F-N共掺杂调控多孔碳实现锌空气电池5300 h超稳定ORR催化

doi:10.1016/S1872-2067(25)64835-2

催化学报 ›› 2025, Vol. 79: 100-111.DOI: 10.1016/S1872-2067(25)64835-2

F-N共掺杂调控多孔碳实现锌空气电池5300 h超稳定ORR催化

刘保发^a, 潘未接^a, 黄志洋^a, 赵熠^a, 罗祖洋^a, 塔伊尔詹•泰勒•伊西姆詹^c^,^*(), 王宝^b^,^*(), 杨秀林^a^,^*()

^a广西师范大学物理科学与技术学院, 化学与药学学院, 广西低碳能源材料重点实验室, 广西桂林541004, 中国
^b中国科学院过程工程研究所, 纳米科学卓越创新中心, 北京100190, 中国
^c阿卜杜拉国王科技大学, 沙特阿拉伯基础工业公司, 图瓦23955-6900, 沙特阿拉伯

收稿日期:2025-05-14 接受日期:2025-08-01 出版日期:2025-12-05 发布日期:2025-10-27
通讯作者: 塔伊尔詹•泰勒•伊西姆詹,王宝,杨秀林
基金资助:
国家自然科学基金(52363028);国家自然科学基金(21965005);广西自然科学基金(2021GXNSFAA076001);广西科技基地和人才课题(GUIKE AD23023004);广西科技基地和人才课题(GUIKE AD20297039)

Unlocking 5300-h ultrastable metal-free ORR catalysts for Zn-air batteries via F-N co-doped tailored carbon pore architectures and synergistic adsorption modulation

Baofa Liu^a, Weijie Pan^a, Zhiyang Huang^a, Yi Zhao^a, Zuyang Luo^a, Tayirjan Taylor Isimjan^c^,^*(), Bao Wang^b^,^*(), Xiulin Yang^a^,^*()

^aSchool of Physical Sciences and Technology, Guangxi Key Laboratory of Low Carbon Energy Materials, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, Guangxi, China
^bCAS Center for Excellence in Nanoscience, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
^cSaudi Arabia Basic Industries Corporation (SABIC) at King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia

Received:2025-05-14 Accepted:2025-08-01 Online:2025-12-05 Published:2025-10-27
Contact: Tayirjan Taylor Isimjan, Bao Wang, Xiulin Yang
Supported by:
National Natural Science Foundation of China(52363028);National Natural Science Foundation of China(21965005);Natural Science Foundation of Guangxi Province(2021GXNSFAA076001);Guangxi Technology Base and Talent Subject(GUIKE AD23023004);Guangxi Technology Base and Talent Subject(GUIKE AD20297039)

摘要/Abstract

摘要：

面对日益严峻的环境污染与能源短缺挑战, 开发高效、低成本的绿色能源转换与存储技术, 已成为解决当前能源困境的关键路径. 可充电锌空气电池(ZABs)因其超高理论能量密度(1086 Wh kg^-1)、环境友好性、内在安全性和零碳排放等特性备受关注. 然而, ZABs的实际输出性能受限于空气阴极缓慢的氧还原反应(ORR), 其高过电位导致显著低的电池效率与功率输出. ORR涉及多电子转移过程且本征动力学缓慢, 亟需高效电催化剂加速该反应. 铂族金属(PGM)催化剂(如Pt/C)虽具有高活性与低过电位, 但其高昂成本与资源稀缺性严重制约ZABs的经济性与规模化应用. 开发低成本、高性能的非PGM催化剂对推动下一代能源技术至关重要.
本文通过气相蚀刻和牺牲模板法设计了氮、氟共掺杂的中空多孔碳球(FNC). 通过调整氟化铵与碳球的比例以及退火温度, 可以有效地对催化剂进行改性. 改性后的催化剂具有较高的比表面积、丰富的介孔以及高比例的半离子碳-氟键和吡啶氮, 协同提升了ORR活性和稳定性. 电化学测试表明, 该催化剂在0.1 mol L^‒1 KOH中的ORR性能可与商业Pt/C催化剂相媲美, 其半波电位达到0.87 V (vs. RHE), 并展现出显著提高的稳定性(在循环21 h后仅衰减6.9%). 基于FNC-900卓越的ORR性能, 构建了具有流动电解质的ZABs, 作为液态电解质锌空气电池的空气阴极, FNC-900开路电压达到1.579 V且峰值功率密度可达172 mW cm^-2. 同时在5 mA cm^-2的恒定电流密度下实现超过5300 h的出色循环稳定性. 此外, FNC空气阴极在高电流密度(10和20 mA cm^-2)下能够稳定运行超过1328和773 h. 组装的柔性以及纽扣ZAB也具有出色的峰值功率密度和稳定性. 理论计算和原位表征表明, 碳和氟之间显著的电负性差异有利于在吡啶氮附近形成坚固的碳-氟键, 氟的掺入重构了吡啶氮的电子结构, 有效地优化了氧中间体的吸附/解吸, 解决传统氮掺杂碳氧吸附能不足的问题, 提高了ORR速率. 晶体轨道哈密顿分析表明, 氟掺杂减少了费米能级处的反键态, 从而提高了键强度, 获得了更高的稳定性.
综上, 本文通过引入杂原子来调节碳材料催化剂这一概念和策略, 为未来设计具有高活性和高稳定性的无金属氧还原反应催化剂提供了指导. 组装的水性和柔性ZABs均展现出较好的性能和稳定性, 这突显了其在下一代可穿戴电子设备和可持续能源存储系统中的潜力.

