MOFs中单金属位点到双金属位点的动态配位转变和塑料的级联光重整制CO

doi:10.1016/S1872-2067(26)65013-9

催化学报 ›› 2026, Vol. 84: 314-323.DOI: 10.1016/S1872-2067(26)65013-9

MOFs中单金属位点到双金属位点的动态配位转变和塑料的级联光重整制CO

李健^a^,^b^,^c^,^d, 吴振发^a^,^c, 张欣茹^a^,^b, 颜同安^a^,^b(), 罗金^f, 薛文娟^a^,^b, 吕照临^e, 黄宏亮^a^,^b^,^c(), 仲崇立^a()

^a 天津工业大学先进分离膜材料国家重点实验室, 天津 300387
^b 天津工业大学化学工程与技术学院, 天津 300387
^c 天津工业大学材料科学与工程学院, 天津 300387
^d 天津工业大学沧州研究院, 河北沧州 061000
^e 中国科学院青岛生物能源与过程研究所, 山东青岛 266101
^f 岭南师范学院化学化工学院, 广东湛江 524048

收稿日期:2025-10-22 接受日期:2025-12-08 出版日期:2026-05-18 发布日期:2026-04-16
通讯作者: *电子信箱: huanghongliang@tiangong.edu.cn (黄宏亮),
yantongan@tiangong.edu.cn (颜同安),
zhongchongli@tiangong.edu.cn (仲崇立).
基金资助:
国家自然科学基金(22578327);国家自然科学基金(22208244);国家自然科学基金(22578328);国家自然科学基金(22508302);国家自然科学基金(22038010);山东省自然科学基金(ZR2022QE005);山东省自然科学基金(ZR2023QB208);河北省自然科学基金(B2025110012)

Dynamic coordination transformation from single-to dual-metal sites in MOFs for cascaded photoreforming of plastics into CO

Jian Li^a^,^b^,^c^,^d, Zhenfa Wu^a^,^c, Xinru Zhang^a^,^b, Tongan Yan^a^,^b(), Jin Luo^f, Wenjuan Xue^a^,^b, Zhaolin Lv^e, Hongliang Huang^a^,^b^,^c(), Chongli Zhong^a()

^a State Key Laboratory of Advanced Separation Membrane Materials, Tiangong University, Tianjin 300387, China
^b School of Chemical Engineering and Technology, Tiangong University, Tianjin 300387, China
^c School of Materials Science and Engineering, Tiangong University, Tianjin 300387, China
^d Cangzhou Institute of Tiangong University, Cangzhou 061000, Hebei, China
^e Qingdao New Energy Shandong Laboratory, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong, China
^f School of Chemistry and Chemical Engineering, Lingnan Normal University, Zhanjiang 524048, Guangdong, China

Received:2025-10-22 Accepted:2025-12-08 Online:2026-05-18 Published:2026-04-16
Contact: *E-mail: huanghongliang@tiangong.edu.cn (H. Huang),
yantongan@tiangong.edu.cn (T. Yan),
zhongchongli@tiangong.edu.cn (C. Zhong).
Supported by:
National Natural Science Foundation of China(22578327);National Natural Science Foundation of China(22208244);National Natural Science Foundation of China(22578328);National Natural Science Foundation of China(22508302);National Natural Science Foundation of China(22038010);Natural Science Foundation of Shandong Province(ZR2022QE005);Natural Science Foundation of Shandong Province(ZR2023QB208);Natural Science Foundation of Hebei(B2025110012)

摘要/Abstract

摘要：

废弃塑料的高效资源化是当前环境与能源领域的一项关键挑战. 传统光催化受限于单金属位点(SMSs)难以协同驱动多步反应, 导致塑料降解与产物定向转化效率低下. 双金属位点(DMSs)催化剂通过相邻位点的电子与空间协同效应, 为塑料的“切割-转化”级联过程提供了新方案. 金属有机框架(MOFs)是构建DMSs的理想平台, 然而, 如何从热力学更稳定的SMSs前驱体出发, 通过动态配位化学实现向DMSs的可控转变, 并以此驱动塑料完全转化为单一产物的研究仍属空白. 因此, 开发一种基于MOFs动态结构转变的SMSs-to-DMSs转化策略, 对于突破现有催化体系瓶颈、实现塑料高选择性光催化升级具有重要的科学价值与应用前景.

