Highly photoreactive TiO2 hollow microspheres with super thermal stability for acetone oxidation

doi:10.1016/S1872-2067(17)62952-8

Abstract

Abstract:

TiO₂ hollow microspheres (TiO₂-HMSs) have attracted much attention because of their high photoreactivity, low density, and good permeability. However, anatase TiO₂-HMSs have poor thermal stability. In this study, surface-fluorinated TiO₂-HMSs were assembled from hollow nanoparticles by the hydrothermal reaction of the mixed Ti(SO₄)₂-NH₄HF-H₂O₂ solution at 180℃. The effect of the calcination temperature on the structure and photoreactivity of the TiO₂-HMSs was systematically investigated, which was evaluated by photocatalytic oxidation of acetone in air under ultraviolet irradiation. We found that after calcination at 300℃, the photoreactivity of the TiO₂-HMSs decreases from 1.39×10^-3 min^-1 (TiO₂-HMS precursor) to 0.82×10^-3 min^-1 because of removal of surface-adsorbed fluoride ions. With increasing calcination temperature from 300 to 900℃, the building blocks of the TiO₂-HMSs evolve from truncated bipyramidal shaped hollow nanoparticles to round solid nanoparticles, and the photoreactivity of the TiO₂-HMSs steady increases from 0.82×10^-3 to 2.09×10^-3 min^-1 because of enhanced crystallization. Further increasing the calcination temperature to 1000 and 1100℃ results in a decrease of the photoreactivity, which is ascribed to a sharp decrease of the Brunau-er-Emmett-Teller surface area and the beginning of the anatase-rutile phase transformation at 1100℃. The effect of surface-adsorbed fluoride ions on the thermal stability of the TiO₂-HMSs is also discussed.

Key words: TiO₂ hollow microsphere, Photocatalytic oxidation, Acetone, Fluorine, Thermal stability

Li Liang, Kaining Li, Kangle Lv, Wingkei Ho, Youyu Duan. Highly photoreactive TiO₂ hollow microspheres with super thermal stability for acetone oxidation[J]. Chinese Journal of Catalysis, 2017, 38(12): 2085-2093.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62952-8

https://www.cjcatal.com/EN/Y2017/V38/I12/2085

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Highly photoreactive TiO₂ hollow microspheres with super thermal stability for acetone oxidation

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