自漂浮Bi4O5Br2/磷掺杂氮化碳/碳纤维布S型异质结光催化剂增强去除新兴有机污染物

doi:10.1016/S1872-2067(25)64780-2

催化学报 ›› 2025, Vol. 76: 37-49.DOI: 10.1016/S1872-2067(25)64780-2

自漂浮Bi₄O₅Br₂/磷掺杂氮化碳/碳纤维布S型异质结光催化剂增强去除新兴有机污染物

李世杰^a^,^b^,^*(), 李蕊^a, 董珂欣^a, 刘艳萍^a, 于欣^b, 李文尧^c, 刘通^d, 赵再望^e, 张明义^f^,^*(), 张宾^a^,^*(), 陈晓波^g

^a浙江海洋大学国家海洋设施养殖工程技术研究中心, 浙江省石油化工环境污染控制重点实验室, 浙江舟山316022, 中国
^b河南大学能源科学与技术学院, 河南省废弃物资源能源化工程技术研究中心, 河南郑州 450046, 中国
^c上海工程技术大学材料科学与工程学院, 上海 201620, 中国
^d武汉工程大学化工与制药学院, 绿色化工过程教育部重点实验室, 湖北省新型反应器与绿色化学工艺重点实验室, 湖北武汉 430205, 中国
^e内蒙古大学能源材料化学研究院, 化学化工学院, 内蒙古呼和浩特 010070, 中国
^f哈尔滨师范大学物理与电子工程学院, 光电带隙材料教育部重点实验室, 黑龙江哈尔滨 150025, 中国
^g能源、物质与系统学部, 科学与工程学院, 密苏里大学堪萨斯城分校, 密苏里州, 美国

收稿日期:2025-04-04 接受日期:2025-07-02 出版日期:2025-09-18 发布日期:2025-09-10
通讯作者: 李世杰,张明义,张宾
基金资助:
国家自然科学基金(U1809214);国家自然科学基金(U23A20263);国家自然科学基金(51708504);浙江省自然科学基金(LY20E080014);浙江省自然科学基金(LTGN23E080001);舟山市科技计划项目(2022C41011);河南大学化学科学部开放合作项目

Self-floating Bi₄O₅Br₂/P-doped C₃N₄/carbon fiber cloth with S-scheme heterostructure for boosted photocatalytic removal of emerging organic contaminants

Shijie Li^a^,^b^,^*(), Rui Li^a, Kexin Dong^a, Yanping Liu^a, Xin Yu^b, Wenyao Li^c, Tong Liu^d, Zaiwang Zhao^e, Mingyi Zhang^f^,^*(), Bin Zhang^a^,^*(), Xiaobo Chen^g

^aZhejiang Key Laboratory of Pollution Control for Port-Petrochemical Industry, National Engineering Research Center for Marine Aquaculture, Zhejiang Ocean University, Zhoushan 316022, Zhejiang, China
^bHenan Engineering Research Center of Resource & Energy Recovery from Waste, School of Energy Science and Technology, Henan University, Zhengzhou 450046, Henan, China
^cSchool of Materials Science and Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
^dKey Laboratory of Green Chemical Process, Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, Hubei, China
^eCollege of Energy Materials and Chemistry, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010070, Inner Mongolia, China
^fKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, Heilongjiang, China
^gDivision of Energy, Matter, and Systems, School of Science and Engineering, University of Missouri-Kansas City, Kansas City, MO 64110, USA

Received:2025-04-04 Accepted:2025-07-02 Online:2025-09-18 Published:2025-09-10
Contact: Shijie Li, Mingyi Zhang, Bin Zhang
Supported by:
National Natural Science Foundation of China(U1809214);National Natural Science Foundation of China(U23A20263);National Natural Science Foundation of China(51708504);Natural Science Foundation of Zhejiang Province(LY20E080014);Natural Science Foundation of Zhejiang Province(LTGN23E080001);Science and Technology Project of Zhoushan(2022C41011);and the Open Cooperation Foundation of the Department of Chemical Science of Henan University

摘要/Abstract

摘要：

水体中新兴有机污染物因结构复杂、高毒性与难降解特性, 难以被现有水处理技术有效去除, 致使环境残留持续累积, 对生态系统和人类健康构成重大威胁. 太阳能光催化技术作为可持续废水净化的理想途径, 在实际应用中面临三重挑战: 光生载流子分离效率低、粉末催化剂难回收、重复使用性差. 传统粉末催化剂在水处理中容易流失, 不仅造成二次污染, 更导致运行成本激增. 针对水产养殖业中四环素(TC)类抗生素的污染问题, 开发兼具高效催化性能与易回收特性的新型光催化剂迫在眉睫. 近年研究表明, S型异质结可通过内建电场(IEF)实现载流子的定向迁移, 而宏观载体集成策略可突破粉末催化剂的回收瓶颈.

