原位配体功能化策略制备共价金属有机骨架促进其析氢反应

doi:10.1016/S1872-2067(21)63892-5

催化学报 ›› 2022, Vol. 43 ›› Issue (3): 811-819.DOI: 10.1016/S1872-2067(21)63892-5

原位配体功能化策略制备共价金属有机骨架促进其析氢反应

郑灵玲^a^,^b, 张龙帅^a^,^#(), 陈颖^a^,^b, 田磊^a^,^b, 江训恒^a^,^b, 谌莉莎^a^,^b, 邢秋菊^a, 刘小真^b, 吴代赦^b, 邹建平^a^,^b^,^*()

^a南昌航空大学, 江西省持久性污染物控制与资源化重点实验室, 江西南昌 330063
^b南昌大学资源环境与化学工程学院, 鄱阳湖环境与资源利用教育部重点实验室, 江西南昌 330031

收稿日期:2021-05-28 接受日期:2021-05-28 出版日期:2022-03-18 发布日期:2022-02-18
通讯作者: 张龙帅,邹建平
基金资助:
国家重点基础研究发展计划(2018YFC1902000);国家自然科学基金(51878325);国家自然科学基金(51238002);国家自然科学基金(51868050);江西省自然科学基金(20181BBG78034);江西省自然科学基金(20171ACB20017);江西省自然科学基金(20171BAB206049)

A new strategy for the fabrication of covalent organic framework-metal-organic framework hybrids via in-situ functionalization of ligands for improved hydrogen evolution reaction activity

Ling-Ling Zheng^a^,^b, Long-Shuai Zhang^a^,^#(), Ying Chen^a^,^b, Lei Tian^a^,^b, Xun-Heng Jiang^a^,^b, Li-Sha Chen^a^,^b, Qiu-Ju Xing^a, Xiao-Zhen Liu^b, Dai-She Wu^b, Jian-Ping Zou^a^,^b^,^*()

^aKey Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, Jiangxi, China
^bKey Laboratory of Poyang Lake Environment and Resource Utilization of Ministry of Education, School of Resources Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, Jiangxi, China

Received:2021-05-28 Accepted:2021-05-28 Online:2022-03-18 Published:2022-02-18
Contact: Long-Shuai Zhang, Jian-Ping Zou
Supported by:
National Key R&D Program of China(2018YFC1902000);National Natural Science Foundation of China(51878325);National Natural Science Foundation of China(51238002);National Natural Science Foundation of China(51868050);Natural Science Foundation of Jiangxi Province(20181BBG78034);Natural Science Foundation of Jiangxi Province(20171ACB20017);Natural Science Foundation of Jiangxi Province(20171BAB206049)

摘要/Abstract

摘要：

新型多孔材料在诸多领域具有广阔的应用前景, 其发展引起了研究者较大关注. 在过去的十年中, 大量的先进多孔材料被设计并应用于不同领域. 其中, 共价有机骨架(COFs)和金属有机骨架(MOFs)材料由于具有结构多样、孔隙可调以及功能多样等独特性质, 得到了广泛研究. 为了有效地结合各个组分的优点以获得最优性能, 科研工作者投入了大量的精力来设计独特的COF/MOF复合材料. 目前, 已报道了多种方法合成COF/MOF复合材料, 但合成过程中引入额外的化学键会分散电子的传递, 降低电荷的有效传输, 且由于配体的选择性和合成的复杂性都限制了合成方法的广泛应用. 因此, 迫切需要开发一种不形成额外化学键且具有普适性的合成COF/MOF复合材料的新方法.
本文提出了一种新颖、简单的原位生长策略来制备COF/MOF复合材料. 由于共价三嗪骨架(CTF-1)具有高的热稳定性、可调的光吸收能力和集成不同功能组分特点, 选择了CTF-1作为基底材料. 首先将苯甲酸基团原位接枝到CTF-1上, 获得苯甲酸化的三嗪基共价骨架(B-CTF-1), 然后将制备的B-CTF-1作为反应物加入到Ti-MOF的合成过程中. 在溶剂热反应过程中, Ti团簇可以通过配位键与苯甲酸基团中暴露的羧基快速自组装, 得到B-CTF-Ti-MOF复合材料. 原位功能化的苯甲酸既可以作为MOFs的成核位点, 也可以作为光生电子的传输通道. 在模拟太阳光照射下, 所制备的B-CTF-Ti-MOF由于高效的电荷转移和组分之间的紧密接触表现出较好的析氢活性(1975 µmol^.g^‒1.h^‒1), 且重复多次后仍能保持稳定的氢气析出. 此外, 由于羧酸基团在金属有机骨架的合成过程中具有较强且多样的桥联配位能力, 使得这种原位配体功能化的合成策略具有普适性和稳定性. 综上, 本文为COF/MOF多孔复合材料的制备提供了新的思路, 并为其他具有挑战性的材料合成领域提供了理论基础.