关键词: 杂原子掺杂, 无金属碳材料, 氧还原反应, 稳定性, 锌空气电池

Abstract:

Designing exceptional-performance and long-lasting oxygen reduction reaction (ORR) catalysts is a critical challenge for the development of rechargeable Zn-air batteries (ZABs). In this study, we introduce a metal-free ORR catalyst composed of F-N co-doped hollow carbon (FNC), specifically engineered to address the limitations of conventional catalysts. The FNC catalysts were synthesized using a template-assisted pyrolysis method, resulting in a hollow, porous architecture with a high specific surface area and numerous active sites. Concurrently, F doping optimized the electronic configuration of pyridinic nitrogen. The introduction of C-F bonds reduced the reaction energy barrier, and the resulting N-C-F configuration enhanced the stability of the nitrogen center. The catalyst exhibits outstanding ORR activity in alkaline media, exhibiting a half-wave potential (E_1/2) of 0.87 V, surpassing that of commercial Pt/C (E_1/2 = 0.85 V). When applied to both aqueous and flexible ZAB configurations, the FNC catalyst achieved peak power densities of 172 and 85 mW cm^-2, respectively, along with exceptional cycling stabilities exceeding 5300 and 302 h, respectively. This study establishes a novel approach for designing metal-free ORR catalysts and next-generation ZABs, particularly for use in flexible and wearable microelectronic devices.

Key words: Heteroatom doping, Metal-free carbon, Oxygen reduction reaction, Stability, Zn-air batteries

刘保发, 潘未接, 黄志洋, 赵熠, 罗祖洋, 塔伊尔詹•泰勒•伊西姆詹, 王宝, 杨秀林. F-N共掺杂调控多孔碳实现锌空气电池5300 h超稳定ORR催化[J]. 催化学报, 2025, 79: 100-111.

Baofa Liu, Weijie Pan, Zhiyang Huang, Yi Zhao, Zuyang Luo, Tayirjan Taylor Isimjan, Bao Wang, Xiulin Yang. Unlocking 5300-h ultrastable metal-free ORR catalysts for Zn-air batteries via F-N co-doped tailored carbon pore architectures and synergistic adsorption modulation[J]. Chinese Journal of Catalysis, 2025, 79: 100-111.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(25)64835-2

https://www.cjcatal.com/CN/Y2025/V79/I12/100

图/表 6

Fig. 1. Preparation of FNC catalyst. (a) Schematic of the preparation of FNC-900. SEM (b) and TEM (c,d) images (inset: SAED image). (e) HAADF-STEM and corresponding elemental mapping images of FNC-900. (f) N2 adsorption-desorption isotherms. (g) Pore size distribution curves. (h) Bubble contact angle images. (i) Raman spectra. (j) TGA curves of SiO2@NC mixed with NH4F in a 1:10 ratio.

Fig. 2. High-resolution C 1s (a), F 1s (b), and N 1s (c) XPS spectra of FNC-800, FNC-900, and FNC-1000. (d) Content of different C?F bonds. (e) Relative contents of different N species. (f) Valance band and secondary electron tail threshold spectra.