本研究创新性地构筑了以碳纤维布(CC)为基底的自漂浮S型异质结光催化剂, 通过离子掺杂-高温聚合-溶剂热法在碳纤维表面原位生长Bi₄O₅Br₂/磷掺杂氮化碳(BB/PN)纳米片壳层, 形成BB/PN/CC分级结构. 实验与理论计算证实, BB与PN间的强界面耦合及费米能级差诱导产生强的IEF, 驱动光生载流子遵循S型转移路径, 即光生电子从BB的导带迁移至PN的价带, 与其光生空穴复合, 同时形成了由PN指向BB的界面电场, 使强氧化还原性的电子-空穴复合率大幅降低. 该机制赋予BB/PN/CC卓越的光催化性能, 其对TC的降解动力学常数达0.0118 min^‒1, 分别是CN/CC (0.0015 min^‒1), BB/CC(0.0066 min^‒1)和PN/CC(0.0023 min^‒1)的7.9倍, 1.8倍和5.1倍. 此外, 催化剂的自漂浮特性赋予其卓越的易回收特性(8次循环后活性保持率>74%), 有效克服粉末催化剂回收瓶颈. 自由基猝灭实验与电子顺磁共振分析表明, •OH, h⁺和•O₂⁻协同主导抗生素的降解过程. 采用高效液相色谱-质谱联用技术结合ECOSAR毒性预测模型, 系统解析了TC降解中间产物及其毒性演化规律. 本工作通过载体工程、离子掺杂与S型机制的协同优化策略, 为水产抗生素污染控制提供了兼具高效降解与工程实用性的解决方案.

关键词: Bi₄O₅Br₂/P-doped C₃N₄, 漂浮S型异质结, 内建电场, 光催化, 抗生素去除

Abstract:

The industrial implementation of Solar-driven photocatalysis is hampered by inefficient charge separation, poor reusability and hard retrieval of powdery catalysts. To conquer these drawbacks, a self- floating S-scheme Bi₄O₅Br₂/P-doped C₃N₄/carbon fiber cloth (BB/PN/CC) composed of carbon fibers (CC) as the core and Bi₄O₅Br₂/P-doped C₃N₄ (BB/PN) nanosheets as the shell was constructed as a competent, recyclable cloth-shaped photocatalyst for safe and efficient degradation of aquacultural antibiotics. The BB/PN/CC fabric achieves an exceptional tetracycline degradation rate constant of 0.0118 min^‒1, surpassing CN/CC (0.0015 min^‒1), BB/CC (0.0066 min^‒1) and PN/CC (0.0023 min^‒1) by 6.9, 0.8 and 4.1 folds, respectively. Beyond its catalytic prowess, the photocatalyst’s practical superiority is evident in its effortless recovery and environmental adaptability. The superior catalytic effectiveness stems from the S-scheme configuration, which retains the maximum redox capacities of the constituent BB and PN while enabling efficient spatial detachment of photo-carriers. X-ray photoelectron spectroscopy (XPS), in-situ XPS, and electron paramagnetic resonance analyses corroborate the S-scheme mechanism, revealing electron accumulation on PN and hole retention on BB under illumination. Density functional theory calculations further confirm S-scheme interfacial charge redistribution and internal electric field formation. This study advances the design of macroscopic S-scheme heterojunction photocatalysts for sustainable water purification.

Key words: Bi₄O₅Br₂/P-doped C₃N₄, Self-floating S-scheme heterojunction, Internal electric field, Photocatalysis, Antibiotic removal

李世杰, 李蕊, 董珂欣, 刘艳萍, 于欣, 李文尧, 刘通, 赵再望, 张明义, 张宾, 陈晓波. 自漂浮Bi₄O₅Br₂/磷掺杂氮化碳/碳纤维布S型异质结光催化剂增强去除新兴有机污染物[J]. 催化学报, 2025, 76: 37-49.

