High-value-added chemicals

张婧, 张锡东, 王开颜, 王雪飞, 王苹, 陈峰, 余火根. 柠檬酸的定向配位用于高效光合成过氧化氢以及高附加值β-酮戊二酸[J]. 催化学报, 2026, 82: 201-211.

Jing Zhang, Xidong Zhang, Kaiyan Wang, Xuefei Wang, Ping Wang, Feng Chen, Huogen Yu. Citric directional coordination for efficient photocatalytic synthesis of H₂O₂ with high value-added β-Ketoglutaric acid[J]. Chinese Journal of Catalysis, 2026, 82: 201-211.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(25)64885-6

https://www.cjcatal.com/CN/Y2026/V82/I3/201

图/表 7

Fig. 1. Schematic illustration of Au/BiVO4 for H2O2 photosynthesis coupled with citric acid (CA) photo-oxidation via a directional coordination strategy.

Fig. 2. (a) Schematic drawing illustrating the controllable preparation of Au/BiVO4 single-crystal photocatalyst. Typical FESEM results of the BiVO4 (b) and Au/BiVO4 (c). XRD patterns (d) and UV-vis diffuse reflection spectra (e).

Fig. 3. (a,b) Photocatalytic performance of Au/BiVO4 for H2O2 production in different systems. (c) Optimizing CA concentration in photocatalytic H2O2 production of Au/BiVO4. (d) Recycles test of Au/BiVO4 for H2O2 production.

Fig. 4. The DFT calculation structure of BiVO4 (a), CA (b), and the DFT calculation optimal structure (c) of Bi sites and coordination of CA. (d) DFT calculated values for different coordination modes of CA and BiVO4. (e) FTIR spectra of Au/BiVO4 and CA modified Au/BiVO4. (f) The high-resolution XPS spectra of Bi 4f for Au/BiVO4 and CA modified Au/BiVO4. (g) Schematic diagram of the band structure of BiVO4. (h) High-resolution XPS spectra of O 1s for Au/BiVO4-CA. LSV curves obtained for glass electrodes modified with different sacrificial agents (i) and transient photocurrent response (j) obtained for glass electrodes modified with BiVO4 photocatalyst in 0.1 mol L-1 HClO4 with CA (1), CH3OH (2), and EtOH (3) at 0.05 V s-1.

Fig. 5. (a) The reaction mechanism of Au/BiVO4 forming OGA under the coordination of CA. LC-MS results of the CA reaction solution after Au/BiVO4 photocatalytic reaction for 0 h (b) and 2 h (c). In-situ DRIFTS result (d) and enlarged spectra (e-g) for Au/BiVO4 sample under light illumination for 0-90 min.

Fig. 6. (a) Evolutions of CA, H2O2, OGA, and CO2 with increasing illumination time. (b) Performance comparison of photocatalytic H2O2 evolution coupled with organic oxidation. (c) Photocatalytic redox reaction equation for OGA and H2O2. (d) The pathways for OGA and H2O2 formation on Au/BiVO4.

Fig. 7. DFT theoretical calculation models. (a) Malic acid (MA). (b) DFT calculated values for different coordination modes of MA and BiVO4. In-situ DRIFTS result (c) and enlarged spectra (d-f) for AuPd/BiVO4 sample under light illumination for 0-90 min. (g) LC-MS results of the MA reaction solution after AuPd/BiVO4 photocatalytic reaction for 2 h. (h) Evolutions of MA, H2O2, and PA with increasing illumination time.