关键词: 金属有机骨架, 共价有机骨架, COF/MOF复合物, 原位, 析氢

Abstract:

The development of novel porous materials have attracted significant attention owing to its possible application in several fields. In this study, we designed a novel covalent organic framework-metal-organic framework (COF-MOF) material through an in-situ ligand self-assembly method. The in-situ modified ligands not only act as nucleation sites to form Ti-MOF, but also as a channel to rapidly transfer photogenerated electrons without introducing additional chemical bonds. The photocatalytic hydrogen production rate achieved over B-CTF-Ti-MOF(1:1) was 1975 µmol·g^-1·h^-1 with an apparent quantum efficiency of 4.76%, which is 11.8 times higher than that of the pure CTF-1. In addition, compared with the sample prepared by separating the ligands (CTF-1/Ti-MOF), B-CTF-Ti-MOF shows excellent activity and stability. Finally, a reasonable photocatalytic mechanism was proposed using the results of electrochemical tests and spectral analyses. This study provides a universal method for the construction of highly efficient and stable COF/MOF materials with excellent properties.

Key words: Metal-organic frameworks, Covalent organic frameworks, COF/MOF hybrid, In-situ, Hydrogen evolution

郑灵玲, 张龙帅, 陈颖, 田磊, 江训恒, 谌莉莎, 邢秋菊, 刘小真, 吴代赦, 邹建平. 原位配体功能化策略制备共价金属有机骨架促进其析氢反应[J]. 催化学报, 2022, 43(3): 811-819.

Ling-Ling Zheng, Long-Shuai Zhang, Ying Chen, Lei Tian, Xun-Heng Jiang, Li-Sha Chen, Qiu-Ju Xing, Xiao-Zhen Liu, Dai-She Wu, Jian-Ping Zou. A new strategy for the fabrication of covalent organic framework-metal-organic framework hybrids via in-situ functionalization of ligands for improved hydrogen evolution reaction activity[J]. Chinese Journal of Catalysis, 2022, 43(3): 811-819.

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链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(21)63892-5

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图/表 6

Scheme 1. Schematic of the B-CTF-Ti-MOF composite preparation process.

Fig. 1. SEM images of CTF-1 (a), Ti-MOF (b), and B-CTF-Ti-MOF (c); (d?f) TEM images of B-CTF-Ti-MOF; C, N, O, and Ti EDS maps (g), HRTEM image (h), and SAED pattern (i) of B-CTF-Ti-MOF.

Fig. 2. XRD patterns (a) and FTIR spectra (b) of Ti-MOF, CTF-1, B-CTF-1, and B-CTF-Ti-MOF; XPS spectra: survey (c), C 1s region (d), O 1s region (e), and Ti 2p region (f) for CTF-1, B-CTF-1, Ti-MOF, and B-CTF-Ti-MOF.

Fig. 3. Photocatalytic H2 production over the as-obtained samples under simulated sunlight irradiation: (a) without co-catalyst; (b) with 3 wt% Pt added as co-catalyst. (c) The wavelength dependence of the H2 evolution rate of B-CTF-Ti-MOF; (d) Recyclability of the H2 evolution over B-CTF-Ti-MOF and CTF-1/Ti-MOF irradiated under simulated sunlight.