Shijie Li, Rui Li, Kexin Dong, Yanping Liu, Xin Yu, Wenyao Li, Tong Liu, Zaiwang Zhao, Mingyi Zhang, Bin Zhang, Xiaobo Chen. Self-floating Bi₄O₅Br₂/P-doped C₃N₄/carbon fiber cloth with S-scheme heterostructure for boosted photocatalytic removal of emerging organic contaminants[J]. Chinese Journal of Catalysis, 2025, 76: 37-49.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(25)64780-2

https://www.cjcatal.com/CN/Y2025/V76/I9/37

图/表 8

Fig. 1. Synthetic process of BB/PN/CC materials.

Fig. 2. Photos and SEM images of CC (a-d), PN/CC (e-h), and BB/PN/CC (i-l). (m) Mapping images of BB/PN/CC. (n-q) TEM and HRTEM images of BB/PN/CC.

Fig. 3. (a) XRD profiles. Bi 4f (b), Br 3d (c), O 1s (d), P 2p (e) and N 1s (f) XPS spectra.

Fig. 4. Temporal evolution of photocatalytic TC eradication (a) and reaction kinetics (b) over various fabric catalysts. (c) Time course of photocatalytic enrofloxacin, ciprofloxacin and oxytetracycline destruction activity over BB/PN/CC. (d) TC destruction efficiencies over BB/PN/CC with different sizes. Impacts of HA (e) and ions (f) on the catalytic effectiveness of BB/PN/CC. (g) TC annihilation performance of BB/PN/CC in real water matrices. (h) Cycle stabilities of BB/PN/CC. (i) TC elimination over BB/PN/CC in the presence of diverse scavengers.

Fig. 5. (a) TC destruction process over BB/PN/CC. (b-d) Eco-toxicity test results.

Fig. 6. Water contact angle photographs of CC (a), BB/CC (b), PN/CC (c), and BB/PN/CC (d). Transient photocurrent signals (e) and EIS curves (f) for BB/CC PN/CC and BB/PN/CC.

Fig. 7. (a) UV-vis absorption plots. Tauc profiles (b,c), Mott-Schottky curves (d,e), and UPS plots (f) of PN and BB. (g,h) In-situ XPS measurement on BB/PN/CC.

Fig. 8. EPR results of DMPO-•O2- (a) and DMPO-•OH (b). Computed Φ values of BB (c) and PN (d). 3D (e) and 2D (f) charge difference distribution for BB/PN/CC. (g) Schematic representation of the operation mechanism of BB/PN/CC for TC destruction.

