Research Progress in Vanadium-Free Catalysts for the Selective Catalytic Reduction of NO with NH3

doi:10.3724/SP.J.1088.2011.10315

Abstract

Abstract: Selective catalytic reduction of NO with NH₃ (NH₃-SCR) is a well-proven technique for the removal of NO_x from stationary sources such as coal-fired power plants, and is also one of the most promising techniques for the NO_x elimination from diesel exhaust under oxygen-rich conditions. Due to some inevitable disadvantages of the present V₂O₅-WO₃ (MoO₃)/TiO₂ catalyst for industrial use, many researchers focus on the development of novel, highly efficient, stable, environmental-friendly and vanadium-free NH₃-SCR catalysts. The research progress in the field of vanadium-free NH₃-SCR catalysts is reviewed, including zeolite catalysts (such as Fe-zeolite catalysts and Cu-zeolite catalysts) and oxide catalysts (such as Fe-based oxide catalysts, Mn-based oxide catalysts, and other vanadium-free oxide catalysts). Several aspects in this field, including the evaluation of catalytic performance, the structure analysis of active sites, the improvement of low temperature activity, the study of NH₃-SCR reaction mechanism, the enhancement of H₂O/SO₂ durability, and the feasibility analysis for industrial use, have been discussed in detail. The possible developing orientation and research interests in the field of vanadium-free NH₃-SCR catalysts are previewed.

Key words: selective catalytic reduction, flue gas denitration, diesel exhaust purification, vanadium-free catalyst, zeolite catalyst, oxide catalyst, low temperature activity, reaction mechanism

LIU Fu-Dong, DAN Wen-Po, SHI Xiao-Yan, ZHANG Chang-Bin, HE Hong. Research Progress in Vanadium-Free Catalysts for the Selective Catalytic Reduction of NO with NH3[J]. Chinese Journal of Catalysis, 2011, 32(7): 1113-1128.

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References

这个期刊审稿速度挺快，基本1个月就有结果了。图要求较高，编辑对稿子修改的也挺细致，能发现挺多作者的疏漏。发表出来的文章版面美观，期刊设计的挺漂亮。发表速度也挺快，论文基本从投稿到发表要半年吧。

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