Fig. 3. Electrochemical tests of FNC-900 and other reference catalysts. CV curves (a), LSV polarization curves (b), and corresponding Tafel slope plots (c). (d) jk curves of as-prepared catalysts. (e) Comparison of the ORR activities of FNC-900 and recently reported catalysts. (f) LSV curves of FNC-900 at various rotation rates and K-L plots (inset). (g) H2O2 yield (%) and electron transfer number (n). (h) Cdl values of NC, FNC-800, FNC-900, and FNC-1000. (i) Stability test of FNC-900 and 20 wt% Pt/C in 0.1 mol L?1 KOH at a rotating speed of 1600.

Fig. 4. Performance of aqueous ZABs. (a) Schematic of a self-assembled ZAB with flowing electrolyte. (b) OCV plots (annotated inset: multimeter-measured OCV and ZAB-driven LED illumination). (c) Discharge polarization curves and power densities. (d) Discharge curves at various current densities, with each step lasting for 20 min (x indicates different current density values of 2?50 mA cm-2). (e) Performance comparison of an FNC-900 assembled ZAB and recently reported catalysts in literature. (f) Charge-discharge cycle curves at a current density of 5 mA cm-2.

Fig. 5. Performance of solid-state ZABs. (a) OCV of flexible ZABs. Inset: Schematic of a flexible ZAB and an image of the flexible ZAB powering an LED light. (b) Discharging capacity plots at a constant current density under 5 mA cm-2. Inset: an image of a flexible ZAB powering a mini fan. (c) Discharge polarization curves and power densities. (d) Charge-discharge cycle curves at a current density of 1 mA cm-2. Inset: Image of a flexible ZAB lighting up an LED panel at different bending angles. (e) OCV of a button-type all-solid-state ZAB. Insect: Simplified schematic of the button-type all-solid-state ZAB. (f) Image of a coin cell employing FNC-900 powering a mini fan and an LED panel. (g) Power density and (h) cycling stability of coin cells.

Fig. 6. Theoretical and in-situ studies unveil the mechanism of enhanced ORR activity. (a) In-situ Raman spectrum of FNC-900 obtained in the potential range of 0.3-1.0 V (vs. RHE) during the ORR process. (b) In-situ ATR-IRAS spectrum recorded in the potential range of 0.3-1.1 V (vs. RHE) during ORR. (c) Charge density difference between FNC-900 and NC (yellow and cyan areas display the accumulation and depletion of charges, respectively). (d) Gibbs free energy profiles for FNC-pyridinic-N, FNC-pyrrolic-N, and NC-pyridinic-N. (e) DOS plots for FNC and NC. (f) COHP analysis of N active sites and O atoms of *O intermediates.