参考文献

[1]	C. L. Brown, A. Maile-Moskowitz, A. J. Lopatkin, K. Xia, L. K. Logan, B. C. Davis, L. Zhang, P. J. Vikesland, A. Pruden, Nat. Commun., 2024, 15, 5412.
[2]	J. D. Miller, C. Staddon, A. Salzberg, J. B. Lucks, W. Bruine de Bruin, S. L. Young, Nat. Commun., 2024, 15, 7320.
[3]	H. Sun, Y. Liu, C. Wu, L. Q. Ma, D. Guan, H. Hong, H. Yu, H. Lin, X. Huang, P. Gao, Eco-Environ. Health, 2024, 3, 183-191.
[4]	A. J. dos Santos, H. L. Barazorda-Ccahuana, G. Caballero-Manrique, Y. Chérémond, P. J. Espinoza-Montero, J. R. González-Rodríguez, U. J. Jáuregui-Haza, M. R. V. Lanza, A. Nájera, C. Oporto, A. Pérez Parada, T. Pérez, V. D. Quezada, V. Rojas, V. Sosa, A. Thiam, R. A. Torres-Palma, R. Vargas, S. Garcia-Segura, Nat. Sustain., 2023, 6, 349-351.
[5]	D. Mangla, Annu, A. Sharma, S. Ikram, J. Hazard. Mater., 2022, 425, 127946.
[6]	Y. Yu, Y. Yu, H. Wu, J. Shi, H. Morikawa, C. Zhu, Adv. Fiber Mater., 2024, 6, 1495-1508.
[7]	R. Liang, S. Li, X. Zhang, Z. Hu, H. Wu, J. Sun, G. Song, J. Liu, Y. Chai, I. Sirés, M. Zhou, Angew. Chem. Int. Ed., 2025, doi:10.1002/anie.202508548.
[8]	V. I. Parvulescu, F. Epron, H. Garcia, P. Granger, Chem. Rev., 2022, 122, 2981-3121.
[9]	B. Weng, M. Zhang, Y. Lin, J. Yang, J. Lv, N. Han, J. Xie, H. Jia, B.-L. Su, M. Roeffaers, J. Hofkens, Y. Zhu, S. Wang, W. Choi, Y.-M. Zheng, Nat. Rev. Clean Technol., 2025, 1, 201-215.
[10]	S. Thakur, A. Ojha, S. K. Kansal, N. K. Gupta, H. C. Swart, J. Cho, A. Kuznetsov, S. Sun, J. Prakash, Adv. Powder Mater., 2024, 3, 100233.
[11]	J. Zhang, X. Tang, Y. Hong, G. Chen, Y. Chen, L. Zhang, W. Gao, Y. Zhou, B. Sun, Eco-Environ. Health, 2023, 2, 47-60.
[12]	J. Kim, S. H. Lee, F. Tieves, C. E. Paul, F. Hollmann, C. B. Park, Sci. Adv., 2019, 5, eaax0501.
[13]	L. Candish, K. D. Collins, G. C. Cook, J. J. Douglas, A. Gómez-Suárez, A. Jolit, S. Keess, Chem. Rev., 2022, 122, 2907-2980.
[14]	T. Banerjee, F. Podjaski, J. Kröger, B. P. Biswal, B. V. Lotsch, Nat. Rev. Mater., 2021, 6, 168-190.
[15]	Y. Yang, L. Guo, X. Wang, Z. Li, W. Zhou, Adv. Powder Mater., 2024, 3, 100178.
[16]	W. Zhang, S. Wei, G. Zhang, J. Yang, L. Peng, S. Zhang, Coord. Chem. Rev., 2025, 524, 216318.
[17]	Q. Zhu, Q. Xu, M. Du, X. Zeng, G. Zhong, B. Qiu, J. Zhang, Adv. Mater., 2022, 34, 2202929.
[18]	S. Chandrasekaran, L. Yao, L. Deng, C. Bowen, Y. Zhang, S. Chen, Z. Lin, F. Peng, P. Zhang, Chem. Soc. Rev., 2019, 48, 4178-4280.
[19]	Z. Cheng, W. Qi, C.-H. Pang, T. Thomas, T. Wu, S. Liu, M. Yang, Adv. Funct. Mater., 2021, 31, 2100553.
[20]	K. Chen, J. Xiao, T. Hisatomi, K. Domen, Chem. Sci., 2023, 14, 9248-9257.
[21]	S. S. Thind, M. Paul, J. B. Hayden, A. Joshi, D. Goodlett, J. S. McIndoe, Ind. Chem. Mater., 2023, 1, 431-442.