参考文献

[1]	T. Cao, Q. Xu, J. Zhang, S. Wang, T. Di, Q. Deng, Chin. J. Catal., 2025, 72, 118-129.
[2]	M. Sayed, H. Li, C. Bie, Acta Phys.-Chim. Sin., 2025, 41, 100117.
[3]	Z. Jiang, J. Zhang, B. Cheng, Y. Zhang, J. Yu, L. Zhang, Small, 2025, 21, 2409079.
[4]	Y. Ma, S. Wang, Y. Zhang, B. Cheng, L. Zhang, J. Materiomics, 2025, 11, 100978.
[5]	L. Wang, J. Zhao, J. Mater. Sci. Technol., 2026, 241, 18-20.
[6]	J. Qiu, K. Meng, Y. Zhang, B. Cheng, J. Zhang, L. Wang, J. Yu, Adv. Mater., 2024, 36, 2400288.
[7]	X. Li, Z. Wang, Acta Phys.-Chim. Sin., 2025, 41, 100080.
[8]	X. Wang, K. Qi, K. Xu, Chin. J. Catal., 2025, 70, 1-4.
[9]	W. Chi, Y. Dong, B. Liu, C. Pan, J. Zhang, H. Zhao, Y. Zhu, Z. Liu, Nat. Commun., 2024, 15, 5316.
[10]	Y. Yang, X. Zhou, M. Gu, B. Cheng, Z. Wu, J. Zhang, Acta Phys.-Chim. Sin., 2025, 41, 100064.
[11]	Y. Zhang, J. Qiu, B. Zhu, G. Sun, B. Cheng, L. Wang, Chin. J. Catal., 2024, 57, 143-153.
[12]	Y. Zhang, Y. Wang, Y. Liu, S. Zhang, Y. Zhao, J. Zhang, J. Materiomics, 2025, 11, 100985.
[13]	M. Sayed, K. Qi, X. Wu, L. Zhang, H. García, J. Yu, Chem. Soc. Rev., 2025, 54, 4874-4921.
[14]	X. Zhou, C. Ai, X. Wang, Z. Wu, J. Zhang, J. Materiomics, 2025, 11, 100974.
[15]	X. Zhou, S. Yang, X. Wang, Z. Wu, Y. Huo, J. Zhang, J. Mater. Sci. Technol., 2025, 234, 60-70.
[16]	G. Chen, Z. Zheng, W. Zhong, G. Wang, X. Wu, Acta Phys.-Chim. Sin., 2024, 40, 2406021.
[17]	X. Zhang, J. Xu, H. Long, J. Yu, H. Yu, ACS Catal., 2024, 14, 18669-18678.
[18]	X. Zhang, D. Gao, B. Zhu, B. Cheng, J. Yu, H. Yu, Nat. Commun., 2024, 15, 3212.
[19]	W. Zhong, A. Meng, Y. Su, H. Yu, P. Han, J. Yu, Angew. Chem. Int. Ed., 2025, 64, e202425038
[20]	Y. Zhao, Y. Zhang, H. Tan, C. Ai, J. Zhang, J. Materiomics, 2025, 11, 100970.
[21]	M. Gu, Y. Yang, B. Cheng, L. Zhang, P. Xiao, T. Chen, Chin. J. Catal., 2024, 59, 185-194.
[22]	C. Jiang, C. Yuan, K. Xu, X. Zhou, C. Bie, J. Mater. Sci. Technol., 2025, 231, 36-44.
[23]	W. Yu, Chin. J. Catal. 2025, 73, 8-11.
[24]	H. Chen, L. Nie, K. Xu, Y. Yang, C. Fang, Acta Phys.-Chim. Sin., 2024, 40, 2406019.
[25]	W. Wang, W. Zhang, C. Deng, H. Sheng, J. Zhao, Angew. Chem. Int. Ed., 2024, 63, e202317969.