参考文献

[1]	R. F. Service, Science, 2021, 372, 890-891.
[2]	L. Yang, X. Zhang, L. Yu, J. Hou, Z. Zhou, R. Lv, Adv. Mater., 2022, 34, 2105410.
[3]	L. Yang, J. Shui, L. Du, Y. Shao, J. Liu, L. Dai, Z. Hu, Adv. Mater., 2019, 31, 1804799.
[4]	X. Hui, P. Zhang, J. Li, D. Zhao, Z. Li, Z. Zhang, C. Wang, R. Wang, L. Yin, Adv. Energy Mater., 2022, 12, 2201393.
[5]	M. Guo, Z. Huang, Y. Qu, L. Wang, H. Li, T. T. Isimjan, X. Yang, Appl. Catal. B, 2023, 320, 121991.
[6]	W. Sun, F. Wang, B. Zhang, M. Zhang, V. Küpers, X. Ji, C. Theile, P. Bieker, K. Xu, C. Wang, M. Winter, Science, 2021, 371, 46-51.
[7]	Y. Zhao, J. Zhang, X. Guo, X. Cao, S. Wang, H. Liu, G. Wang, Chem. Soc. Rev., 2023, 52, 3215-3264.
[8]	Y. Liu, Z. Chen, Z. Li, N. Zhao, Y. Xie, Y. Du, J. Xuan, D. Xiong, J. Zhou, L. Cai, Y. Yang, Nano Energy, 2022, 99, 107325.
[9]	S. Sarkar, A. Biswas, E. E. Siddharthan, R. Thapa, R. S. Dey, ACS Nano, 2022, 16, 7890-7903.
[10]	X. Wen, Q. Zhang, J. Guan, Coord. Chem. Rev., 2020, 409, 213214.
[11]	L. Peng, C.-T. Hung, S. Wang, X. Zhang, X. Zhu, Z. Zhao, C. Wang, Y. Tang, W. Li, D. Zhao, J. Am. Chem. Soc., 2019, 141, 7073-7080.
[12]	X.-H. Yu, J.-L. Yi, R.-L. Zhang, F.-Y. Wang, L. Liu, Front. Chem. Sci. Eng., 2021, 15, 1380-1407.
[13]	Y. Zhang, K. Fugane, T. Mori, L. Niu, J. Ye, J. Mater. Chem., 2012, 22, 6575-6580.
[14]	X. Wang, Y. Liu, Z. Liu, Z. Li, T. Zhang, Y. Cheng, L. Lei, B. Yang, Y. Hou, Chin. Chem. Lett., 2024, 35, 108926.
[15]	R. Othman, A. L. Dicks, Z. Zhu, Int. J. Hydrogen Energy, 2012, 37, 357-372.
[16]	L. Dai, Y. Xue, L. Qu, H.-J. Choi, J.-B. Baek, Chem. Rev., 2015, 115, 4823-4892.
[17]	D. Gu, Y. Zhou, R. Ma, F. Wang, Q. Liu, J. Wang, Nano-Micro Lett., 2018, 10, 29.
[18]	D. Guo, R. Shibuya, C. Akiba, S. Saji, T. Kondo, J. Nakamura, Science, 2016, 351, 361-365.
[19]	D. Cao, Y. Mu, L. Liu, Z. Mou, S. Chen, W. Yan, H. Zhou, T.-S. Chan, L.-Y. Chang, L. Song, H.-J. Zhai, X. Fan, ACS Nano, 2024, 18, 11474-11486.
[20]	L. Li, N. Qin, H. Ma, J. Liu, Z. Zhu, Y. Huo, L. Zhai, L. Mi, Carbon Neutrality, 2025, 4, 1.
[21]	F. Zhang, D. Zhang, W. Liu, X. Li, Q. Chen, Carbon, 2022, 187, 67-77.
[22]	X. Cao, H. Guo, Y. Han, M. Li, C. Shang, R. Zhao, Q. Huang, M. Li, Q. Zhang, F. Lv, H. Tan, Z. Qian, M. Luo, S. Guo, Nat. Commun., 2025, 16, 2851.
[23]	R.-W. Fu, Z.-H. Li, Y.-R. Liang, F. Li, F. Xu, D.-C. Wu, New Carbon Mater., 2011, 26, 171-179.
[24]	K. Wu, R. Chen, Z. Zhou, X. Chen, Y. Lv, J. Ma, Y. Shen, S. Liu, Y. Zhang, Angew. Chem. Int. Ed., 2023, 62, e202217078.
[25]	Y. Liu, B. Huang, S. Peng, T. Wang, G. Ji, G. Yang, S. Ramakrishna, Inorg. Chem. Front., 2018, 5, 1307-1313.
[26]	Y. Liu, S. Zhou, C. Niu, T. T. Isimjan, Y. Zhu, D. Wang, X. Yang, J. Qiu, B. Wu, Chin. J. Catal., 2025, 72, 266-276.
