Highly active Cu/SiO2 catalysts for hydrogenation of diethyl malonate to 1,3-propanediol

doi:10.1016/S1872-2067(15)61053-1

Abstract

Abstract:

Cu/SiO₂ catalysts prepared by the ammonia evaporation method were applied to hydrogenation of diethyl malonate to 1,3-propanediol. The calcination temperature played an important role in the structural evolution and catalytic performance of the Cu/SiO₂ catalysts, which were systematically characterized by N₂ adsorption-desorption, inductively coupled plasma-atomic emission spectroscopy, N₂O chemisorption, X-ray diffraction, Fourier transform infrared spectroscopy, H₂ temperature-programmed reduction, transmission electron microscopy, and X-ray photoelectron spectroscopy. When the Cu/SiO₂ catalyst was calcined at 723 K, 90.7% conversion of diethyl malonate and 32.3% selectivity of 1,3-propanediol were achieved. Compared with Cu/SiO₂ catalysts calcined at other temperatures, the enhanced catalytic performance of the Cu/SiO₂ catalyst calcined at 723 K can be attributed to better dispersion of copper species, larger cupreous surface area and greater amount of copper phyllosilicate, which results in a higher ratio of Cu⁺/Cu⁰. The synergetic effect of Cu⁰ and Cu⁺ is suggested to be responsible for the optimum activity.

Key words: Copper, Silica, Diethyl malonate, Hydrogenation, 1,3-Propanediol, Calcination temperature

Tongmei Ding, Hengshui Tian, Jichang Liu, Wenbin Wu, Jintao Yu. Highly active Cu/SiO₂ catalysts for hydrogenation of diethyl malonate to 1,3-propanediol[J]. Chinese Journal of Catalysis, 2016, 37(4): 484-493.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61053-1

https://www.cjcatal.com/EN/Y2016/V37/I4/484

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Highly active Cu/SiO₂ catalysts for hydrogenation of diethyl malonate to 1,3-propanediol

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