本文创新性地提出无溶剂策略, 借助MOF的动态配位化学特性, 通过体相Cu₁-SMSs/MOF的热驱动相变, 成功构建了二维Cu₂-DMSs/MOF催化剂, 并实现了聚乙烯到CO的高效级联光重整. 综合运用原位傅里叶变换红外光谱、原位透射电镜及密度泛函理论计算, 系统阐明了相转变机理: 热处理下, Cu₁-SMSs/MOF中Cu‒N键与Cl···H氢键的动态平衡被打破, 伴随HCl及副产物(C₃N₆H₇)Cl的挥发, 促使孤立Cu原子迁移并重构, 最终形成稳定的Cu-Cu双金属配位单元(Cu₂-N₄结构). 球差校正电镜和X-射线吸收精细结构谱证实了金属在两种材料中均为原子级分散, 且Cu₂-DMSs/MOF中形成了约1.94 Å的Cu‒Cu配位键. 所制备的Cu₂-DMSs/MOF催化剂在无需任何牺牲剂的条件下, 展现出卓越的级联光催化性能. 其可将聚乙烯通过“氧化降解—还原转化”两步法高效转化为CO: 首先, 光激发产生的空穴与电子分别活化H₂O和O₂, 产生·OH和·O₂^‒活性自由基, 协同断裂聚乙烯的C‒C和C‒H键, 将其完全氧化为CO₂, 产率高达2.32 mmol·g^‒1·h^‒1; 随后, 生成的CO₂在双Cu位点上被原位光还原为CO, 产率达0.29 mmol·g^‒1·h^‒1, 且选择性为100%. 该综合性能相较于Cu₁-SMSs/MOF及文献报道的氧化物等催化剂实现了数量级的提升. 循环使用后, 催化剂的晶体结构、化学组成及微观形貌无明显变化, 稳定性优异. 密度泛函理论计算证实, 双Cu位点向CO₂的电子转移数(0.134 e)高于单Cu位点(0.076 e), 对CO₂的吸附能(0.23 eV)更低, 且COOH中间体在双位点上的吸附能(‒1.73 eV)强于单位点(‒1.11 eV), 高效电荷转移与双位点协同作用是性能提升的核心原因.

综上, 本文发现了MOF中的动态配位化学可实现SMSs向DMSs的转化, 为双金属位点催化剂的开发开辟了新途径. 这种塑料转化为燃料的级联光催化转化策略, 为同时缓解白色污染危机和生产高价值化学品提供了极具前景的解决方案.

关键词: 金属有机框架, 双金属位点, 相变, 光级联反应, 塑料制燃料

Abstract:

Building on the success of catalytic single-metal sites (SMSs) in various model reaction systems, dual-metal sites (DMSs) could provide further breakthrough on catalysing complex reactions especially for those involving multiple cascading steps. Specifically, photocatalytic waste plastic conversion requires bond cleavage into small molecules followed by site-dependent transformations, where DMSs photocatalysts can, in principle, be highly active and selective through efficient charge separation and dual-site synergy. However, related studies remain rare since difficulty on efficient waste plastic photodegradation usually hinders subsequent catalytic conversion. Herein, we report for the first time that dual-metal sites are developed in a two-dimensional metal-organic framework (MOF) (Cu₂-DMSs/MOF) derived from single-metal sites in bulk MOF (Cu₁-SMSs/MOF) via dynamic coordination-driven transformation. The Cu₂-DMSs/MOF catalyst exhibits enhanced photocatalytic performance without sacrificial agents, catalysing the cascading polyethylene-to-CO₂ and CO₂-to-CO reactions in one step. The polyethylene-to-CO₂ degradation rate is 2.32 mmol·g^‒1·h^‒1 and the subsequent CO₂-to-CO conversion proceeds at 0.29 mmol·g^‒1·h^‒1 with 100% selectivity, representing an order-of-magnitude enhancement compared with previous reports. The *O₂^‒ and *OH radicals formed from O₂ and H₂O oxidative cleave C‒C and C‒H bonds in polyethylene to CO₂, which is subsequentially selective reduced to CO via multi-electron proton-coupling. This work offers a conceptual advance in designing dual-metal site catalysts, opening new avenues for cascading photocatalytic conversion of white pollution into valuable chemicals.

Key words: Metal-organic framework, Dual-metal sites, Phase transformation, Photocascade, Plastic-to-fuel conversion

李健, 吴振发, 张欣茹, 颜同安, 罗金, 薛文娟, 吕照临, 黄宏亮, 仲崇立. MOFs中单金属位点到双金属位点的动态配位转变和塑料的级联光重整制CO[J]. 催化学报, 2026, 84: 314-323.

Jian Li, Zhenfa Wu, Xinru Zhang, Tongan Yan, Jin Luo, Wenjuan Xue, Zhaolin Lv, Hongliang Huang, Chongli Zhong. Dynamic coordination transformation from single-to dual-metal sites in MOFs for cascaded photoreforming of plastics into CO[J]. Chinese Journal of Catalysis, 2026, 84: 314-323.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(26)65013-9

https://www.cjcatal.com/CN/Y2026/V84/I5/314

图/表 6

Scheme 1. Schematic illustration for photocatalytic cascade conversion of waste plastics over DMSs.

Fig. 1. Phase transformation process. (a) Schematic diagram of the transformation from Cu1-SMSs/MOF to Cu2-DMSs/MOF. (b) Energy diagram for the formation of Cu1-SMSs/MOF and Cu2-DMSs/MOF (ΔG is the energy change). In-situ FTIR spectra (c) and in-situ TEM images (d) of the transformation from single-metal sites into dual-metal sites by the dynamic coordination chemistry of MOFs.

Fig. 2. Structural characterization of SMSs and DMSs. HAADF-STEM images of Cu1-SMSs/MOF (a) and Cu2-DMSs/MOF (b). (c) The EDS mapping images of Cu2-DMSs/MOF. Cu K-edge XANES spectra (d) and FT-EXAFS spectra (e) of Cu1-SMSs/MOF and Cu2-DMSs/MOF with other reference compounds. DFT-optimized structure of the Cu site coordinated in Cu1-SMSs/MOF (f) and Cu2-DMSs/MOF (g) (Only the partial framework is shown for the clarity). (h?l) WT-EXAFS of Cu1-SMSs/MOF and Cu2-DMSs/MOF with other reference compounds.

Fig. 3. Photocascade catalytic performance. The yield of CO2 (a) and CO (b) during the photoconversion of PE over the Cu1-SMSs/MOF and Cu2-DMSs/MOF. (c) The control experiments of photocascade catalytic over Cu2-DMSs/MOF under altered conditions.

Fig. 4. Photocascade catalytic mechanisms over Cu2-DMSs/MOF. DMPO spin trapping ESR spectra of DMPO-*O2? (a) and DMPO-*OH (b) adducts over Cu2-DMSs/MOF. In-situ DRIFTS spectra at 3500?3800 cm?1 (c) and at 1000?2100 cm?1 (d) for detecting the reaction intermediates in the photocascade catalytic process from PE to CO over Cu2-DMSs/MOF (Reaction conditions: room temperature, O2 and H2O atmosphere, 300 W Xe lamp illumination, spectra collected with a 20-min time resolution). (e) Gibbs free energy profile of CO2 reduction reaction over Cu1-SMSs/MOF and Cu2-DMSs/MOF (inset for the optimized structures of corresponding reaction intermediates. Only the partial framework is shown for the clarity.)