[22]	S. Corby, R. R. Rao, L. Steier, J. R. Durrant, Nat. Rev. Mater., 2021, 6, 1136-1155.
[23]	B. Mishra, A. Alam, A. Chakraborty, B. Kumbhakar, S. Ghosh, P. Pachfule, A. Thomas, Adv. Mater., 2024, doi: 10.1002/adma.202413118.
[24]	F. Ahmadijokani, A. Ghaffarkhah, H. Molavi, S. Dutta, Y. Lu, S. Wuttke, M. Kamkar, O. J. Rojas, M. Arjmand, Adv. Funct. Mater., 2024, 34, 2305527.
[25]	W. Zhang, G. Liu, Chin. J. Catal., 2024, 66, 76-109.
[26]	E. Nikoloudakis, I. López-Duarte, G. Charalambidis, K. Ladomenou, M. Ince, A. G. Coutsolelos, Chem. Soc. Rev., 2022, 51, 6965-7045.
[27]	S.-M. Wu, P. Schmuki, Adv. Mater., 2025, 37, 2414889.
[28]	H. Fu, J. Tian, Q. Zhang, Z. Zheng, H. Cheng, Y. Liu, B. Huang, P. Wang, Chin. J. Catal., 2024, 64, 143-151.
[29]	A. Khandelwal, D. Maarisetty, S. S. Baral, Renew. Sustain. Energy Rev., 2022, 167, 112693.
[30]	S. R. Nagella, R. Vijitha, B. Ramesh Naidu, K. S. V. Krishna Rao, C.-S. Ha, K. Venkateswarlu, Nano Energy, 2023, 111, 108402.
[31]	Y. Xu, M. Fan, W. Yang, Y. Xiao, L. Zeng, X. Wu, Q. Xu, C. Su, Q. He, Adv. Mater., 2021, 33, 2101455.
[32]	C. Pulignani, C. A. Mesa, S. A. J. Hillman, T. Uekert, S. Giménez, J. R. Durrant, E. Reisner, Angew. Chem. Int. Ed., 2022, 61, e202211587.
[33]	A. Dhakshinamoorthy, Z. Li, S. Yang, H. Garcia, Chem. Soc. Rev., 2024, 53, 3002-3035.
[34]	M. A. Khan, S. Mutahir, I. Shaheen, Q. Yuan, M. Bououdina, M. Humayun, Coord. Chem. Rev., 2025, 522, 216227.
[35]	Y. Feng, Y. Tao, J. Qu, Y. Zhang, Chem. Eng. J., 2023, 472, 145053.
[36]	Z. Zhou, H. Zeng, L. Li, R. Tang, C. Feng, D. Gong, Y. Huang, Y. Deng, Water Res., 2024, 255, 121521.
[37]	J. Wang, S. Wang, Coord. Chem. Rev., 2022, 453, 214338.
[38]	S. Patnaik, D. P. Sahoo, K. Parida, Carbon, 2021, 172, 682-711.
[39]	J. Tyczkowski, H. Kierzkowska-Pawlak, ACS Appl. Mater. Interfaces, 2024, 16, 37339-37345.
[40]	G. F. S. R. Rocha, M. A. R. da Silva, A. Rogolino, G. A. A. Diab, L. F. G. Noleto, M. Antonietti, I. F. Teixeira, Chem. Soc. Rev., 2023, 52, 4878-4932.
[41]	L. Chen, M. A. Maigbay, M. Li, X. Qiu, Adv. Powder Mater., 2024, 3, 100150.
[42]	H. Liao, K. Huang, W. Hou, H. Guo, C. Lian, J. Zhang, Z. Liu, L. Wang, Adv. Powder Mater., 2024, 3, 100243.
[43]	L. Zhang, H. Zhang, D. Zhu, Z. Fu, S. Dong, C. Lyu, Chin. J. Catal., 2024, 66, 181-194.
[44]	G. A. Bin Azizar, J. W. Hong, J. Mater. Sci. Technol., 2024, 168, 103-113.
[45]	H. S. Moon, K.-C. Hsiao, M.-C. Wu, Y. Yun, Y.-J. Hsu, K. Yong, Adv. Mater., 2023, 35, 2200172.
[46]	S. Li, K. Dong, M. Cai, X. Li, X. Chen, eScience, 2024, 4, 100208.