[27]	Z. Zhao, L. Duan, Y. Zhao, L. Wang, J. Zhang, F. Bu, Z. Sun, T. Zhang, M. Liu, H. Chen, Y. Yang, K. Lan, Z. Lv, L. Zu, P. Zhang, R. Che, Y. Tang, D. Chao, W. Li, D. Zhao, J. Am. Chem. Soc., 2022, 144, 11767-11777.
[28]	L. Peng, J. Yang, Y. Yang, F. Qian, Q. Wang, D. Sun-Waterhouse, L. Shang, T. Zhang, G. I. N. Waterhouse, Adv. Mater., 2022, 34, 2202544.
[29]	M. Liu, J. Qian, Y. Zhao, D. Zhu, L. Gan, L. Chen, J. Mater. Chem. A, 2015, 3, 11517-11526.
[30]	L. Zhang, Y. Dong, L. Li, Y. Shi, Y. Zhang, L. Wei, C.-L. Dong, Z. Lin, J. Su, Nano-Micro Lett., 2025, 17, 88.
[31]	J. Shen, J. Li, B. Li, Y. Zheng, X. Bao, J. Guo, Y. Guo, C. Lai, W. Lei, S. Wang, H. Shao, Energy Environ. Mater., 2023, 6, e12462.
[32]	M. Guo, L. Wang, Z. Huang, H. Li, T. T. Isimjan, X. Yang, ACS Nano, 2024, 18, 17901-17912.
[33]	C.-C. Hou, L. Zou, L. Sun, K. Zhang, Z. Liu, Y. Li, C. Li, R. Zou, J. Yu, Q. Xu, Angew. Chem. Int. Ed., 2020, 59, 7384-7389.
[34]	K. Kim, K. Min, Y. Go, Y. Lee, S. E. Shim, D. Lim, S.-H. Baeck, Appl. Catal. B, 2022, 315, 121501.
[35]	J. Chang, G. Wang, M. Wang, Q. Wang, B. Li, H. Zhou, Y. Zhu, W. Zhang, M. Omer, N. Orlovskaya, Q. Ma, M. Gu, Z. Feng, G. Wang, Y. Yang, Nat. Energy, 2021, 6, 1144-1153.
[36]	W. Yu, H. Wang, S. Liu, N. Mao, X. Liu, J. Shi, W. Liu, S. Chen, X. Wang, J. Mater. Chem. A, 2016, 4, 5973-5983.
[37]	S. Huang, Y. Li, Y. Feng, H. An, P. Long, C. Qin, W. Feng, J. Mater. Chem. A, 2015, 3, 23095-23105.
[38]	J. Liang, L. Liang, B. Zeng, B. Feng, L. Du, X. Qiu, Y. Wang, H. Song, S. Liao, M. Shao, Z. Cui, Angew. Chem. Int. Ed., 2024, 63, e202412825.
[39]	S. G. Peera, A. K. Sahu, A. Arunchander, S. D. Bhat, J. Karthikeyan, P. Murugan, Carbon, 2015, 93, 130-142.
[40]	Y. Chang, J. Chen, J. Jia, X. Hu, H. Yang, M. Jia, Z. Wen, Appl. Catal. B, 2021, 284, 119721.
[41]	W. Wang, S. Liu, C. Min, M. Zeng, H. Shi, R. Shao, S. Liu, Z. Xu, Y. Xia, N. Li, ACS Appl. Energy Mater., 2022, 5, 2036-2044.
[42]	L. Wang, J. Huang, X. Hu, Z. Huang, M. Gao, D. Yao, T. Taylor Isimjan, X. Yang, J. Colloid Interface Sci., 2024, 660, 989-996.
[43]	H. Xia, R. Pang, X. Dong, Q. Liu, J. Chen, E. Wang, J. Li, J. Am. Chem. Soc., 2023, 145, 25695-25704.
[44]	P. Cui, L. Zhao, Y. Long, L. Dai, C. Hu, Angew. Chem. Int. Ed., 2023, 62, e202218269.
[45]	D. Xia, X. Yang, L. Xie, Y. Wei, W. Jiang, M. Dou, X. Li, J. Li, L. Gan, F. Kang, Adv. Funct. Mater., 2019, 29, 1906174.
[46]	G. Zhang, W. Yi, Y. Cao, S. Zhang, X. Liu, J. Mater. Chem. A, 2024, 12, 14801-14808.
[47]	Z. Li, S. Ji, H. Liu, C. Xu, C. Guo, X. Lu, H. Sun, S. Dou, S. Xin, J. H. Horton, C. He, Adv. Funct. Mater., 2024, 34, 2314444.