Fig. 5. The proposed photocascade catalytic mechanism from PE into CO.

参考文献

[1]	B. Qiao, A. Wang, X. Yang, L. F. Allard, Z. Jiang, Y. Cui, J. Liu, J. Li, T. Zhang, Nat. Chem., 2011, 3, 634-641.
[2]	X. Liang, N. Fu, S. Yao, Z. Li, Y. Li, J. Am. Chem. Soc., 2022, 144, 18155-18174.
[3]	J. Li, K. Zhang, N. Wang, Q. Sun, Chem. J. Chin. Univ., 2022, 43, 20220032.
[4]	H. Zhang, W. Tian, X. Duan, H. Sun, Y. Huang, Y. Fang, S. Wang, Chin. J. Catal., 2022, 43, 2301-2315.
[5]	J. Li, M. Du, Z. Wu, X. Zhang, W. Xue, H. Huang, C. Zhong, Angew. Chem. Int. Ed., 2024, 63, e202407975.
[6]	M. Xu, Z. Li, R. Shen, X. Zhang, Z. Zhang, P. Zhang, X. Li, Chin. J. Catal., 2025, 70, 431-443.
[7]	Z. Li, Y. Yang, C. Zhang, W. Fan, G. Li, J. Fang, L. Lu, Chem Catal., 2024, 4, 100902.
[8]	K. Cheng, D. Shen, Y. Xia, K. Dai, C. Shao, Y. Jiang, Y. Chen, Angew. Chem. Int. Ed., 2025, 64, e202508932.
[9]	J. Li, H. Huang, W. Xue, K. Sun, X. Song, C. Wu, L. Nie, Y. Li, C. Liu, Y. Pan, H.-L. Jiang, D. Mei, C. Zhong, Nat. Catal., 2021, 4, 719-729.
[10]	M. Zhang, P. Che, H. Ma, X. Liu, S. Zhang, Y. Luo, J. Xu, Chin. J. Catal., 2024, 67, 144-156.
[11]	S. Wang, J. Ma, L. Chen, X. Zhang, Acta Chim. Sin., 2021, 79, 216.
[12]	S. Yue, Z. Zhao, Y. Liu, M. Yang, T. Zhang, F. Li, K. Liu, P. Wang, S. Zhan, Adv. Funct. Mater., 2025, 35, 09766.
[13]	Y. Li, B. Wei, M. Zhu, J. Chen, Q. Jiang, B. Yang, Y. Hou, L. Lei, Z. Li, R. Zhang, Y. Lu, Adv. Mater., 2021, 33, 2102212.
[14]	Y. Ling, H. Su, R.-Y. Zhou, Q. Feng, X. Zheng, J. Tang, Y. Li, M. Zhang, Q. Wang, J.-F. Li, Chin. J. Catal., 2025, 73, 347-357.
[15]	Y. Wu, W. Jiang, W. Xu, F. Lv, S. Song, L. Hu, C. Wang, L. Zheng, W. Gu, R. Zhang, S. Guo, C. Zhu, J. Am. Chem. Soc., 2025, 147, 1, 1356-1363.
[16]	H. Liu, S. He, J. Qu, Y. Cai, X. Yang, C.-M. Li, J. Hu, Chin. J. Catal., 2024, 65, 1-39.
[17]	J. Tian, C. Guan, H. Hu, E. Liu, D. Yang, Acta Phys.-Chim. Sin., 2025, 41, 100068.
[18]	T. Uekert, M. F. Kuehnel, D. W. Wakerley, E. Reisner, Energy Environ. Sci., 2018, 11, 2853-2857.
