Bi掺杂NaTaO3中Bi的化学价态对其光催化性能的影响

doi:10.1016/S1872-2067(15)60858-0

催化学报 ›› 2015, Vol. 36 ›› Issue (7): 969-974.DOI: 10.1016/S1872-2067(15)60858-0

Bi掺杂NaTaO₃中Bi的化学价态对其光催化性能的影响

崔华楠, 石建英, 刘鸿

中山大学化学与化学工程学院, 环境与能源化学广东普通高校重点实验室, 广东广州510275

收稿日期:2014-12-29 修回日期:2015-03-28 出版日期:2015-06-12 发布日期:2015-07-30
通讯作者: 石建英, 电话: (020)84114227; 电子信箱: shijying@mail.sysu.edu.cn;刘鸿, 电话: (020)84115573; 传真: (020)84110927; 电子信箱: ceshliu@mail.sysu.edu.cn
基金资助:
国家自然科学基金(21103235); 广州市科技计划(2013J4100110).

Influence of Bi chemical state on the photocatalytic performance of Bi-doped NaTaO₃

Huanan Cui, Jianying Shi, Hong Liu

Key Laboratory of Environment and Energy Chemistry of Guangdong Higher Education Institutes, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, Guangdong, China

Received:2014-12-29 Revised:2015-03-28 Online:2015-06-12 Published:2015-07-30
Supported by:
This work was supported by the National Natural Science Foundation of China (21103235) and the Science and Technology Program of Guangzhou City (2013J4100110).

摘要/Abstract

摘要：

分别采用NaBiO₃和Bi(NO₃)₃为Bi源制备了Bi掺杂NaTaO₃光催化剂, 研究了Bi离子的价态对NaTaO₃光催化分解水制氢性能的影响. 采用X射线衍射(XRD)、拉曼光谱、X射线光电子能谱(XPS)和紫外-可见吸收光谱研究了催化剂的晶体结构、Bi离子的化学状态和催化剂的光学吸收性能. 以光催化分解水制氢反应研究了Bi离子掺杂NaTaO₃的催化性能. XRD结果表明, 对于两个不同Bi源掺杂的NaTaO₃样品, Bi离子的掺杂没有改变催化剂的单斜相结构, 但拉曼光谱证实Bi离子的掺杂致使Ta-O-Ta键角偏离了180°. XPS结果表明, 以Bi(NO₃)₃为Bi源时, Bi离子以Bi³⁺掺杂于NaTaO₃的A位; 当以NaBiO₃为原料时, Bi³⁺和Bi⁵⁺共掺杂于NaTaO₃的A位. 两种不同Bi源掺杂得到的样品在紫外-可见吸收光谱中给出了相似的光学吸收, 但Bi³⁺的掺杂对NaTaO₃光催化性能影响不大, 而Bi³⁺和Bi⁵⁺共掺杂大大提高了NaTaO₃的光解水制氢性能. Bi离子取代Na离子在A位的掺杂, 在NaTaO₃结构中引入了能够促进载流子分离的空位和缺陷; 与此同时, Bi的掺杂导致Ta-O-Ta键角偏离180^o而不利于载流子迁移. 对于Bi³⁺掺杂的NaTaO₃样品, 这两种作用相互抵消, 使得其催化性能与NaTaO₃相比没有变化; 而Bi³⁺和Bi⁵⁺的共掺杂和高价态Bi⁵⁺的掺杂引入了更多的空位和缺陷, 提高了光生电子-空穴的分离效率, 从而提高了光催化产氢性能. 研究表明, 光催化过程中载流子的迁移是影响催化性能的重要因素, 而在ABO₃钙钛矿结构的A位引入高价态离子是促进光生载流子分离的有效途径.

关键词: 光催化剂, 钽酸钠, Bi掺杂, 化学价态, 水分解

Abstract:

NaBiO₃ and Bi(NO₃)₃ were used to synthesize Bi-doped NaTaO₃. The influence of the Bi chemical state on the photocatalytic activity was investigated using X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and diffused reflectance spectroscopy to study the structure, chemical state and light absorption characteristics, respectively. The photocatalytic activity was evaluated by the H₂ evolution water splitting reaction. The monoclinic phase of NaTaO₃ remained intact for the two Bi-doped samples, but the Ta-O-Ta bond was distorted from 180° after Bi doping. XPS results indicated that Bi³⁺ was doped into NaTaO₃ with the Bi(NO₃)₃ precursor, while Bi⁵⁺ and Bi³⁺ were doped into NaTaO₃ with the NaBiO₃ precursor. The two samples showed identical light absorption, where doping with Bi extended the light absorption to long wavelength light as expected. However, Bi³⁺ doping did not promote the photocatalytic activity of NaTaO₃, while Bi⁵⁺ and Bi³⁺ doping did. The distorted Ta-O-Ta bond from 180° due to doping with Bi was detrimental for charge carrier transfer in the photocatalytic process. In contrast, the vacancies or defects in the NaTaO₃ lattice induced by Bi doping for charge balance were beneficial for charge carrier separation. The opposing action of these two factors resulted in the activity of the Bi³⁺-doped sample being comparable with pristine NaTaO₃. For Bi⁵⁺- and Bi³⁺-doped NaTaO₃, a high concentration of defects was induced by the high valence Bi⁵⁺ ion and this led to its higher photocatalytic activity. Our results indicated that charge carrier transfer is a priority factor in the photocatalytic process and the doping of a high valence ion in the ABO₃ structure is a way to promote the separation of charge carriers.