[47]	S. Li, C. You, K. Rong, C. Zhuang, X. Chen, B. Zhang, Adv. Powder Mater., 2024, 3, 100183.
[48]	L. Zhang, J. Zhang, J. Yu, H. García, Nat. Rev. Chem., 2025, 9, 328-342.
[49]	T. F. Qahtan, T. O. Owolabi, O. E. Olubi, A. Hezam, Coord. Chem. Rev., 2024, 514, 215839.
[50]	G.-C. Liu, X.-H. Yi, H.-Y. Chu, C.-C. Wang, Y. Gao, F. Wang, F.-X. Wang, P. Wang, J.-F. Wang, J. Hazard. Mater., 2024, 472, 134420.
[51]	M. Cai, Y. Liu, K. Dong, X. Chen, S. Li, Chin. J. Catal., 2023, 52, 239-251.
[52]	A. Balakrishnan, M. M. Jacob, M. Chinthala, N. Dayanandan, M. Ponnuswamy, D. N. Vo, Environ. Chem. Lett., 2024, 22, 635-656.
[53]	H. Ding, B. Peng, Z. Wang, Q. Han, Acta Phys.-Chim. Sin., 2024, 40, 2305048.
[54]	X. Qian, Y. Ma, X. Xia, J. Xia, J. Ye, G. He, H. Chen, Catal. Sci. Technol., 2024, 14, 1085-1104.
[55]	S. Vinoth, W.-J. Ong, A. Pandikumar, Coord. Chem. Rev., 2022, 464, 214541.
[56]	H. Wang, Y. Wang, L. Xu, M. Zhang, X. Wu, H. Li, Ceram. Int., 2022, 48, 21988-21995.
[57]	J.-Y. Yue, Z.-X. Pan, P. Yang, B. Tang, ACS Mater. Lett., 2024, 6, 3932-3940.
[58]	Z. Ya, X. Jiang, P. Wang, J. Cai, Q. Wang, H. Xie, S. Xiang, T. Wang, D. Cai, Small, 2023, 19, 2208254.
[59]	W. Zeng, Y. Dong, X. Ye, Z. Zhang, T. Zhang, X. Guan, L. Guo, Chin. Chem. Lett., 2024, 35, 109252.
[60]	T. Liang, Y. Li, S. Xu, Y. Yao, R. Xu, J. Bian, Z. Zhang, L. Jing, Chin. J. Catal., 2024, 62, 277-286.
[61]	B. Huang, X. Fu, K. Wang, L. Wang, H. Zhang, Z. Liu, B. Liu, J. Li, Adv. Powder Mater., 2024, 3, 100140.
[62]	X. Chen, Y. Wu, Y. Tang, P. Li, S. Gao, Q. Wang, W. Liu, S. Zhan, Chin. Chem. Lett., 2024, 35, 109245.
[63]	X. Sun, L. Li, S. Jin, W. Shao, H. Wang, X. Zhang, Y. Xie, eScience, 2023, 3, 100095.
[64]	H. Wang, Z. Chen, Y. Shang, C. Lv, X. Zhang, F. Li, Q. Huang, X. Liu, W. Liu, L. Zhao, L. Ye, H. Xie, X. Jin, ACS Catal., 2024, 14, 5779-5787.
[65]	S.-X. Yuan, K. Su, Y.-X. Feng, M. Zhang, T.-B. Lu, Chin. Chem. Lett., 2023, 34, 107682.
[66]	Y. Zhang, H. Khanbareh, S. Dunn, C. R. Bowen, H. Gong, N. P. H. Duy, P. T. T. Phuong, Adv. Sci., 2022, 9, 2105248.
[67]	D. Li, C. Wen, J. Huang, J. Zhong, P. Chen, H. Liu, Z. Wang, Y. Liu, W. Lv, G. Liu, Appl. Catal. B, 2022, 307, 121099.
[68]	X. Zheng, Y. Wang, S. Ren, Q. Gai, W. Liu, Q. Dong, ACS Appl. Energy Mater., 2022, 5, 5756-5765.
[69]	W. Zhong, D. Zheng, Y. Ou, A. Meng, Y. Su, Acta Phys.-Chim. Sin., 2024, 40, 2406005.
[70]	X.-H. Yi, G.-C. Liu, H.-Y. Chu, Y. Gao, C.-C. Wang, P. Wang, Chem. Commun., 2024, 60, 9530-9533.
[71]	S. Li, C. You, F. Yang, G. Liang, C. Zhuang, X. Li, Chin. J. Catal., 2025, 68, 259-271.
[72]	S. Li, K. Rong, X. Wang, C. Shen, F. Yang, Q. Zhang, Acta Phys.-Chim. Sin., 2024, 40, 2403005.