[48]	X. Wei, S. Song, W. Cai, X. Luo, L. Jiao, Q. Fang, X. Wang, N. Wu, Z. Luo, H. Wang, Z. Zhu, J. Li, L. Zheng, W. Gu, W. Song, S. Guo, C. Zhu, Chem, 2023, 9, 181-197.
[49]	M. Xiao, L. Gao, Y. Wang, X. Wang, J. Zhu, Z. Jin, C. Liu, H. Chen, G. Li, J. Ge, Q. He, Z. Wu, Z. Chen, W. Xing, J. Am. Chem. Soc., 2019, 141, 19800-19806.
[50]	Z. Luo, J. Gong, Q. Li, F. Wei, B. Liu, T. Taylor Isimjan, X. Yang, Chem. Eur. J., 2024, 30, e202303943.
[51]	X. Wang, L. Zhao, X. Li, Y. Liu, Y. Wang, Q. Yao, J. Xie, Q. Xue, Z. Yan, X. Yuan, W. Xing, Nat. Commun., 2022, 13, 1596.
[52]	M. Liu, L. Wang, L. Zhang, Y. Zhao, K. Chen, Y. Li, X. Yang, L. Zhao, S. Sun, J. Zhang, Small, 2022, 18, 2104934.
[53]	N. Wang, C. Meng, B. Wang, X. Tan, Y. Wan, Y. Yang, D. Kong, W. Wang, F. Cao, A. J. Fielding, L. Li, M. Wu, H. Hu, Natl. Sci. Rev., 2025, 12, nwaf061.
[54]	S. Chen, T. Luo, X. Li, K. Chen, J. Fu, K. Liu, C. Cai, Q. Wang, H. Li, Y. Chen, C. Ma, L. Zhu, Y. R. Lu, T. S. Chan, M. Zhu, E. Cortés, M. Liu, J. Am. Chem. Soc., 2022, 144, 14505-14516.
[55]	X. Zhu, X. Tan, K.-H. Wu, S.-C. Haw, C.-W. Pao, B.-J. Su, J. Jiang, S. C. Smith, J.-M. Chen, R. Amal, X. Lu, Angew. Chem. Int. Ed., 2021, 60, 21911-21917.
[56]	J. Bai, X. Guan, H. Qu, L. Liang, C. Ru, X. Gong, Z. Jin, M. Xiao, C. Liu, W. Xing, ACS Energy Lett., 2025, 10, 2743-2751.
[57]	X. Liu, A. Sau, A. R. Green, M. V. Popescu, N. F. Pompetti, Y. Li, Y. Zhao, R. S. Paton, N. H. Damrauer, G. M. Miyake, Nature, 2025, 637, 601-607.
[58]	K. Leng, J. Zhang, Y. Wang, D. Li, L. Bai, J. Shi, X. Li, L. Zheng, J. Bai, Y. Qu, Adv. Funct. Mater., 2022, 32, 2205637.
[59]	W. Zhou, H. Su, W. Cheng, Y. Li, J. Jiang, M. Liu, F. Yu, W. Wang, S. Wei, Q. Liu, Nat. Commun., 2022, 13, 6414.
[60]	M. Jiang, C. Fu, R. Cheng, W. Zhang, T. Liu, R. Wang, J. Zhang, B. Sun, Adv. Sci., 2020, 7, 2000747.
[61]	M. Li, H. Zhu, Q. Yuan, T. Li, M. Wang, P. Zhang, Y. Zhao, D. Qin, W. Guo, B. Liu, X. Yang, Y. Liu, Y. Pan, Adv. Funct. Mater., 2023, 33, 2210867.
[62]	R. Su, X. Tao, K. Zheng, L. Jiao, C. Zhang, R. Yang, H. Xie, X. Meng, C. Xu, Carbon, 2024, 225, 119125.
[63]	Y. Guo, P. Yuan, J. Zhang, Y. Hu, I. S. Amiinu, X. Wang, J. Zhou, H. Xia, Z. Song, Q. Xu, S. Mu, ACS Nano, 2018, 12, 1894-1901.
[64]	Z. Lu, Z. Li, S. Huang, J. Wang, R. Qi, H. Zhao, Q. Wang, Y. Zhao, Appl. Surf. Sci., 2020, 507, 145154.
[65]	J. Zhu, A. S. Childress, M. Karakaya, S. Dandeliya, A. Srivastava, Y. Lin, A. M. Rao, R. Podila, Adv. Mater., 2016, 28, 7185-7192.
[66]	D.-H. Lim, J. Wilcox, J. Phys. Chem. C, 2012, 116, 3653-3660.
[67]	Y. Li, J. Xu, F. Lan, Y. Wang, H. Jiang, X. Wu, Y. Huang, R. Li, Q. Jiang, D. Gao, P. Zhu, S. Zhao, Y. Zhao, F. Wang, L. Zhang, L. Zhang, R. Zhang, Angew. Chem. Int. Ed., 2025, 64, e202420481.