Key words: Photocatalyst, Sodium tantalum oxide, Bi doping, Chemical state, Water splitting

崔华楠, 石建英, 刘鸿. Bi掺杂NaTaO₃中Bi的化学价态对其光催化性能的影响[J]. 催化学报, 2015, 36(7): 969-974.

Huanan Cui, Jianying Shi, Hong Liu. Influence of Bi chemical state on the photocatalytic performance of Bi-doped NaTaO₃[J]. Chinese Journal of Catalysis, 2015, 36(7): 969-974.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(15)60858-0

https://www.cjcatal.com/CN/Y2015/V36/I7/969

参考文献

[1] Maeda K, Teramura K, Lu D L, Takata T, Saito N, Inoue Y, Domen K. Nature, 2006, 440: 295
[2] Kang H W, Kim E J, Park S B. Int J Photoenergy, 2008, Article ID 519643
[3] Kato H, Kobayashi H, Kudo A. J Phys Chem B, 2002, 106: 12441
[4] Ishihara T, Nishiguchi H, Fukamachi K, Takita Y. J Phys Chem B, 1999, 103: 1
[5] Mizoguchi H, Ueda K, Orita M, Moon S C, Kajihara K, Hirano M, Hosono H. Mater Res Bull, 2002, 37: 2401
[6] Ouyang S X, Tong H, Umezawa N, Cao J Y, Li P, Bi Y P, Zhang Y J, Ye J H. J Am Chem Soc, 2012, 134: 1974
[7] Kudo A, Miseki Y. Chem Soc Rev, 2009, 38: 253
[8] Ditzig J, Liu H, Logan B E. Int J Hydrogen Energy, 2007, 32: 2296
[9] Kudo A, Niishiro R, Iwase A, Kato H. Chem Phys, 2007, 339: 104
[10] Kang H W, Lim S N, Park S B. Int J Hydrogen Energy, 2012, 37: 4026
[11] Gao Y, Su Y G, Meng Y, Wang S W, Jia Q Y, Wang X J. Integr Ferroelectr, 2011, 127: 106
[12] Liu Y L, Su Y G, Han H, Wang X J. J Nanosci Nanotechnol, 2013, 13: 853
[13] Husin H, Su W N, Chen H M, Pan C J, Chang S H, Rick J, Chuang W T, Sheu H S, Hwang B J. Green Chem, 2011, 13: 1745
[14] Hu C C, Lee Y L, Teng H S. J Mater Chem, 2011, 21: 3824
[15] Li X, Zang J L. Catal Commun, 2011, 12: 1380
[16] Iwase A, Kato H, Kudo A. ChemSusChem, 2009, 2: 873
[17] Kudo A, Kato H. Chem Phys Lett, 2000, 331: 373
[18] Zhou X, Shi J Y, Li C. J Phys Chem C, 2001, 115: 8305
[19] Kanhere P, Nisar J, Tang Y X, Pathak B, Ahuja R, Zheng J W, Chen Z. J Phys Chem C, 2012, 116: 22767
[20] Kang H W, Lim S N, Park S B, Park A H A. Int J Hydrogen Energy, 2013, 38: 6323
[21] Liu H M, Nakamura R, Nakato Y. J Electrochem Soc, 2005, 152: G856
[22] Konig J, Jancar B, Suvorov D. J Am Ceram Soc, 2007, 90: 3621
[23] Wang X J, Bai H L, Meng Y, Zhao Y H, Tang C H, Gao Y. J Nanosci Nanotechnol, 2010, 10: 1788
[24] Kanhere P D, Zheng J W, Chen Z. J Phys Chem C, 2011, 115: 11846
[25] Li Z G, Wang Y X, Liu J W, Chen G, Li Y X, Zhou C. Int J Hydrogen Energy, 2009, 34: 147
[26] Shi J Y, Chen T, Zhou G H, Feng Z C, Ying P L, Li C. Chem J Chin Univ (石建英, 陈涛, 周国华, 冯兆池, 应品良, 李灿. 高等学校化学学报), 2007, 28: 692
[27] Shi J Y, Cui H N, Liang Z X, Lu X H, Tong Y X, Su C Y, Liu H. Energy Environ Sci, 2011, 4: 466
[28] Perry C H, Tornberg N E. Phys Rev, 1969, 183: 595
[29] Hu C C, Teng H. Appl Catal A, 2007, 331: 44
[30] Sidorov N V, Palatnikov M N, Mel’nik N N, Kalinnikov V T. J Appl Spectroscopy, 2000, 67: 259
[31] Reddy K H, Martha S, Parida K M. RSC Adv, 2012, 2: 9423
[32] Shi R, Lin J, Wang Y J, Xu J, Zhu Y F. J Phys Chem C, 2010, 114: 6472

