氧化铈在氨选择性催化还原氮氧化物中的应用

doi:10.1016/S1872-2067(14)60155-8

催化学报 ›› 2014, Vol. 35 ›› Issue (8): 1251-1259.DOI: 10.1016/S1872-2067(14)60155-8

氧化铈在氨选择性催化还原氮氧化物中的应用

单文坡^a,b, 刘福东^a, 余运波^a, 贺泓^a

a. 中国科学院生态环境研究中心, 北京 100085;
b. 南京理工大学环境与生物工程学院, 江苏南京 210094

收稿日期:2014-03-30 修回日期:2014-05-08 出版日期:2014-08-01 发布日期:2014-08-05
通讯作者: 贺泓
基金资助:
国家重点基础研究发展计划（973计划，2010CB732304）；国家高技术研究发展计划（863计划，2013AA065301）；国家自然科学基金（51308296，51108446）；中央高校基本科研业务费专项资金（30920140111012）；江苏省“青蓝工程”.

The use of ceria for the selective catalytic reduction of NO_x with NH₃

Wenpo Shan^a,b, Fudong Liu^a, Yunbo Yu^a, Hong He^a

a. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;
b. School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu, China

Received:2014-03-30 Revised:2014-05-08 Online:2014-08-01 Published:2014-08-05
Supported by:
This work was supported by the National Basic Research Program of China (973 Program, 2010CB732304), the National High Technology Research and Development Program of China (863 Program, 2013AA065301), the National Natural Science Foundation of China (51308296, 51108446), the Fundamental Research Funds for the Central Universities (30920140111012), and the Qing Lan Project of Jiangsu Province.

摘要/Abstract

摘要：

NH₃选择性催化还原NO_x（NH₃-SCR）是一种广泛应用于以燃煤电厂为代表的固定源和以柴油发动机为代表的移动源NO_x排放控制的技术. 近年来，氧化铈由于具有优异的氧化-还原、储氧和表面酸性等特性而在NH₃-SCR催化剂研究中受到广泛关注. 本文系统综述了氧化铈用作NH₃-SCR催化剂载体、助剂和主催化组分的相关研究，并对该领域未来可能的研究方向进行展望.

关键词: 氧化铈, 柴油车尾气, 氮氧化物控制, 选择性催化还原

Abstract:

The selective catalytic reduction of NO_x with NH₃ (NH₃-SCR) is one of the widely used NO_x control strategies for stationary sources (particularly for power plants) and mobile sources (particularly for diesel vehicles). The application is aimed at meeting the increasingly stringent standards for NO_x emissions. Recently, ceria has attracted much attention for its applications in NH₃-SCR catalysts owing to its unique redox, oxygen storage, and acid-base properties. In this article, we comprehensively review recent studies on ceria for NH₃-SCR catalysts when used as support, promoter, or the main active component. In addition, the general development of ceria for NH₃-SCR catalysts is discussed.

Key words: Ceria, Diesel exhaust, Nitrogen oxides abatement, Selective catalytic reduction

单文坡, 刘福东, 余运波, 贺泓. 氧化铈在氨选择性催化还原氮氧化物中的应用[J]. 催化学报, 2014, 35(8): 1251-1259.

Wenpo Shan, Fudong Liu, Yunbo Yu, Hong He. The use of ceria for the selective catalytic reduction of NO_x with NH₃[J]. Chinese Journal of Catalysis, 2014, 35(8): 1251-1259.

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https://www.cjcatal.com/CN/Y2014/V35/I8/1251

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氧化铈在氨选择性催化还原氮氧化物中的应用

The use of ceria for the selective catalytic reduction of NO_x with NH₃

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氧化铈在氨选择性催化还原氮氧化物中的应用

The use of ceria for the selective catalytic reduction of NOx with NH3

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The use of ceria for the selective catalytic reduction of NO_x with NH₃