Fig. 4. (a) UV-vis DRS spectra of the samples; Steady-state PL spectra (b), time-resolved fluorescence decay spectra (c), and electrochemical impedance spectra (d) of Ti-MOF, B-CTF-1, CTF-1/Ti-MOF, and B-CTF-Ti-MOF.

Scheme 2. Possible photocatalytic mechanism for the H2 evolution reaction over B-CTF-Ti-MOF under light irradiation.

参考文献

[1]	M. Ding, R. W. Flaig, H. L. Jiang, O. M. Yaghi, Chem. Soc. Rev., 2021, 48, 2783-2828.
[2]	S. S. Li, J. R. Sun, J. Q. Guan, Chin. J. Catal., 2021, 42, 511-556.
[3]	L. J. Kong, M. Zhong, W. Shuang, Y. H. Xu, X. H. Bu, Chem. Soc. Rev., 2020, 49, 2378-2407.
[4]	X. H. Jiang, L. S. Zhang, H. Y. Liu, D. S. Wu, F. Y. Wu, L. Tian, L. L. Liu, J. P. Zou, S. L. Luo, B. B. Chen, Angew. Chem. Int. Ed., 2020, 59, 23112-23116.
[5]	M. Zhu, L. S. Zhang, S. S. Liu, D. K. Wang, Y. C. Qin, Y. Chen, W. L. Dai, Y. H. Wang, Q. J. Xing, J. P. Zou, Chin. Chem. Lett., 2020, 31, 1961-1965.
[6]	A. Acharjya, L. L. Dunbar, J. Roeser, P. Pachfule, A. Thomas, J. Am. Chem. Soc., 2020, 142, 14033-14038.
[7]	F. C. Leng, H. Liu, M. L. Ding, Q. P. Lin, H. L. Jiang, ACS Catal., 2018, 8, 4583-4590.
[8]	X. Y. Guan, H. Li, Y. C. Ma, M. Xue, Q. R. Fang , Y. S. Yan, V. Valtchev, S. L. Qiu, Nat. Chem., 2019, 11, 587-594.
[9]	H. Hua, Q. Q. Yan, R. L. Ge, Y. N. Gao, Chin. J. Catal., 2018, 39, 1167-1179.
[10]	C. S. Diercks, O. M. Yaghi, Science, 2017, 355, 923.
[11]	J. Q. Dong, X. Han, Y. Liu, H. Y. Li, Y. Cui, Angew. Chem. Int. Ed., 2020, 59, 13722-13733.
[12]	C. G. Pei, M. S. Choi, X. Yu, H. G. Xue, B. Y. Xia, H. S. Park, J. Mater. Chem. A, 2021, 9, 8832-8869.
[13]	Y. X. Wang, X. Zhao, H. J. Yang, X. H. Bu, Y. Wang, X. X. Jia, J. P. Li, P. Y. Feng, Angew. Chem. Int. Ed., 2019, 58, 6316-6320.
[14]	S. J. He, Q. F. Rong, H. Y. Niu, Y. Q. Cai, Appl. Catal. B, 2019, 247, 49-56.
[15]	H. X. Zhang, Q. L. Hong, J. Li, F. Wang, X. S. Huang, S. M. Chen, W. G. Tu, D. S. Yu, R. Xu, T. H. Zhou, J. Zhang, Angew. Chem. Int. Ed., 2019, 58, 11752-11756.
[16]	A. Kuc, M. A. Springer, K. Batra, R. J. Mosqueda, C. Wöll, T. Heine, Adv. Funct. Mater., 2020, 30, 1908004.
[17]	H. J. Peng, J. Raya, F. Richard, W. Baaziz, O. Ersen, A. Ciesielski, P. Samorì, Angew. Chem. Int. Ed., 2020, 59, 19602-19609.