Bi掺杂NaTaO₃中Bi的化学价态对其光催化性能的影响

Influence of Bi chemical state on the photocatalytic performance of Bi-doped NaTaO₃

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	蔡铭洁, 刘艳萍, 董珂欣, 陈晓波, 李世杰. 漂浮型Bi₂WO₆/C₃N₄/碳布S型异质结光催化材料用于高效净化水体环境[J]. 催化学报, 2023, 52(9): 239-251.
[2]	乔蔚, 于立策, 常进法, 杨甫林, 冯立纲. MoSe₂纳米片耦合Pt纳米颗粒用于高效双功能催化甲醇辅助水电解制氢[J]. 催化学报, 2023, 51(8): 113-123.
[3]	袁鑫, 范海滨, 刘杰, 覃龙州, 王剑, 段秀, 邱江凯, 郭凯. 连续流技术在光氧化还原催化转化的最新进展[J]. 催化学报, 2023, 50(7): 175-194.
[4]	Mengistu Tulu Gonfa, 申升, 陈浪, 胡彪, 周威, 白张君, 区泽堂, 尹双凤. 光催化苯制苯酚的研究进展[J]. 催化学报, 2023, 49(6): 16-41.
[5]	韦之栋, 严嘉玮, 郭伟琦, 上官文峰. 多面体SrTiO₃原位生长N缺陷PCN中的纳米叠层效应助力光催化完全分解水: 内建电场调控的协同机制[J]. 催化学报, 2023, 48(5): 279-289.
[6]	李宁, 高雪云, 苏俊珲, 高旸钦, 戈磊. 类金属WO₂/g-C₃N₄复合光催化剂的构造及其优异的光催化性能[J]. 催化学报, 2023, 47(4): 161-170.
[7]	李钱, 唐麒君, 熊珮瑶, 陈东之, 陈建孟, 吴忠标, 王海强. 钯化学态对g-C₃N₄光催化还原CO₂的影响: 单原子态在促进CH₄生成中的独特作用[J]. 催化学报, 2023, 46(3): 177-190.
[8]	李晓宁, 郝崇琰, 杜雨蒙, 卢昀, 范亚蒙, 王明月, 王娜娜, 孟瑞晋, 王晓临, 徐梽川, 程振翔. 利用磁场加速析氧反应[J]. 催化学报, 2023, 55(12): 191-199.
[9]	吴立清, 梁庆, 赵家仪, 朱娟, 贾宏男, 张伟, 蔡苹, 罗威. 铋掺杂的二氧化钌催化剂用于高效酸性水氧化[J]. 催化学报, 2023, 55(12): 182-190.
[10]	王宁宁, 王硕, 李灿, 李晨阳, 刘春江, 陈闪山, 章福祥. ZrO₂修饰均匀氮掺杂氧化物MgTa₂O_6-_xN_x以提升其光催化分解水性能[J]. 催化学报, 2023, 54(11): 220-228.
[11]	刘伟旭, 贺唱, 朱博文, 朱恩伟, 张亚宁, 陈云宁, 李军山, 朱永法. 利用有机超分子光催化剂在太阳光下处理污水的研究进展[J]. 催化学报, 2023, 53(10): 13-30.
[12]	雷一鸣, 叶金花, Jordi García-Antón, 刘慧敏. 内建电场辅助光催化甲烷干重整的研究进展[J]. 催化学报, 2023, 53(10): 72-101.
[13]	Shunta Nishioka, Kengo Shibata, Yugo Miseki, Kazuhiro Sayama, Kazuhiko Maeda. 可见光驱动改性氮化碳无牺牲剂光催化析氢[J]. 催化学报, 2022, 43(9): 2316-2320.
[14]	孙万军, 朱佳玉, 张美玉, 孟翔宇, 陈梦雪, 冯钰, 陈新龙, 丁勇. 钴基非均相催化剂在光催化水分解、二氧化碳还原和氮还原的研究进展与展望[J]. 催化学报, 2022, 43(9): 2273-2300.
[15]	李志伟, 黄辉庭, 罗文俊, 胡颖飞, 范容莉, 朱治, 王骏, 冯建勇, 李朝升, 邹志刚. 电化学处理构建表面电荷传输通道用于高效光电催化分解水[J]. 催化学报, 2022, 43(9): 2342-2353.