The roles of hydroxyapatite and FeOx in a Au/FeOx-hydroxyapatite catalyst for CO oxidation

doi:10.1016/S1872-2067(12)60590-7

Abstract

Abstract: A FeO_x-modified hydroxyapatite (HAP, Ca₁₀(PO₄)₆(OH)₂)-supported gold catalyst is highly active and stable during CO oxidation at low temperature, and it is also sinter-resistant to calcination at temperature up to 600 ℃. This work used catalyst characterization and activity tests to investigate the roles of the HAP support and FeO_x promoter in CO oxidation. XPS results suggested that a strong interaction between the HAP support and the Au and FeO_x nanoparticles gave the sintering resistance. In situ DRIFT studies revealed that the addition of FeO_x changed the nature of the reaction mechanism and intermediates to promote catalytic activity. TEM and Mössbauer examination of the spent catalysts in combination with the in situ DRIFT results suggested that the better stability of Au/FeO_x-HAP originated from its better prevention of carbonate accumulation.

Key words: Gold, Iron oxide, Hydroxyapatite, Carbon monoxide, Sintering resistance

ZHAO Kunfeng, QIAO Botao, ZHANG Yanjie, WANG Junhu. The roles of hydroxyapatite and FeO_x in a Au/FeO_x-hydroxyapatite catalyst for CO oxidation[J]. Chinese Journal of Catalysis, DOI: 10.1016/S1872-2067(12)60590-7.

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The roles of hydroxyapatite and FeO_x in a Au/FeO_x-hydroxyapatite catalyst for CO oxidation

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