[73]	X. Song, X. Li, B. Zhu, S. Sun, Z. Chen, L. Zhang, Adv. Fiber Mater., 2024, 6, 1569-1582.
[74]	A. Li, P. Zhang, E. Kan, J. Gong, eScience, 2024, 4, 100157.
[75]	Y. Dong, P. Ji, X. Xu, R. Li, Y. Wang, K. P. Homewood, X. Xia, Y. Gao, X. Chen, Energy Environ. Mater., 2024, 7, e12643.
[76]	W. Al Zoubi, A. Al Mahmud, F. Hazmatulhaq, M. R. Thalji, S. Leoni, J.-H. Kang, Y. G. Ko, SusMat, 2024, 4, e216.
[77]	V. Dutta, A. Sudhaik, Sonu, P. Raizada, A. Singh, T. Ahamad, S. Thakur, Q. Van Le, V.-H. Nguyen, P. Singh, J. Mater. Sci. Technol., 2023, 162, 11-24.
[78]	Q. Xiao, T. Liu, Q. Zhou, L. Li, C. Chang, D. Gao, D. Li, F. You, Chem. Res. Chin. Univ., 2024, 40, 484-489.
[79]	M. Gao, Z. Sun, Y. Gao, G. Yu, Y. Feng, J. Liaocheng Univ. (Nat. Sci. Ed.), 2024, 37(6), 39-48.
[80]	Z. Wang, J. Li, Y. Qiao, X. Liu, Y. Zheng, Z. Li, J. Shen, Y. Zhang, S. Zhu, H. Jiang, Y. Liang, Z. Cui, P. K. Chu, S. Wu, Adv. Fiber Mater., 2023, 5, 484-496.
[81]	Z. Wei, J. Yan, W. Guo, W. Shangguan, Chin. J. Catal., 2023, 48, 279-289.
[82]	D.-E. Lee, N. Mameda, K. P. Reddy, B. M. Abraham, W.-K. Jo, S. Tonda, J. Mater. Sci. Technol., 2023, 161, 74-87.
[83]	F.-X. Wang, Z.-W. Zhang, Z.-C. Zhang, K.-X. Li, Y. Li, H.-Y. Chu, C.-C. Wang, J.-F. Wang, L. Chen, W. Liu, H. Wang, P. Wang, Chem. Eng. J., 2024, 487, 150506.
[84]	D. Gao, P. Deng, J. Zhang, L. Zhang, X. Wang, H. Yu, J. Yu, Angew. Chem. Int. Ed., 2023, 62, e202304559.
[85]	D. Gao, H. Long, X. Wang, J. Yu, H. Yu, Adv. Funct. Mater., 2023, 33, 2209994.
[86]	Z. Xu, Y. Wu, R. Tao, Z. Jin, X. Fang, Chem. Res. Chin. Univ., 2023, 39, 928-932.
[87]	C. Fu, D. Li, J. Zhang, W. Guo, H. Yang, B. Zhao, Z. Chen, X. Fu, Z. Liang, L. Jiang, Chem. Res. Chin. Univ., 2023, 39, 891-901.
[88]	X. Yang, Z. Guo, Y. Xu, Z. Li, Y. Zhou, Z. Yang, Z. Zhou, Y. Gao, J. Zhang, Chem. Res. Chin. Univ., 2024, 40, 536-547.
[89]	Y. Qin, X. Zhang, B. Ge, T. Zhang, G. Ren, J. Liaocheng Univ. (Nat. Sci. Ed.), 2024, 37 (6), 49-55.
[90]	Y. Liu, S. Zhang, X. Li, Y. Liu, J. Lu, X. Lu, Z. Xu, J. Liaocheng Univ. (Nat. Sci. Ed.), 2024, 37(3), 34-41.
[91]	Y. Gong, Y. Ding, Q. Tang, F. Lian, C. Bai, R. Xie, H. Xie, X. Zhao, Chin. Chem. Lett., 2024, 35, 108475.
[92]	C. Chen, X. Zhang, E. Liu, J. Xu, J. Sun, H. Shi, J. Mater. Sci. Technol., 2024, 198, 1-11.
[93]	A. H. Raza, S. Farhan, Z. Yu, Y. Wu, Acta Phys.-Chim. Sin., 2024, 40, 2406020.
[94]	S. Yang, K. Wang, Z. Wu, Y. Wu, J. Mater. Sci. Technol., 2024, 200, 253-264.
[95]	J. Yan, L. Wei, Acta Phys.-Chim. Sin., 2024, 40, 2312024.
[96]	L. Zhang, J. Zhang, H. Yu, J. Yu, Adv. Mater., 2022, 34, 2107668.
[97]	B. Zhu, J. Sun, Y. Zhao, L. Zhang, J. Yu, Adv. Mater., 2024, 36, 2310600.