[19]	T. Uekert, H. Kasap, E. Reisner, J. Am. Chem. Soc., 2019, 141, 15201-15210.
[20]	J. Lv, H. Chu, C. Shao, L. Sun, G. Dawson, K. Dai, Chin. J. Catal., 2025, 78, 75-99.
[21]	J. Xiao, Sci. Bull., 2023, 68, 2498-2499.
[22]	Z. Ya, S. Zhang, D. Xu, H. Wang, M. Li, ACS Catal., 2025, 15, 5339-5369.
[23]	H. Ran, X. Sun, M. Zheng, Y. Jing, ACS Catal., 2025, 15, 8551-8585.
[24]	H. Yang, Y. Su, J. Liu, J. Liu, D. Fang, F. Liu, J. Colloid Interface Sci., 2026, 703, 139127.
[25]	Y. Yan, L. Hao, Z. Ren, R. Shen, G. Liang, P. Zhang, Y. Teng, D. Xu, X. Li, J. Mater. Sci. Technol., 2026, 249, 305-332.
[26]	Y. Shao, R. Shen, S. Wang, S. Li, P. Zhang, X. Li, Acta Phys.-Chim. Sin., 2025, 41, 100176.
[27]	W. Yu, Chin. J. Catal., 2025, 73, 8-11.
[28]	M. G. Campbell, D. Sheberla, S. F. Liu, T. M. Swager, M. Dincă, Angew. Chem. Int. Ed., 2015, 54, 4349-4352.
[29]	M. Song, X. Song, X. Liu, W. Zhou, P. Huo, Chin. J. Catal., 2023, 51, 180-192.
[30]	S. Krause, N. Hosono, S. Kitagawa, Angew. Chem. Int. Ed., 2020, 59, 15325-15341.
[31]	B. Zhong, J. Hu, X. Yang, Y. Shu, Y. Cai, C.-M. Li, J. Qu, Chin. J. Catal., 2025, 68, 177-203.
[32]	A. Schneemann, V. Bon, I. Schwedler, I. Senkovska, S. Kaskel, R. A. Fischer, Chem. Soc. Rev., 2014, 43, 6062-6096.
[33]	J. Li, X. Yu, W. Xue, L. Nie, H. Huang, C. Zhong, AlChE J., 2023, 69, e17906.
[34]	Z. Chang, D.-H. Yang, J. Xu, T.-L. Hu, X.-H. Bu, Adv. Mater., 2015, 27, 5432-5441.
[35]	Z. Wang, P. Yeary, X. Feng, W. Lin, J. Am. Chem. Soc., 2023, 145, 8647-8655.
[36]	X. Yu, J. Li, M. Du, X. Song, H. Huang, L. Nie, Cell Rep. Phys. Sci., 2023, 4, 101657.
[37]	H. Fang, X.-Y. Liu, H.-J. Ding, M. Mulcair, B. Space, H. Huang, X.-W. Li, S.-M. Zhang, M.-H. Yu, Z. Chang, X.-H. Bu, J. Am. Chem. Soc., 2024, 146, 14357-14367.
[38]	N. Yanai, K. Kitayama, Y. Hijikata, H. Sato, R. Matsuda, Y. Kubota, M. Takata, M. Mizuno, T. Uemura, S. Kitagawa, Nat. Mater., 2011, 10, 787-793.
[39]	X.-C. Sun, X.-C. Li, Z.-W. Xie, C.-Y. Yuan, D.-J. Wang, Q. Zhang, X.-Y. Guo, H. Dong, H.-C. Liu, Y.-W. Zhang, J. Energy Chem., 2024, 91, 475-483.