F-N共掺杂调控多孔碳实现锌空气电池5300 h超稳定ORR催化

Unlocking 5300-h ultrastable metal-free ORR catalysts for Zn-air batteries via F-N co-doped tailored carbon pore architectures and synergistic adsorption modulation

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 6

参考文献

相关文章 15

编辑推荐

Metrics

[1]	王舟舟, 周前程, 罗丽, 史雅然, 李浩然, 王春春, 林可聖, 王成思, 朱利兵, 韩凌云, 邢卓, 余颖. 钨掺杂稳定钼酸钴的钴-氧-钼点对点连接结构用于中性析氧反应[J]. 催化学报, 2025, 76(9): 146-158.
[2]	余成文, 梁乐程, 穆张岩, 尹绍祺, 刘欲文, 陈胜利. FeNC层稳定的L1₀-PtFe金属间纳米颗粒用于高效氧还原[J]. 催化学报, 2025, 75(8): 125-136.
[3]	王刚, Imran Muhammad, 阎慧敏, 李隽, 王阳刚. 用杂原子调控Ni单原子催化剂的局部环境以实现高效CO₂电还原[J]. 催化学报, 2025, 74(7): 120-129.
[4]	衣启松, 林露, 耿华伟, 陈少华, 邵元超, 何平, 刘志峰, 许海梅, 陈铁红, 刘远帅, Valentin Valtchev. 氟离子介导酸性体系合成H-ZSM-5分子筛及其液相环己醇催化转化性能研究[J]. 催化学报, 2025, 74(7): 97-107.
[5]	张昊, 熊小松, 汪涛, 吴宇平. 动态氢插层催化[J]. 催化学报, 2025, 74(7): 1-3.
[6]	李晨浩, 王昊, 王卫卫, 白烁, 公忠彬, 桑勤勤, 张雨晴, 霍锋, 刘艳荣. PtCu纳米枝晶催化剂及其增强质子交换膜燃料电池稳定性研究[J]. 催化学报, 2025, 73(6): 322-333.
[7]	姚瑶, 徐菊萍, 邵敏华. 多晶金表面上析氢反应与氧还原反应的竞争[J]. 催化学报, 2025, 73(6): 271-278.
[8]	李思明, 孙恩样, 魏鹏飞, 赵微, 裴随珠, 陈颖, 杨洁, 陈绘丽, 尹熙, 王旻, 李亚伟. 浸渍离子液体于多孔Fe-N-C电催化剂以改善聚合物电解质燃料电池电极动力学与质量传输[J]. 催化学报, 2025, 72(5): 277-288.
[9]	李如硕, 班涛, 赵丹凤, 胡发杰, 林璟, 黄秀兵, 陶志平, 王戈. 缺陷UiO-66(Ce)负载的具有优化微环境和电子态的镍纳米颗粒用于高效烯烃加氢反应[J]. 催化学报, 2025, 72(5): 344-358.
[10]	陈繁荣, 傅佳驹, 丁亮, 卢晓英, 蒋哲, 张小玲, 胡劲松. 硫锚定策略提升亚3纳米In₂S₃纳米颗粒电还原CO₂至甲酸盐的稳定性[J]. 催化学报, 2025, 71(4): 138-145.
[11]	魏抒豪, 蓝国钧, 邱一洋, 林迪, 孔薇, 李瑛. 乙炔氢氯化非金属碳催化剂的研究进展: 从杂原子掺杂到本征缺陷[J]. 催化学报, 2025, 70(3): 8-43.
[12]	李德正, 刘会敏, 肖雪文, 赵曼淇, 贺德华, 雷一鸣. 碳扩散机制作为有效的稳定性增强策略——以镍基催化剂用于光热催化甲烷干重整为例的研究[J]. 催化学报, 2025, 70(3): 399-409.
[13]	梁超安, 曾波, 冯保林, 史会兵, 张凤岐, 刘建华, 何林, 丁玉晓, 夏春谷. 烯烃氢甲酰化的钴基多相催化体系[J]. 催化学报, 2025, 70(3): 115-141.
[14]	郭昊天, 赵路路, 刘欣宇, 李晶, 王鹏飞, 柳宗琳, 王琳琳, 舒杰, 伊廷锋. 静电纺丝技术与MOFs结合: 推动高性能锌空气电池发展[J]. 催化学报, 2025, 79(12): 32-67.
[15]	简楚倩, 黄逸轩, 高辉, 夏娇娇, 龚文杰, 张茜瑞, 陈晓锋, 刘江, 刘瑛, 陈宇. Rb掺杂的可逆质子陶瓷电化学电池双钙钛矿空气电极的氧还原和制氢电催化性能提升研究[J]. 催化学报, 2025, 78(11): 313-323.