Effects of Support Acidity on the Catalytic Performance of Mo/HZSM-5-Al2O3 Catalysts in Olefin Metathesis

doi:10.3724/SP.J.1088.2011.10744

Abstract

Abstract: Mo/HZSM-5-Al₂O₃ catalyst samples, where the HZSM-5 had different Si/Al ratios (12, 42, and 213), were prepared and evaluated in a fixed-bed reactor. Effects of support acidity changes on the catalytic performance of Mo/HZSM-5-Al₂O₃ in the metathesis of ethene and 2-butene to propene were investigated. NH₃ temperature-programmed desorption and pyridine infrared spectra revealed that the differences in support acidity led to the different anchoring modes of Mo species on the composite supports. Quick deactivation phenomena were observed on Mo/HZSM-5-Al₂O₃ (Si/Al = 12) due to the high acidity density of the catalyst. For Mo/HZSM-5-Al₂O₃ (Si/Al = 213), more Mo species dispersed on the alumina in octahedral form and those locating in the zeolite channels existed in the state of (Mo₂O₅)²⁺ clusters evidenced by ultraviolet-visible diffuse reflectance spectroscopy and H₂ temperature-programmed reduction results. Such distribution was linked with the low metathesis activity and the appearance of the induction period on Mo/HZSM-5-Al₂O₃ (Si/Al = 213). Mo/HZSM-5-Al₂O₃ (Si/Al = 42) sample demonstrated the best catalytic activity and reaction stability among the three samples. This was attributed to its suitable acidity amount and optimal distribution of Mo species on the support.

Key words: ethene, butene, metathesis reaction, propene, support acidity, HZSM-5 zeolite, alumina

ZHANG Da-Zhou, LI Xiu-Jie, LIU Sheng-Lin, ZHU Xiang-Xue, XIN Wen-Jie, XIE Su-Juan, ZENG Peng, XU Long-Ya-. Effects of Support Acidity on the Catalytic Performance of Mo/HZSM-5-Al₂O₃ Catalysts in Olefin Metathesis[J]. Chinese Journal of Catalysis, 2011, 32(11): 1747-1754.

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References

1Mol J C. Catal Today, 1999, 51: 289
2Schrock R R. Chem Rev, 2009, 109: 3211
3Mol J C, van Leeuwen P. In: Ertl G, Schüth F, Knözinger H, Weitkamp J eds. Handbook of Heterogeneous Catalysis. 2nd Ed. Weinheim: Wiley-VCH, 2008. 3240
4Mol J C. Green Chem, 2002, 4: 5
5Liu S L, Huang S J, Xin W J, Bai J, Xie S J, Xu L Y. Catal Today, 2004, 93: 471
6黄声骏, 辛文杰, 白杰, 谢素娟, 刘盛林, 徐龙伢. 石油化工 (Huang Sh J, Xin W J, Bai J, Xie S J, Liu Sh L, Xu L Y. Petrochem Technol), 2003, 32: 191
7Liu Sh L, Li X J, Xin W J, Xie S J, Zeng P, Zhang L X, Xu L Y. J Nat Gas Chem, 2010, 19: 482
8Li X J, Zhang W P, Liu S L, Xu L Y, Han X W, Bao X H. J Catal, 2007, 250: 55
9Xu X D, Mol J C, Boelhouwer C. J Chem Soc, Faraday Trans I, 1986, 82: 2707
10Andreini A, Xu X D, Mol J C. Appl Catal, 1986, 27: 31
11Mol J C. J Mol Catal, 1991, 65: 145
12Xu X D, Boelhouwer C, Vonk D, Benecke J I, Mol J C. J Mol Catal, 1986, 36: 47
13Xu X D, Mol J C. J Chem Soc, Chem Commun, 1985: 631
14Schekler-Nahama F, Clause O, Commereuc D, Saussey J. Appl Catal A, 1998, 167: 237
15Li X, Zheng A M, Guan J, Han X W, Zhang W P, Bao X H. Catal Lett, 2010, 138: 116
16Handzlik J. J Mol Catal A, 2010, 316: 106
17Li B, Li S J, Li N, Chen H Y, Zhang W J, Bao X H, Lin B X. Microporous Mesoporous Mater, 2006, 88: 244
18Tessonnier J P, Louis B, Rigolet S, Ledoux M J, Pham-Huu C. Appl Catal A, 2008, 336: 79
19Ma D, Zhang W P, Shu Y Y, Liu X M, Xu Y D, Bao X H. Catal Lett, 2000, 66: 155
20Wang D J, Lunsford J H, Rosynek M P. J Catal, 1997, 169: 347
21Abello M C, Gomez M F, Ferretti O. Appl Catal A, 2001, 207: 421
22Heracleous E, Lemonidou A A, Lercher J A. Appl Catal A, 2004, 264: 73
23Jin F, Li Y D. Catal Today, 2009, 145: 101
24Emeis C A. J Catal, 1993, 141: 347
25Segawa K, Hall W K. J Catal, 1982, 76: 133
26Kiviat F E, Petrakis L. J Phys Chem, 1973, 77: 1232
27Rajagopal S, Marzari J A, Miranda R. J Catal, 1995, 151: 192
28Braun S, Appel L G, Camorim V L, Schmal M. J Phys Chem B, 2000, 104: 6584
29Mosqueira L, Fuentes G A. Mol Phys, 2002, 100: 3055
30Vasenin N T, Anufrienko V F, Ismagilov I Z, Larina T V, Paukshtis E A, Matus E V, Tsikoza L T, Kerzhentsev M A, Ismagilov Z R. Top Catal, 2005, 32: 61
31Solis D, Agudo A L, Ramirez J, Klimova T. Catal Today, 2006, 116: 469
32刘红梅, 徐奕德. 催化学报 (Liu H M, Xu Y D. Chin J Catal), 2006, 27: 319
33Tessonnier J P, Louis B, Walspurger S, Sommer J, Ledoux M J, Pham-Huu C. J Phys Chem B, 2006, 110: 10390
34Han Y W, Lu C Y, Xu D Sh, Zhang Y L, Hu Y, Huang H. Appl Catal A, 2011, 396: 8
35Handzlik J, Ogonowski J, Stoch J, Mikolajczyk M. Catal Lett, 2005, 101: 65
36Handzlik J, Ogonowski J, Stoch J, Mikolajczyk M, Mi-chorczyk P. Appl Catal A, 2006, 312: 213
37Li X J, Zhang W P, Li X, Liu S L, Huang H J, Han X W, Xu L Y, Bao X H. J Phys Chem C, 2009, 113: 8228
38黄慧娟, 刘宪春, 刘盛林, 刘秀梅, 徐龙伢, 韩秀文, 张维萍, 包信和. 催化学报 (Huang H J, Liu X Ch, Liu Sh L, Liu X M, Xu L Y, Han X W, Zhang W P, Bao X H. Chin J Catal), 2010, 31: 186
39Marafi A, Stainslaus A, Hauser A, Matsushita K. Pet Sci Technol, 2005, 23: 385
40Ma D, Wang D Z, Su L L, Shu Y Y, Xu Y D, Bao X H. J Catal, 2002, 208: 260
41Liu H J, Zhang L, Li X J, Huang S J, Liu Sh L, Xin W J, Xie S J, Xu L Y. J Nat Gas Chem, 2009, 18: 331
42Liu H M, Su L L, Wang H X, Shen W J, Bao X H, Xu Y D. Appl Catal A, 2002, 236: 263

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Effects of Support Acidity on the Catalytic Performance of Mo/HZSM-5-Al₂O₃ Catalysts in Olefin Metathesis

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