催化学报 ›› 2016, Vol. 37 ›› Issue (10): 1594-1599.DOI: 10.1016/S1872-2067(16)62547-0

• 小综述 • 上一篇    下一篇

含金金属纳米颗粒用于液相化学氢化物催化制氢

杨新春a,b, 徐强a,b   

  1. a 日本国立产业技术综合研究所, 大阪府池田市563-8577, 日本;
    b 神户大学工学研究科, 兵库县神户市滩区657-8501, 日本
  • 收稿日期:2016-04-12 修回日期:2016-05-10 出版日期:2016-10-21 发布日期:2016-10-22
  • 通讯作者: Qiang Xu

Gold-containing metal nanoparticles for catalytic hydrogen generation from liquid chemical hydrides

Xinchun Yanga,b, Qiang Xua,b   

  1. a National Institute of Advanced Industrial Science and Technology(AIST), Ikeda, Osaka 563-8577, Japan;
    b Graduate School of Engineering, Kobe University, Nada Ku, Kobe, Hyogo 657-8501, Japan
  • Received:2016-04-12 Revised:2016-05-10 Online:2016-10-21 Published:2016-10-22
  • Contact: Qiang Xu
  • Supported by:

    This work was supported by Ministry of Economy, Trade and Industry (METI), National Institute of Advanced Industrial Science Technology (AIST) and Kobe University.

摘要:

液相化学氢化物以化学键的形式储存氢能,被认为是一类很有前景的化学储氢材料.液相化学氢化物的大规模应用很大程度上依赖于高效催化系统的开发.含金金属纳米颗粒在用于液相化学氢化物催化制氢中表现出优异的催化性能.本文综述了金纳米颗粒和含金异金属纳米颗粒用于液相氢化物催化制氢的最新研究进展.

关键词: 金催化剂, 制氢, 甲酸, 氨硼烷, 多相催化

Abstract:

Liquid chemical hydrides, which store hydrogen in the form of chemical bonds, are considered one of the most promising classes of hydrogen storage materials. Their application depends heavily on the development of efficient catalytic systems. Gold-containing metal nanoparticles have exhibited excellent catalytic performance for hydrogen generation from liquid chemical hydrides. The present mini-review focuses on recent developments in hydrogen generation from liquid chemical hydrides using gold-nanoparticle and gold-containing heterometallic nanoparticle catalysts.

Key words: Gold catalysts, Hydrogen generation, Formic acid, Ammonia borane, Heterogeneous catalysis