Sorbitol hydrogenolysis to glycerol and glycols over M-MgO (M=Ni, Co, Cu) nanocomposite: A comparative study of active metals

doi:10.1016/S1872-2067(15)60928-7

Chinese Journal of Catalysis ›› 2015, Vol. 36 ›› Issue (9): 1614-1622.DOI: 10.1016/S1872-2067(15)60928-7

• Articles • Previous Articles Next Articles

Sorbitol hydrogenolysis to glycerol and glycols over M-MgO (M=Ni, Co, Cu) nanocomposite: A comparative study of active metals

Xicheng Wang^a, Xiaoran Liu^a,b, Yue Xu^c, Gongming Peng^a, Quan Cao^a, Xindong Mu^a

a Key Laboratory of Bio-based Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c School of Water Resources and Environment, China University of Geosciences, Beijing 100083, China

Received:2015-04-01 Revised:2015-06-05 Online:2015-08-28 Published:2015-09-26
Supported by:
This work was supported by the National Natural Science Foundation of China (21273260, 21433001), Shandong Provincial Natural Science Foundation for Distinguished Young Scholar, China (JQ201305), and the "135" Projects Fund of CAS-QIBEBT Director Innovation Foundation.

Abstract

Abstract:

The activities and selectivities of MgO-supported Ni, Cu, and Co catalysts have been compared in aqueous-phase hydrogenolysis of sorbitol to glycerol and glycols. All catalysts effectively catalyzed the sorbitol conversion into C2 and C3 polyols like glycerol, 1,2-propylene glycol, and ethylene glycol, but with different product distributions. The differences in activities and selectivities are ascribed to their different dehydrogenation/hydrogenation activities. The influences of base promoter, temperature, H₂ pressure, and reaction time were also studied. Added base promoter and prolonged reaction time enhanced sorbitol conversion for the three catalysts, but led to product degradation and decreased selectivity over Ni-MgO and Co-MgO, whereas selectivity maintained almost unchanged over Cu-MgO.

Key words: Biomass, Hydrogenolysis, Sorbitol, Magnesia, Supported metal catalyst, Bifunctional catalyst

Xicheng Wang, Xiaoran Liu, Yue Xu, Gongming Peng, Quan Cao, Xindong Mu. Sorbitol hydrogenolysis to glycerol and glycols over M-MgO (M=Ni, Co, Cu) nanocomposite: A comparative study of active metals[J]. Chinese Journal of Catalysis, 2015, 36(9): 1614-1622.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60928-7

https://www.cjcatal.com/EN/Y2015/V36/I9/1614

References

[1] Ruppert A M, Weinberg K, Palkovits R. Angew Chem Int Ed, 2012, 51: 2564
[2] Zheng M Y, Pang J F, Wang A Q, Zhang T. Chin J Catal(郑明远, 庞纪峰, 王爱琴, 张涛. 催化学报), 2014, 35: 602
[3] Rinaldi R, Schüth F. Energy Environ Sci, 2009, 2: 610
[4] Wang X C, Meng L Q, Wu F, Jiang Y J, Wang L, Mu X D. Green Chem, 2012, 14: 758
[5] Liu X R, Wang X C, Yao S X, Jiang Y J, Guan J, Mu X D. RSC Adv, 2014, 4: 49501
[6] Ma J P, Yu W Q, Wang M, Jia X Q, Lu F, Xu J. Chin J Catal(马继平, 于维强, 王敏, 贾秀全, 路芳, 徐杰. 催化学报), 2013, 34: 492
[7] Banu M, Venuvanalingam P, Shanmugam R, Viswanathan B, Sivasanker S. Top Catal, 2012, 55: 897
[8] Banu M, Sivasanker S, Sankaranarayanan T M, Venuvanalingam P. Catal Commun, 2011, 12: 673
[9] Zhao L, Zhou J H, Sui Z J, Zhou X G. Chem Eng Sci, 2010, 65: 30
[10] Zhou J H, Liu G C, Sui Z J, Zhou X G, Yuan W K. Chin J Catal(周静红, 刘国才, 隋志军, 周兴贵, 袁渭康. 催化学报), 2014, 35: 692
[11] Leo I M, Granados M L, Fierro J L G, Mariscal R. Chin J Catal(催化学报), 2014, 35: 614
[12] Sun J Y, Liu H C. Catal Today, 2014, 234: 75
[13] Sun J Y, Liu H C. Green Chem, 2011, 13: 135
[14] Wang K Y, Hawley M C, Furney T D. Ind Eng Chem Res, 1995, 34: 3766
[15] Chen X G, Wang X C, Yao S X, Mu X D. Catal Commun, 2013, 39: 86
[16] Guo X H, Li Y, Song W, Shen W J. Catal Lett, 2011, 141: 1458
[17] Guo X H, Li Y, Shi R J, Liu Q Y, Zhan E S, Shen W J. Appl Catal A, 2009, 371: 108
[18] Yuan Z L, Wang J H, Wang L N, Xie W H, Chen P, Hou Z Y, Zheng X M. Bioresour Technol, 2010, 101: 7088
[19] Balaraju M, Jagadeeswaraiah K, Prasad P S S, Lingaiah N. Catal Sci Technol, 2012, 2: 1967
[20] Wang X C, Wu F, Yao S X, Jiang Y J, Guan J, Mu X D. Chem Lett, 2012, 41: 476
[21] Xiao Z H, Jin S H, Pang M, Liang C H. Green Chem, 2013, 15: 891
[22] Ye L M, Duan X P, Lin H Q, Yuan Y Z. Catal Today, 2012, 183: 65
[23] Liu H L, Huang Z W, Xia C G, Jia Y Q, Chen J, Liu H C. ChemCatChem, 2014, 6: 2918
[24] Montassier C, Giraud D, Barbier J. Stud Surf Sci Catal, 1988, 41: 165

