催化学报

催化学报 ›› 2012, Vol. 33 ›› Issue (10): 1736-1741.DOI: 10.3724/SP.J.1088.2012.20756

• 研究论文 • 上一篇    

纳米纤维铁氧化物柱撑蒙脱土可见光助芬顿降解罗丹明B

张世龙1,2, 胡小明2, 王晓韡1, 梁诗景1, 吴棱1,?   

  1. 1福州大学光催化国家重点实验室培育基地, 福建福州 350002; 2江西省地质矿产勘查开发局赣西地质调查大队, 江西南昌 330201
  • 收稿日期:2012-07-28 修回日期:2012-08-14 出版日期:2012-09-28 发布日期:2012-09-28

Photo-Fenton Degradation of RhB over Nano-fibre Iron Oxides Interacted Montmorillonite under Visible Light Irradiation

ZHANG Shilong1,2, HU Xiaoming2, WANG Xiaowei1, LIANG Shijing1, WU Ling1,?   

  1. 1State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, Fujian, China; 2Western Geological Exploration Brigade of Jiangxi Geology & Mineral Resources Development Bureau, Nanchang 330201, Jiangxi, China
  • Received:2012-07-28 Revised:2012-08-14 Online:2012-09-28 Published:2012-09-28

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939

被引次数

13

摘要： 利用简单的阳离子交换法制备了系列三核铁簇合物插层蒙脱土固相光助芬顿催化剂. 利用 X 射线粉末衍射、扫描电镜、透射电镜、紫外-可见漫反射光谱、X 射线精细结构能谱及等离子体发射光谱对催化剂进行了表征. 结果表明, 经三核铁簇合物柱撑后, 蒙脱土的比表面积显著增加, 其表面附着少量纳米纤维织构状的无定形铁氧化物. 在过氧化氢及可见光激发下, 所制催化剂能够快速降解并矿化染料罗丹明 B, 表现出良好的多相可见光助芬顿性能. 结合反应过程中活性物种的表征结果, 初步探讨了该催化剂的可见光助芬顿降解机理.

关键词: 蒙脱土, 纳米纤维, 芬顿试剂, 降解, 可见光, 铁氧化物, 罗丹明 B

Abstract: Trinuclear Fe(III) acetate complex intercalated montmorillonite Fenton catalysts were successfully prepared by a facile ion exchange process. The obtained catalysts were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Ultraviolet-visible (UV-Vis) diffuse reflectance spectroscopy, X-ray absorption fine structure, and inductively coupled plasma-atomic emission spectrometry. The results showed that the montmorillonite’s surface area was greatly increased after the trinuclear iron cluster intercalated. A few amorphous nano-fibre iron oxides were anchored on the surface of the catalyst. The prepared catalyst exhibited high efficiencies for the degradation and mineralization of rhodamine B in the presence of H2O2 under visible light irradiation. Furthermore, the main active species in catalytic reaction process have been investigated. Based on the experimental results, a possible mechanism was discussed and proposed.

Key words: montmorillonite, nano-fibre, photo-Fenton, degradation, visible light, iron oxide, rhodamine B