[40]	K. Sun, Y. Huang, F. Sun, Q. Wang, Y. Zhou, J. Wang, Q. Zhang, X. Zheng, F. Fan, Y. Luo, J. Jiang, H.-L. Jiang, Nat. Chem., 2024, 16, 1638-1646.
[41]	H. Deng, M. A. Olson, J. F. Stoddart, O. M. Yaghi, Nat. Chem., 2010, 2, 439-443.
[42]	D. J. Cerasale, D. C. Ward, T. L. Easun, Nat. Rev. Chem., 2022, 6, 9-30.
[43]	L.-J. Ji, T.-Y. Yang, G.-Q. Feng, S. Li, W. Li, X.-H. Bu, Adv. Mater., 2024, 36, 2404756.
[44]	L.-J. Ji, Y. Qin, D. Gui, W. Li, Y. Li, X. Li, P. Lu, Chem. Mater., 2018, 30, 8732-8738.
[45]	J. Xu, X. Jiao, K. Zheng, W. Shao, S. Zhu, X. Li, J. Zhu, Y. Pan, Y. Sun, Y. Xie, Natl. Sci. Rev., 2022, 9, nwac011.
[46]	S. Deng, R. Cao, X. Wang, Y. Zhou, J. Liang, H. Tang, X. Feng, S. Yang, Y. Shangguan, Y. Li, H. Chen, Nano Lett., 2024, 24, 14082-14090.
[47]	M. Jiang, J. Li, X. Wan, J. Qiu, T. Yao, W. Zhang, S. Ma, H. Tan, A. Han, C. Chen, G. Liu, Nat. Commun., 2025, 16, 4136.
[48]	M. Li, S. Zhang, ACS Catal., 2024, 14, 6717-6727.
[49]	Y. Miao, Y. Zhao, J. Gao, J. Wang, T. Zhang, J. Am. Chem. Soc., 2024, 146, 4842-4850.
[50]	M. Bertoldo, S. Bronco, C. Cappelli, T. Gragnoli, L. Andreotti, J. Phys. Chem. B, 2003, 107, 11880-11888.
[51]	J. Shang, M. Chai, Y. Zhu, Environ. Sci. Technol., 2003, 37, 4494-4499.
[52]	X. Zhao, Z. Li, Y. Chen, L. Shi, Y. Zhu, Appl. Surf. Sci., 2008, 254, 1825-1829.
[53]	X. Jiao, K. Zheng, Q. Chen, X. Li, Y. Li, W. Shao, J. Xu, J. Zhu, Y. Pan, Y. Sun, Y. Xie, Angew. Chem. Int. Ed., 2020, 59, 15497-15501.
[54]	K. Su, T. Gao, C. H. Tung, L. Z. Wu, Angew. Chem. Int. Ed., 2024, 63, e202407464.
[55]	S.-L. Meng, C. Ye, X.-B. Li, C.-H. Tung, L.-Z. Wu, J. Am. Chem. Soc., 2022, 144, 16219-16231.
[56]	Z. Huang, M. Shanmugam, Z. Liu, A. Brookfield, E. L. Bennett, R. Guan, D. E. Vega Herrera, J. A. Lopez-Sanchez, A. G. Slater, E. J. L. McInnes, X. Qi, J. Xiao, J. Am. Chem. Soc., 2022, 144, 6532-6542.
[57]	T.-C. Chou, C.-C. Chang, H.-L. Yu, W.-Y. Yu, C.-L. Dong, J.-J. Velasco-Vélez, C.-H. Chuang, L.-C. Chen, J.-F. Lee, J.-M. Chen, H.-L. Wu, J. Am. Chem. Soc., 2020, 142, 2857-2867.