[26]	C. Chen, G. Qiu, T. Wang, Z. Zheng, M. Huang, B. Li, J. Colloid Interface Sci., 2021, 592, 1-12.
[27]	W. Chi, B. Liu, Y. Dong, J. Zhang, X. Sun, C. Pan, H. Zhao, Y. Ling, Y. Zhu, Appl. Catal. B, 2024, 355, 124077.
[28]	L. Yuan, P. Du, C. Zhang, Y. Xi, Y. Zou, J. Li, Y. Bi, T. Bao, C. Liu, C. Yu, Appl. Catal. B, 2025, 364, 124855.
[29]	Q. Zhang, L. Li, Q. Zhou, H. Zhang, H. Zhang, B. An, H. Ning, T. Xing, M. Wang, M. Wu, W. Wu, ACS Catal., 2023, 13, 13101-13110.
[30]	Y. Yang, J. Liu, M. Gu, B. Cheng, L. Wang, J. Yu, Appl. Catal. B, 2023, 333, 122780.
[31]	H. Zhao, J. Yang, M. Eisapour, J. Hu, Z. Chen, Chem. Eng. J., 2024, 490, 151767.
[32]	K. T. Wong, C. E. Choong, W. Kim, Y. Yoon, W. Choi, E. H. Choi, M. Jang, Appl. Catal. B, 2024, 357, 124256.
[33]	C.-L. Tan, M.-Y. Qi, Z.-R. Tang, Y.-J. Xu, Artif. Photosynth., 2025, 1, 144-155.
[34]	W. Zhong, D. Zheng, Y. Ou, A. Meng, Y. Su, Acta Phys.-Chim. Sin., 2024, 40, 2406005.
[35]	J.-N. Chang, J.-W. Shi, Q. Li, S. Li, Y.-R. Wang, Y. Chen, F. Yu, S.-L. Li, Y.-Q. Lan, Angew. Chem. Int. Ed., 2023, 62, e202303606.
[36]	Q. Zhang, C. Chen, F. Liu, Z. Zhang, X. Fang, Q. Liu, Chem. Eng. J., 2025, 509, 161204.
[37]	Y. Wu, C. Cheng, K. Qi, B. Cheng, J. Zhang, J. Yu, L. Zhang, Acta Phys.-Chim. Sin., 2024, 40, 2406027.
[38]	Z. Tian, C. Han, Y. Zhao, W. Dai, X. Lian, Y. Wang, Y. Zheng, Y. Shi, X. Pan, Z. Huang, H. Li, W. Chen, Nat. Commun., 2021, 12, 2039.
[39]	B. He, Z. Wang, P. Xiao, T. Chen, J. Yu, L. Zhang, Adv. Mater., 2022, 34, 2203225.
[40]	L. Wu, Q. Li, K. Dang, D. Tang, C. Chen, Y. Zhang, J. Zhao, Angew. Chem. Int. Ed., 2024, 63, e202316218.
[41]	K. Meng, J. Zhang, B. Cheng, X. Ren, Z. Xia, F. Xu, L. Zhang, J. Yu, Adv. Mater., 2024, 36, 2406460.
[42]	C. Cheng, J. Yu, D. Xu, L. Wang, G. Liang, L. Zhang, M. Jaroniec, Nat. Commun., 2024, 15, 1313.
[43]	J. Hu, M. Zhu, Z. Ali Ghazi, Y. Cao, Chin. J. Catal., 2025, 71, 319-329.
[44]	Y. Hu, X. Yu, Q. Liu, L. Wang, H. Tang, Carbon, 2022, 188, 70-80.
[45]	S. Wu, X. Wang, H. Yu, Chin. J. Struct. Chem., 2024, 43, 100457.
[46]	Y. Wang, H. Shi, Z. Chen, F. Chen, P. Wang, X. Wang, Acta Phys.-Chim. Sin., 2025, 41, 100081.
