Production of 5-Hydroxymethylfurfural from Cellulose Catalyzed by Lewis Acid under Microwave Irradiation in Ionic Liquid

doi:10.3724/SP.J.1088.2010.00149

Chinese Journal of Catalysis ›› 2010, Vol. 31 ›› Issue (9): 1157-1161.DOI: 10.3724/SP.J.1088.2010.00149

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Production of 5-Hydroxymethylfurfural from Cellulose Catalyzed by Lewis Acid under Microwave Irradiation in Ionic Liquid

WU Shuchang1,2, WANG Chunlei1, GAO Yongjun1,2, ZHANG Shaochun3, MA Ding1,*, ZHAO Zongbao1,4

1State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China 2Graduate University of Chinese Academy of Sciences, Beijing 100049, China 3School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China 4Dalian National Laboratory of Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2010-09-30 Online:2010-09-30 Published:2014-01-25

Abstract

Abstract: Direct conversion of cellulose into 5-hydroxymethylfurfural (HMF) catalyzed by CrCl3•6H2O in ionic liquid 1-butyl-3-methylimidazolium chloride ([bmim]Cl) was described with the promotion of microwave. The effects of microwave irradiation setting, reaction temperature, reaction time, and catalyst amount on HMF yield were investigated. The results showed that cellulose was converted into HMF rapidly and efficiently in [bmim]Cl with the HMF yield of 55%.

Key words: ionic liquid, microwave, Lewis acid, cellulose, 5-hydroxymethylfurfural

WU Shuchang1,2, WANG Chunlei1, GAO Yongjun1,2, ZHANG Shaochun3, MA Ding1,*, ZHAO Zongbao1,4. Production of 5-Hydroxymethylfurfural from Cellulose Catalyzed by Lewis Acid under Microwave Irradiation in Ionic Liquid[J]. Chinese Journal of Catalysis, 2010, 31(9): 1157-1161.

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Production of 5-Hydroxymethylfurfural from Cellulose Catalyzed by Lewis Acid under Microwave Irradiation in Ionic Liquid

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