Effect of promoters on the selective hydrogenolysis of glycerol over Pt/W-containing catalysts

doi:10.1016/S1872-2067(16)62479-8

Abstract

Abstract:

Diverse promoters, including noble metals(such as Ru, Ir and Rh) and transition metal oxides(such as Re, La, Fe, Zr, Sn and Ce oxides) were introduced into Pt/WO_x and Pt/WO_x/Al₂O₃ catalysts to investigate the ability of these promoters to modify activity and selectivity during glycerol hydrogenolysis to 1,3-propanediol. Among these, La exhibited the greatest promotional effect; the introduction of 0.1% La to the Pt/WO_x improved activity, selectivity and stability, although the significant increase in selectivity came at the cost of a slight activity loss in the case of the Pt/WO_x/Al₂O₃ catalyst. Transmission electron microscopy, high angle annular dark field scanning tunneling electron microscopy and NH₃-temperature programmed desorption all demonstrated that the introduction of La generates a greater quantity of acidic sites on the catalyst surface, and that the majority of the La species are associated with Pt particles. Most of the other additives resulted in only minimal improvements or even detrimental effects with regard to both activity and selectivity, although some appear to improve the stability of the catalyst.

Key words: Glycerol, Hydrogenolysis, 1,3-propanediol, Tungsten oxide, Promoter

Jia Wang, Nian Lei, Chaojun Yang, Yang Su, Xiaochen Zhao, Aiqin Wang. Effect of promoters on the selective hydrogenolysis of glycerol over Pt/W-containing catalysts[J]. Chinese Journal of Catalysis, 2016, 37(9): 1513-1520.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62479-8

https://www.cjcatal.com/EN/Y2016/V37/I9/1513

References

[1] T. Mizugaki, R. Arundhathi, T. Mitsudome, K. Jitsukawa, K. Kaneda, ACS Sustain. Chem. Eng., 2014, 2, 574-578.
[2] B. Katryniok, S. Paul, F. Dumeignil, ACS Catal., 2013, 3, 1819-1834.
[3] P. Lauriol-Garbay, J. M. M. Millet, S. Loridant, V. Bellière-Baca, P. Rey, J. Catal., 2011, 280, 68-76.
[4] L. L. Ning, Y. J. Ding, W. M. Chen, L. F. Gong, R. H. Lin, Y. Lü, Q. Xin, Chin. J. Catal., 2008, 29, 212-214.
[5] J. Gao, D. Liang, P. Chen, Z. Y. Hou, X. M. Zheng, Catal. Lett., 2009, 130, 185-191.
[6] M. Lo Faro, M. Minutoli, G. Monforte, V. Antonucci, A. S. Aricò, Biomass Bioenergy, 2011, 35, 1075-1084.
[7] S. Authayanun, A. Arpornwichanop, Y. Patcharavorachot, W. Wiyaratn, S. Assabumrungrat, Int. J. Hydrogen Energy, 2011, 36, 267-275.
[8] P. D. Vaidya, A. E. Rodrigues, Chem. Eng. Technol., 2009, 32, 1463-1469.
[9] Y. Nakagawa, M. Tamura, K. Tomishige, J. Mater. Chem. A, 2014, 2, 6688-6702.
[10] Y. L. Wang, J. X. Zhou, X. W. Guo, RSC Adv., 2015, 5, 74611-74628.
[11] R. Arundhathi, T. Mizugaki, T. Mitsudome, K. Jitsukawa, K. Kaneda, ChemSusChem, 2013, 6, 1345-1347.
[12] L. F. Gong, Y. Lü, Y. J. Ding, R. H. Lin, J. W. Li, W. D. Dong, T. Wang, W. M. Chen, Chin. J. Catal., 2009, 30, 1189-1191.
[13] L. J. Liu, Y. H. Zhang, A. Q. Wang, T. Zhang, Chin. J. Catal., 2012, 33, 1257-1261.
[14] Y. Amada, Y. Shinmi, S. Koso, T. Kubota, Y. Nakagawa, K. Tomishige, Appl. Catal. B, 2011, 105, 117-127.
[15] C. H. Deng, L. Leng, J. H. Zhou, X. G. Zhou, W. K. Yuan, Chin. J. Catal., 2015, 36, 1750-1758.
[16] J. Guan, X. F. Chen, G. M. Peng, X. C. Wang, Q. Cao, Z. G. Lan, X. D. Mu, Chin. J. Catal., 2013, 34, 1656-1666.
[17] J. Wang, X. C. Zhao, N. Lei, L. Li, L. L. Zhang, S. T. Xu, S. Miao, X. L. Pan, A. Q. Wang, T. Zhang, ChemSusChem, 2016, 9, 784-790.
[18] D. L. Li, Y. Nakagawa, K. Tomishige, Appl. Catal. A, 2011, 408, 1-24.
[19] J. K. A. Clarke, Chem. Rev., 2002, 11, 41-70.
[20] Y. Amada, S. Koso, Y. Nakagawa, K. Tomishige, MRS Proceedings, 2011, 1326.
[21] Y. Amada, H. Watanabe, M. Tamura, Y. Nakagawa, K. Okumura, K. Tomishige, J. Phy. Chem. C, 2012, 116, 23503-23514.
[22] T. Mizugaki, T. Yamakawa, R. Arundhathi, T. Mitsudome, K. Jitsukawa, K. Kaneda, Chem. Lett., 2012, 41, 1720-1722.
[23] S. H. Zhu, X. Q. Gao, Y. L. Zhu, J. L. Cui, H. Y. Zheng, Y. W. Li, Appl. Catal. B, 2014, 158-159, 391-399.
[24] L. Z. Qin, M. J. Song, C. L. Chen, Green Chem., 2010, 12, 1466-1472.
[25] R. Y. Sun, T. T. Wang, M. Y. Zheng, W. Q. Deng, J. F. Pang, A. Q. Wang, X. D. Wang, T. Zhang, ACS Catal., 2015, 5, 874-883.R. Arundhathi, T. Mitsudome, K. Jitsukawa, K. Kaneda, Chem. Lett., 2012, 41, 1720-1722.
[23] S. H. Zhu, X. Q. Gao, Y. L. Zhu, J. L. Cui, H. Y. Zheng, Y. W. Li, Appl. Catal. B, 2014, 158-159, 391-399.
[24] L. Z. Qin, M. J. Song, C. L. Chen, Green Chem., 2010, 12, 1466-1472.
[25] R. Y. Sun, T. T. Wang, M. Y. Zheng, W. Q. Deng, J. F. Pang, A. Q. Wang, X. D. Wang, T. Zhang, ACS Catal., 2015, 5, 874-883.