[18]	D. R. Sun, S. W. Jang, S. J. Yim, L. Ye, D. P. Kim, Adv. Funct. Mater., 2018, 30, 1707110.
[19]	Y. W. Peng, M. T. Zhao, B. Chen, Z. C. Zhang, Y. Huang, F. N. Dai, Z. C. Lai, X. Y. Cui, C. L. Tan, H. Zhang, Adv. Mater., 2017, 30, 1705454.
[20]	F. M. Zhang, J. L. Sheng, Z. D. Yang, X. J. Sun, H. L. Tang, M. Lu, H. Dong, F. C. Shen, J. Liu, Y. Q. Lan, Angew. Chem. Int. Ed., 2018, 57, 12106-12110.
[21]	F. Li, D. K. Wang, Q. J. Xing, G. Zhou, S. S. Liu, Y. Li, L. L. Zheng, P. Ye, J. P. Zou, Appl. Catal. B, 2019, 243, 621-628.
[22]	S. W. Lv, J. M. Liu, C. Y. Li, N. Zhao, Z. H. Wang, S. Wang, Chemosphere, 2020, 243, 125378.
[23]	S. Kuecken, A. Acharjya, L. Zhi, M. Schwarze, R. Schomacker, A. Thomas, Chem. Commun., 2017, 53, 5854-5857.
[24]	L. L. Zheng, D. K. Wang, S. L. Wu, X. H. Jiang, J. Zhang, Q. J. Xing, J. P. Zou, S. L. Luo, J. Mater. Chem. A, 2020, 8, 25425-25430.
[25]	M. Jahan, Q. L. Bao, J. X. Yang, K. P. Loh, J. Am. Chem. Soc., 2010, 132, 14487-14495.
[26]	A. Q. Hu, Q. Q. Pang, C. Tang, J. X. Bao, H. Q. Liu, K. Ba, S. H. Xie, J. Chen, J. H. Chen, Y. W. Yue, Y. Tang, Q. W. Li, Z. Z. Sun, J. Am. Chem. Soc., 2019, 41, 11322-11327.
[27]	G. Zhou, L. L. Zheng, D. K. Wang, Q. J. Xing, F. Li, P. Ye, X. Xiao, Y. Li, J. P. Zou, Chem. Commun., 2019, 55, 4150-4153.
[28]	M. Oveisi, M. A. Asli, N. M. Mahmoodi, J. Hazard. Mater., 2018, 347, 123-140.
[29]	X. Y. Chen, X. Peng, L. B. Jiang, X. Z. Yuan, H. B. Yu, H. Wang, J. Zhang, Q. Xia, Chem. Eng. J., 2020, 395, 125080.
[30]	Z. Z. Yang, H. Chen, S. Wang, W. Guo, T. Wang, X. Suo, D. E. Jiang, X. Zhu, I. Popovs, S. Dai, J. Am. Chem. Soc., 2020, 14, 6856-6860.
[31]	H. M. Wang, C. Deng, X. L. Li, D. K. Yan, M. X. Xie, S. Zhang, B. Huang, Chem. Eng. J., 2021, 42, 129681.
[32]	P. Wang, Z. L. Yang, Z. W. Wang, C. Y. Xu, L. Huang, S. C. Wang, H. Zhang, A. W. Lei, Angew. Chem. Int. Ed., 2019, 58, 15747-15751.
[33]	D. R. Sun, D. P. Kim, ACS Appl. Mater. Interfaces, 2020, 12, 20589-20595.
[34]	S. Y. Zhang, M. Du, Z. P. Xing, Z. Z. Li, K. Pan, W. Zhou, Appl. Catal. B, 2020, 262, 118202.
[35]	X. He, M. Wu, Z. M. Ao, B. Lai, Y. B. Zhou, T. C. An, S. B. Wang, J. Hazard. Mater., 2021, 403, 124048.
[36]	M. Slouf, R. Skoupy, E. Pavlova, V. Krzyzanek, Nanomaterials, 2021, 11, 962.