Sorbitol hydrogenolysis to glycerol and glycols over M-MgO (M=Ni, Co, Cu) nanocomposite: A comparative study of active metals

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Enara Fernandez, Laura Santamaria, Irati García, Maider Amutio, Maite Artetxe, Gartzen Lopez, Javier Bilbao, Martin Olazar. Elucidating coke formation and evolution in the catalytic steam reforming of biomass pyrolysis volatiles at different fixed bed locations [J]. Chinese Journal of Catalysis, 2023, 48(5): 101-116.
[2]	Duozheng Ma, Xiangcheng Li, Chuang Liu, Caroline Versluis, Yingchun Ye, Zhendong Wang, Eelco T. C. Vogt, Bert M. Weckhuysen, Weimin Yang. SCM-36 zeolite nanosheets applied in the production of renewable p-xylene from ethylene and 2,5-dimethylfuran [J]. Chinese Journal of Catalysis, 2023, 47(4): 200-213.
[3]	Hongfang Wang, Leitao Xu, Jingcheng Wu, Peng Zhou, Shasha Tao, Yuxuan Lu, Xianwen Wu, Shuangyin Wang, Yuqin Zou. Boosting 5-hydroxymethylfurfural electrooxidation in neutral electrolytes via TEMPO-enhanced dehydrogenation and OH adsorption [J]. Chinese Journal of Catalysis, 2023, 46(3): 148-156.
[4]	Yuxuan Lu, Liu Yang, Yimin Jiang, Zhenran Yuan, Shuangyin Wang, Yuqin Zou. Engineering a localized electrostatic environment to enhance hydroxyl activating for electrocatalytic biomass conversion [J]. Chinese Journal of Catalysis, 2023, 53(10): 153-160.
[5]	Wenjuan Zhang, Pei Jing, Juan Du, Shujie Wu, Wenfu Yan, Gang Liu. Interfacial-interaction-induced fabrication of biomass-derived porous carbon with enhanced intrinsic active sites [J]. Chinese Journal of Catalysis, 2022, 43(8): 2231-2239.
[6]	Jiang Zhang, Zijian Wang, Mugeng Chen, Yifeng Zhu, Yongmei Liu, Heyong He, Yong Cao, Xinhe Bao. N-doped carbon layer-coated Au nanocatalyst for H₂-free conversion of 5-hydroxymethylfurfural to 5-methylfurfural [J]. Chinese Journal of Catalysis, 2022, 43(8): 2212-2222.
[7]	Hongbin Chen, Yaqian Ye, Xinzhi Chen, Lili Zhang, Guoxue Liu, Suqing Wang, Liang-Xin Ding. N-doped porous carbon nanofibers inlaid with hollow Co₃O₄ nanoparticles as an efficient bifunctional catalyst for rechargeable Li-O₂ batteries [J]. Chinese Journal of Catalysis, 2022, 43(6): 1511-1519.
[8]	Xiaoqin Han, Jiachang Zuo, Danlu Wen, Youzhu Yuan. Toluene methylation with syngas to para-xylene by bifunctional ZnZrO_x-HZSM-5 catalysts [J]. Chinese Journal of Catalysis, 2022, 43(4): 1156-1164.
[9]	Jianxiang Wu, Xuejing Yang, Ming Gong. Recent advances in glycerol valorization via electrooxidation: Catalyst, mechanism and device [J]. Chinese Journal of Catalysis, 2022, 43(12): 2966-2986.
[10]	Ling Zhou, Yingying Li, Yuxuan Lu, Shuangyin Wang, Yuqin Zou. pH-Induced selective electrocatalytic hydrogenation of furfural on Cu electrodes [J]. Chinese Journal of Catalysis, 2022, 43(12): 3142-3153.
[11]	Huibing Liu, Rixin Xie, Ziqiang Niu, Qiaohuan Jia, Liu Yang, Shitao Wang, Dapeng Cao. Two-in-one strategy to construct bifunctional oxygen electrocatalysts for rechargeable Zn-air battery [J]. Chinese Journal of Catalysis, 2022, 43(11): 2906-2912.
[12]	Xiaoling Liu, Lei Chen, Hongzhong Xu, Shi Jiang, Yu Zhou, Jun Wang. Straightforward synthesis of beta zeolite encapsulated Pt nanoparticles for the transformation of 5-hydroxymethyl furfural into 2,5-furandicarboxylic acid [J]. Chinese Journal of Catalysis, 2021, 42(6): 994-1003.
[13]	Xiaoyan Liu, Guojun Lan, Zhenqing Li, Lihua Qian, Jian Liu, Ying Li. Stabilization of heterogeneous hydrogenation catalysts for the aqueous-phase reactions of renewable feedstocks [J]. Chinese Journal of Catalysis, 2021, 42(5): 694-709.
[14]	Dawang Chu, Yingying Xin, Chen Zhao. Production of bio-ethanol by consecutive hydrogenolysis of corn-stalk cellulose [J]. Chinese Journal of Catalysis, 2021, 42(5): 844-854.
[15]	Dongdong Wang, Wanbing Gong, Jifang Zhang, Miaomiao Han, Chun Chen, Yunxia Zhang, Guozhong Wang, Haimin Zhang, Huijun Zhao. Encapsulated Ni-Co alloy nanoparticles as efficient catalyst for hydrodeoxygenation of biomass derivatives in water [J]. Chinese Journal of Catalysis, 2021, 42(11): 2027-2037.