MOFs中单金属位点到双金属位点的动态配位转变和塑料的级联光重整制CO

Dynamic coordination transformation from single-to dual-metal sites in MOFs for cascaded photoreforming of plastics into CO

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 6

参考文献

相关文章 15

编辑推荐

Metrics

[1]	吕昕彤, 魏正昌, 邓欣, 柴玉超, 武光军, 李兰冬. 分子筛骨架铁锚定孤立铂位点实现高效丙烷脱氢反应[J]. 催化学报, 2026, 84(5): 61-73.
[2]	李伊馨, 邱健豪, 夏广路, 刘琪英, 方碧瑶, 刘梦, 陈晨, 姚建峰. 中空管状In₂O₃修饰氮化碳395 nm光催化木质素C-C键高产率裂解[J]. 催化学报, 2026, 83(4): 209-218.
[3]	王雄, 彭超, 肖永康, 张子烨, 郑慧平, 岳文杰, 田昇, 胡星盛, 邵伟凡, 陈广辉, 王丙昊, 王慧娟, 尹明明, 李锦锌, 李扬, 陈浪, 尹双凤. 通过表面工程提升Bi₂WO_6-_x在选择性C-H键光氧化反应中的催化活性与稳定性[J]. 催化学报, 2026, 81(2): 246-258.
[4]	肖丽媛, 王振旅, 管景奇. 多核金属有机框架材料在电催化中的研究进展[J]. 催化学报, 2026, 80(1): 59-91.
[5]	孙博文, 穆思允, 陈冰冰, 胡国骏, 高瑞, 石川. 碳化钼催化氨分解制氢: Mo/C比调控与相变动力学机制研究[J]. 催化学报, 2025, 74(7): 365-376.
[6]	余维来. 共享金属节点的核壳型金属有机框架促进界面电荷转移[J]. 催化学报, 2025, 73(6): 8-11.
[7]	刘利芳, 肖晔珺, 郭向阳, 金盛烨, 章福祥. 基于过饱和策略的MOFs晶面可控合成用于理解本征晶面效应[J]. 催化学报, 2025, 73(6): 153-158.
[8]	李如硕, 班涛, 赵丹凤, 胡发杰, 林璟, 黄秀兵, 陶志平, 王戈. 缺陷UiO-66(Ce)负载的具有优化微环境和电子态的镍纳米颗粒用于高效烯烃加氢反应[J]. 催化学报, 2025, 72(5): 344-358.
[9]	胡婷婷, 冯盼盼, 褚宏旗, 高腾, 刘福胜, 周卫. 缺陷型介孔MIL-125(Ti)@BiOCl S 型异质结中内建电场的调控机制及光催化性能研究[J]. 催化学报, 2025, 69(2): 123-134.
[10]	郭昊天, 赵路路, 刘欣宇, 李晶, 王鹏飞, 柳宗琳, 王琳琳, 舒杰, 伊廷锋. 静电纺丝技术与MOFs结合: 推动高性能锌空气电池发展[J]. 催化学报, 2025, 79(12): 32-67.
[11]	李可欣, 袁浩, 杨祖保, 胡准. MOF包埋衍生策略缓释氧物种增强甲烷选择性氧化的活性与选择性: 基于瞬时原位红外的研究[J]. 催化学报, 2025, 78(11): 202-214.
[12]	钟百灵, 胡俊蝶, 杨晓刚, 舒银颖, 蔡亚辉, 李长明, 曲家福. 金属有机框架中限域金属物种用于CO₂加氢: 合成方法、催化机理及未来展望[J]. 催化学报, 2025, 68(1): 177-203.
[13]	侯现飚, 于辰, 倪腾嘉, 张树聪, 周健, 代水星, 初蕾, 黄明华. 构筑非晶/晶体NiFe-MOF@NiS异质结构催化剂增强大电流密度下水/海水氧化[J]. 催化学报, 2024, 61(6): 192-204.
[14]	杨冲亚, 王玮珏, 卓红英, 沈铮, 张天雨, 杨小峰, 黄延强. 晶相设计钌基纳米催化剂提高CO₂甲烷化活性[J]. 催化学报, 2024, 61(6): 226-236.
[15]	王长安, 欧阳颖, 罗一斌, 高心茹, 高鸿毅, 王戈, 舒兴田. 相变储热材料强化催化反应过程的研究进展[J]. 催化学报, 2024, 60(5): 128-157.