Amine-functionalized boehmite nanoparticle-supported molybdenum and vanadium complexes: Efficient catalysts for epoxidation of alkenes

doi:10.1016/S1872-2067(16)62451-8

Abstract

Abstract:

Boehmite nanoparticles with a high surface area and a high degree of surface hydroxyl groups were covalently functionalized by 3-(trimethoxysilyl)-propylamine to support vanadium-oxo-sulfate and molybdenum hexacarbonyl complexes. These supported catalysts were then characterized by Fourier-transform infrared spectroscopy, powder X-ray diffraction, thermogravimetry and differential thermal analysis, X-ray-photoelectron spectroscopy, elemental analysis, inductively coupled plasma, and transmission electron microscopy techniques. The catalysts were subsequently used for the epoxidation of cis-cyclooctene, and the experimental procedures were optimized. The progress of the reactions was investigated by gas-liquid chromatography. Recycling experiments revealed that these nanocatalysts could be repeatedly used several times for a nearly complete epoxidation of cis-cyclooctene. The optimized experimental conditions were also used successfully for the epoxidation of some other substituted alkenes.

Key words: Boehmite nanoparticles, Heterogeneous catalysts, Hexa-carbonyl molybdenum, Oxo-sulfate vanadium, Epoxidation

Mahdi Mirzaee, Bahram Bahramian, Marieh Mirebrahimi. Amine-functionalized boehmite nanoparticle-supported molybdenum and vanadium complexes: Efficient catalysts for epoxidation of alkenes[J]. Chinese Journal of Catalysis, 2016, 37(8): 1263-1274.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62451-8

https://www.cjcatal.com/EN/Y2016/V37/I8/1263

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