[47]	H. Shi, S. Li, M. Wang, X. Yin, J. Huang, W. Qi, X. Wang, P. Wang, F. Chen, H. Yu, Catal. Sci. Technol., 2023, 13, 3884-3890.
[48]	Y. Luo, X. Wang, P. Wang, F. Chen, H. Yu, Chem. Eng. J., 2024, 497, 154886.
[49]	Y. Tian, X. Wang, H. Shi, JiachaoXu, J. Zhang, P. Wang, F. Chen, H. Yu, Chem. Eng. J., 2025, 519, 165453.
[50]	Z. Wang, Y. Guo, M. Liu, X. Liu, H. Zhang, W. Jiang, P. Wang, Z. Zheng, Y. Liu, H. Cheng, Y. Dai, Z. Wang, B. Huang, Adv. Mater., 2022, 34, 2201594.
[51]	T. Liu, Z. Pan, J. J. M. Vequizo, K. Kato, B. Wu, A. Yamakata, K. Katayama, B. Chen, C. Chu, K. Domen, Nat. Commun., 2022, 13, 1034.
[52]	J. Wang, Y. Zhang, S. Jiang, C. Sun, S. Song, Angew. Chem. Int. Ed., 2023, 62, e202307808.
[53]	K. Fuku, R. Takioka, K. Iwamura, M. Todoroki, K. Sayama, N. Ikenaga, Appl. Catal. B, 2020, 272, 119003.
[54]	S. Wang, C. Li, Y. Qi, J. Zhang, N. Wang, M. Liu, B. Zhang, X. Cai, H. Zhang, S.-H. Wei, G. Ma, J. Yang, S. Chen, F. Zhang, Nat. Commun., 2025, 16, 3776.
[55]	F. Sun, Y. Deng, J. Leng, M. Shi, C. Li, S. Jin, R. Li, W. Tian, J. Am. Chem. Soc., 2024, 146, 31106-31113.
[56]	T. Liu, Z. Pan, K. Kato, J. J. M. Vequizo, R. Yanagi, X. Zheng, W. Yu, A. Yamakata, B. Chen, S. Hu, K. Katayama, C. Chu, Nat. Commun., 2022, 13, 7783.
[57]	M. Lv, F. Tong, Z. Wang, Y. Liu, P. Wang, H. Cheng, Y. Dai, Z. Zheng, B. Huang, J. Mater. Chem. A, 2022, 10, 19699-19709.
[58]	J. Wang, D. Huang, F. Chen, J. Chen, H. Jiang, Y. Zhu, C. Chen, J. Zhao, Environ. Sci. Technol., 2023, 57, 4434-4442.
[59]	Z. Fang, X. Yue, Q. Xiang, Small, 2024, 20, 2401914.
[60]	H. Shi, Y. Li, K. Wang, S. Li, X. Wang, P. Wang, F. Chen, H. Yu, Chem. Eng. J., 2022, 443, 136429.
[61]	J. Cheng, W. Wang, J. Zhang, S. Wan, B. Cheng, J. Yu, S. Cao, Angew. Chem. Int. Ed., 2024, 63, e202406310.
[62]	Y. Liu, W. Xu, Z. Gao, Y. Liang, H. Jiang, Z. Li, F. Wang, S. Zhu, Z. Cui, ChemSusChem, 2025, 18, e202500380.
[63]	C. Chen, C. Wang, Y. Zhang, H. Sun, J. Xu, Y. Zhang, Y. Lou, Y. Zhu, C. Pan, Appl. Catal. B, 2024, 348, 123854.
[64]	B. Liu, J. Zhang, H. Li, B. Cheng, C. Bie, Acta Phys.-Chim. Sin., 2025, DOI: 10.1016/j.actphy.2025.100121.
[65]	K. Meng, J. Zhang, B. Zhu, C. Jiang, H. García, J. Yu, Adv. Mater., 2025, 37, 2505088.

