Gold supported on nitrogen-incorporated TS-1 for gas-phase epoxidation of propylene

doi:10.1016/S1872-2067(11)60474-9

Abstract

Abstract: Nitrogen-incorporated titanium silicalite-1 (NTS-1) was used to prepare a supported gold catalyst for direct gas-phase epoxidation of propylene using H₂ and O₂. The NTS-1 was synthesized by direct calcination of the TS-1 powder in a flow of NH₃ at high temperature. Gold catalyst supported on NTS-1 was synthesized by the deposition-precipitation method. The samples were characterized by X-ray diffraction, N₂ adsorption-desorption, diffuse reflectance ultraviolet-visible spectroscopy, inductively coupled plasma optical emission spectrometry, elemental analysis, X-ray photoelectron spectroscopy, and transmission electron microscopy. The results indicated that nitrogen was incorporated into the TS-1 framework, and that the NTS-1 preserved the multidimensional fatigue inventory (MFI) structure well. It was found that NH₃-treatment resulted in decreased acidity of the TS-1 zeolite support and improved both the Au capture efficiency and dispersion, which remarkably improved the catalytic performance. The enhanced activity was ascribed to the decrease in acidic surface sites and the ligand effect of the terminal NH₂ groups on the support surface.

Key words: gold, nitrogen-incorporated titanium silicalite-1, epoxidation, nitridation, propylene oxide, titanium silicalite-1

LIU Yi-Wu, ZHANG Xiao-Ming, SUO Ji-Shuan. Gold supported on nitrogen-incorporated TS-1 for gas-phase epoxidation of propylene[J]. Chinese Journal of Catalysis, 2013, 34(2): 336-340.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60474-9

https://www.cjcatal.com/EN/Y2013/V34/I2/336

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