Silica Sulfuric Acid: An Efficient Heterogeneous Catalyst for the One-Pot Synthesis of 1,4-Dihydropyridines under Mild and Solvent-Free Conditions

doi:10.1016/S1872-2067(10)60252-5

Abstract

Abstract: A series of 1,4-dihydropyridines have been prepared by a one-pot condensation of aldehydes, ethyl acetoacetate, and ammonium acetate in the presence of a heterogeneous catalyst silica sulfuric acid at room temperature under solvent-free condition. This new protocol has the advantage of short reaction time and excellent yields, and is an environmentally benign route to the synthesis of 1,4-dihydropyridines.

Key words: aldehyde, ethyl acetoacetate, ammonium acetate, silica sulfuric acid, 1,4-dihydropyridine

Bandita DATTA, M. Afzal PASHA. Silica Sulfuric Acid: An Efficient Heterogeneous Catalyst for the One-Pot Synthesis of 1,4-Dihydropyridines under Mild and Solvent-Free Conditions[J]. Chinese Journal of Catalysis, 2011, 32(7): 1180-1184.

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