[37]	C. T. Saouma, S. Richard, S. Smolders, M. F. Delley, R. Ameloot, F. Vermoortele, D. E. D. Vos, J. M. Mayer, J. Am. Chem. Soc., 2018, 140, 16184-16189.
[38]	W. T. Zhang, W. G. Huang, J. Y. Jin, Y. H. Gan, S. J. Zhang, Appl. Catal. B, 2021, 292, 120197.
[39]	Y. J. Tong, L. D. Yu, J. T. Zheng, G. F. Liu, Y. X. Ye, S. M. Huang, G. S. Chen, H. S. Yang, C. Wen, S. B. Wei, J. Q. Xu, F. Zhu, J. Pawliszyn, G. F. Ouyang, Anal. Chem., 2020, 92, 15550-15557.
[40]	F. Yu, L. C. Wang, Q. J. Xing, D. K. Wang, X. H. Jiang, G. C. Li, A. M. Zheng, F. R. Ai, J. P. Zou, Chin. Chem. Lett., 2020, 31, 1648-1653.
[41]	H. H. Liu, D. L. Chen, Z. Q. Wang, H. J. Jing, R. Zhang, Appl. Catal. B, 2017, 203, 300.
[42]	H. Y. Liu, J. Chu, Z. L. Yin, X. Cai, L. Zhuang, H. X. Deng, Chem, 2018, 4, 1696-1709.
[43]	C. Zhao, Z. H. Wang, X. Chen, H. Y. Chu, H. F. Fu, C. C. Wang, Chin. J. Catal., 2020, 41, 1186-1197.
[44]	C. Qi, L. Xu, J. Wang, H. L. Li, C. C. Zhao, L. N. Wang, T. X. Liu, ACS Sustainable Chem. Eng., 2020, 8, 12968-12975.
[45]	X. Ma, K. Y. Chen, B. Niu, Y. Li, L. Wang, J. W. Huang, H. D. She, Q. Z. Wang, Chin. J. Catal., 2020, 41, 1535-1543.
[46]	M. Curti, A. Kirsch, L. I. Granone, F. Tarasi, G. L. Robledo, D. W. Bahnemann, M. M. Murshed, T. M. Gesing, C. B. Mendive, ACS Catal., 2018, 8, 8844-8855.
[47]	J. P. Wang, Y. N. Song, J. Hu, Y. Li, Z. Y. Wang, P. Yang, G. Wang, Q. Ma, Q. D. Che, Y. Dai, B. B. Huang, Appl. Catal. B, 2019, 251, 94-101.
[48]	J. M. Bolts, M. S. Wrighton, J. Phys. Chem., 1976, 80, 2641-2645.
[49]	G. L. Xu, H. B. Zhang, J. Wei, H. X. Zhang, X. Wu, Y. Li, C. S. Li, J. Zhang, J. H. Ye, ACS Nano, 2018, 12, 5333-5340.
[50]	Q. L. Xu, L. Y. Zhang, B. Cheng, J. J. Fan, J. G. Yu, Chem, 2020, 6, 1543-1599.
[51]	F. Y. Xu, K. Meng, B. Cheng, S. Y. Wang, J. S. Xu, J. G. Yu, Nat Commun., 2020, 11, 4613.
[52]	J. Wang, G. H. Wang, B. Cheng, J. G. Yu, J. J. Fan, Chin. J. Catal., 2020, 42, 56-68.

原位配体功能化策略制备共价金属有机骨架促进其析氢反应

A new strategy for the fabrication of covalent organic framework-metal-organic framework hybrids via in-situ functionalization of ligands for improved hydrogen evolution reaction activity

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[15]	吴则星, 高玉肖, 王子璇, 肖卫平, 王新萍, 李彬, 李镇江, 刘晓斌, 马天翼, 王磊. 表面富集的超小铂纳米颗粒耦合缺陷磷化钴用于高效的电催化水分解和柔性锌空气电池[J]. 催化学报, 2023, 46(3): 36-47.