自漂浮Bi₄O₅Br₂/磷掺杂氮化碳/碳纤维布S型异质结光催化剂增强去除新兴有机污染物

Self-floating Bi₄O₅Br₂/P-doped C₃N₄/carbon fiber cloth with S-scheme heterostructure for boosted photocatalytic removal of emerging organic contaminants

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 8

参考文献

相关文章 15

编辑推荐

Metrics

[1]	封波, 冯丹宁, 裴燕, 宗保宁, 乔明华, 李伟. 缺陷氮化碳负载铜单原子用于高选择性光催化氧化甲烷制甲醇[J]. 催化学报, 2025, 76(9): 96-107.
[2]	钟威, 孟爱云, 蔡旭东, 甘义遥, 王敬涛, 苏耀荣. Co诱导不对称电荷分布弱化S-H_ad键增强NiCoS助剂的光催化制氢性能[J]. 催化学报, 2025, 76(9): 108-119.
[3]	郑相阳, 吴金往, 史海峰. 双空位诱导极化场与内建电场增强的S型异质结用于去除抗生素及六价铬[J]. 催化学报, 2025, 76(9): 50-64.
[4]	季碧铖, 李希成, 高帅, 秦泽平, 汪长征, 王强, 王崇臣. 自发极化增强的空心球Bi₄Ti₃O₁₂促进高效压电光催化: 构效关系与降解机制[J]. 催化学报, 2025, 76(9): 133-145.
[5]	陈鸿境, 李月英, 陈敏, 解仲凯, 施伟东. 硫电子桥介导CuInS₂/CuS异质结构实现高选择性CO₂光还原为C₂H₄[J]. 催化学报, 2025, 75(8): 180-191.
[6]	李正, 曾影, 董媛媛, 吕红金, 杨国昱. 十钨酸盐+Pd/C催化体系中金属/H⁺位点的调控用于光催化生成糠基乙醚[J]. 催化学报, 2025, 75(8): 137-146.
[7]	熊祺, 史全全, 王彬力, 李杲. 晶面诱导还原导向的AgBr/Ag⁰/TiO₂{100} Z型异质结用于四环素去除[J]. 催化学报, 2025, 75(8): 164-179.
[8]	王啟航, 孟利, 李卓, 杨卓然, 汤意南, 余浪, 李志君, 孙建辉, 井立强. 钴单原子-磷酸功能化还原氧化石墨烯/苝四羧酸纳米片异质结用于高效光催化生产过氧化氢[J]. 催化学报, 2025, 75(8): 192-203.
[9]	张自豪, 张家铭, 王海峰, 刘梦, 许垚, 刘铠玮, 张博杨, 史珂, 张继方, 马贵军. 基于Sm₂Ti₂O₅S₂纳米片各向异性电荷迁移性质提升光催化分解水产氢活性[J]. 催化学报, 2025, 74(7): 341-351.
[10]	张云超, 潘劲康, 倪响, 莫非奇, 徐远国, 董鹏玉. 有机/无机杂化FS-COF/WO₃ S型异质结电荷载流子动力学及其光催化析氢性能[J]. 催化学报, 2025, 74(7): 250-263.
[11]	李亚慧, 陈宇, 郭锦瑜, 王锐, 赵淑娜, 李纲, 臧双全. 调控COF共价连接的多吡啶镍催化剂微环境促进光催化二氧化碳还原[J]. 催化学报, 2025, 74(7): 155-166.
[12]	周正宇, 靳治良. 自定义暴露晶面: 最佳晶面各向异性和欧姆异质结的协同效应促进光催化析氢[J]. 催化学报, 2025, 74(7): 294-307.
[13]	张鹏坤, 吴秦汉, 王昊昱, 郭东昊, 赖雨洁, 陆东芳, 李吉庆, 林金国, 袁占辉, 陈孝云. Z型异质结Zn₃(OH)₂(V₂O₇)(H₂O)₂/V-Zn(O,S): 钒异价态与氧空位缺陷协同增强可见光催化固氮性能[J]. 催化学报, 2025, 74(7): 279-293.
[14]	张琳, 张慧, 方敬红, 崔嘉琳, 刘洁, 刘辉, 孙立水, 孙琼, 董立峰, 赵英杰. 高共轭和化学稳定的三维共价有机框架材料用于高效光催化CO₂还原[J]. 催化学报, 2025, 74(7): 144-154.
[15]	郑馨龙, 宋一铭, 王崇太, 高奇志, 邵钟鋆, 林佳鑫, 翟佳迪, 李静, 史晓东, 吴道雄, 刘维峰, 黄玮, 陈琦, 田新龙, 刘雨昊. 铜/锌体系多元过渡金属硫化物光催化剂的半导体特性及其光催化制氢的应用与挑战[J]. 催化学报, 2025, 74(7): 22-70.