柠檬酸的定向配位用于高效光合成过氧化氢以及高附加值β-酮戊二酸

Citric directional coordination for efficient photocatalytic synthesis of H₂O₂ with high value-added β-Ketoglutaric acid

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 7

参考文献

相关文章 15

编辑推荐

Metrics

[1]	詹钰捷, 钟承钦, 毕明莉, 梁亚飞, 祁玉基, 陈家琪, 刘家旭, 张新党, 张帅, 王业红, 王峰. 催化甲醇选择性氧化制甲醛的铁钒催化剂活性位点的识别[J]. 催化学报, 2025, 72(5): 334-343.
[2]	李爽, 林海莉, 贾雪梅, 金昕, 汪钱龙, 李馨悦, 陈士夫, 曹静. 双金属Ni_xFe₂₋_xP修饰的RP用于增强光催化苯甲醇氧化耦合产H₂[J]. 催化学报, 2025, 70(3): 363-377.
[3]	肖建洲, 赵致灏, 张楠楠, 车宏途, 乔秀, 张光颖, 初小宇, 王雅, 董鸿, 张凤鸣. 共价有机框架中的连接工程用于在水和空气中光催化全合成H₂O₂[J]. 催化学报, 2025, 69(2): 219-229.
[4]	李可欣, 袁浩, 杨祖保, 胡准. MOF包埋衍生策略缓释氧物种增强甲烷选择性氧化的活性与选择性: 基于瞬时原位红外的研究[J]. 催化学报, 2025, 78(11): 202-214.
[5]	亓文慧, 李秀艳, 顾少楠, 孙彬, 王轶男, 周国伟. 金属有机催化剂的电子结构调控在光催化产H₂O₂中的应用[J]. 催化学报, 2025, 77(10): 45-69.
[6]	魏征, 蒋国霞, 王怡雯, 黎刚刚, 张中申, 程杰, 张凤莲, 郝郑平. La₂FeMO₆双钙钛矿中的不对称氧空位用于促进氧活化和H₂S选择性氧化[J]. 催化学报, 2024, 62(7): 198-208.
[7]	屠振涛, 何晓洋, 刘璇, 熊登科, 左娟, 吴德礼, 汪建营, 陈作锋. 通过钨对镍活性位点的电子改性实现苯甲胺选择性氧化耦合制氢[J]. 催化学报, 2024, 58(3): 146-156.
[8]	曾冰, 黄凤伟, 王月欣, 熊康慧, 郎贤军. TEMPO显著加速芘基金属有机框架光催化硫化物到亚砜的转化[J]. 催化学报, 2024, 58(3): 226-236.
[9]	龚汉涛, 邓才豪, 何佩佩, 刘明杰, 蔡翼亮, 杨亦文, 杨启炜, 鲍宗必, 任其龙, 姚思宇, 张治国. 异质结光催化剂选择性光氧化甲烷为C1含氧化合物[J]. 催化学报, 2024, 67(12): 61-70.
[10]	奚亦凡, 高睿行, 方萍, 韩亚平, 马聪, 梅天胜. 电化学苄位区域选择性氧化反应研究[J]. 催化学报, 2024, 67(12): 54-60.
[11]	张富林, 李霞, 董晓芸, 郝慧敏, 郎贤军. 基于噻唑并噻唑的共价有机框架微球用于蓝光光催化胺的选择性需氧氧化[J]. 催化学报, 2022, 43(9): 2395-2404.
[12]	Muhammad Tayyab, 刘玉洁, 敏世雄, Rana Muhammad Irfan, 朱乔虹, 周亮, 雷菊英, 张金龙. 无贵金属光催化剂VC/CdS纳米线将苯甲醇选择性氧化为苯甲醛并产氢[J]. 催化学报, 2022, 43(4): 1165-1175.
[13]	苗昱聪, 邵明飞. 光电催化用于高附加值化学品合成[J]. 催化学报, 2022, 43(3): 595-610.
[14]	梁子展, 沈荣晨, 张鹏, 李佑稷, 李能, 李鑫. 全有机COF/PUP S型光催化剂分解水制氢的性能研究[J]. 催化学报, 2022, 43(10): 2581-2591.
[15]	郑笑笑, 齐思慧, 曹彦宁, 沈丽娟, 区泽棠, 江莉龙. 乙酸调控MIL-53(Fe)的形貌演变及其高效选择性氧化H₂S性能[J]. 催化学报, 2021, 42(2): 279-287.

柠檬酸的定向配位用于高效光合成过氧化氢以及高附加值β-酮戊二酸

Citric directional coordination for efficient photocatalytic synthesis of H2O2 with high value-added β-Ketoglutaric acid

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 7

参考文献

相关文章 15

编辑推荐

Metrics

Citric directional coordination for efficient photocatalytic synthesis of H₂O₂ with high value-added β-Ketoglutaric acid