BiOBr/Ni2P/g-C3N4体系中用Ni2P电子桥加速S型体系光生载流子分离

doi:10.1016/S1872-2067(21)63817-2

催化学报 ›› 2022, Vol. 43 ›› Issue (2): 276-287.DOI: 10.1016/S1872-2067(21)63817-2

BiOBr/Ni₂P/g-C₃N₄体系中用Ni₂P电子桥加速S型体系光生载流子分离

陈男男^a, 贾雪梅^a, 何恒^a, 林海莉^a^,^*(), 郭敏娜^a, 曹静^a, 张金锋^b, 陈士夫^a^,^#()

^a淮北师范大学化学与材料科学学院, 绿色和精准合成化学及应用教育部重点实验室, 安徽淮北 235000
^b淮北师范大学物理与电子信息学院, 安徽淮北 235000

收稿日期:2021-01-31 接受日期:2021-03-28 出版日期:2022-02-18 发布日期:2021-05-20
通讯作者: 林海莉,陈士夫
基金资助:
国家自然科学基金(21902056);国家自然科学基金(51972134);国家自然科学基金(51772118);国家自然科学基金(51973078);安徽省自然科学基金(1908085MB36)

Promoting photocarriers separation in S-scheme system with Ni₂P electron bridge: The case study of BiOBr/Ni₂P/g-C₃N₄

Nannan Chen^a, Xuemei Jia^a, Heng He^a, Haili Lin^a^,^*(), Minna Guo^a, Jing Cao^a, Jinfeng Zhang^b, Shifu Chen^a^,^#()

^aKey Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, College of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, Anhui, China
^bCollege of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, Anhui, China

Received:2021-01-31 Accepted:2021-03-28 Online:2022-02-18 Published:2021-05-20
Contact: Haili Lin, Shifu Chen
Supported by:
This work was supported by the National Natural Science Foundation of China(21902056);This work was supported by the National Natural Science Foundation of China(51972134);This work was supported by the National Natural Science Foundation of China(51772118);This work was supported by the National Natural Science Foundation of China(51973078);the Natural Science Foundation of Anhui Province(1908085MB36)

摘要/Abstract

摘要：

水污染对人类健康和生态环境造成了严重的危害, 引起了人们广泛关注. 半导体光催化技术被认为是一种去除废水中有机污染物的有效方法. 近年来, 石墨相氮化碳(g-C₃N₄)作为一种无金属的光催化剂, 具有合适的带隙能(E_g ≈ 2.7 eV)、良好的化学稳定性、较好的热稳定性、无毒以及强的还原电位(E_CB ≈ -1.3 eV)等特点, 表现出较好的光催化活性. 但由于g-C₃N₄光生载流子复合快和量子效率低, 限制了其实际应用. 因此, 研究者们开发了各种有效的方法来克服上述缺点, 如调控形貌、掺杂离子、沉积贵金属和构建异质结等. 其中, 构建梯型(S型)异质结已被证实是提高复合材料光催化活性的一种有效策略. S型异质结的形成不仅有效地加速光生电子和空穴的分离和迁移, 而且还增强了光生载流子的氧化还原能力. 除了电子结构外, 异质结的界面电阻直接影响着光生载流子的分离效率, 从而决定光催化活性强弱. 据报道, 具有高导电性的“电子传递介质”或“电子桥”可有效地降低载流子迁移过程中的界面阻力. 过渡金属磷化物具有优良的导电性、低廉的价格和无毒的特性, 完全满足电子桥的要求, 成为电子桥的最佳候选材料之一.
结合S型异质结和电子桥的优势, 本文采用沉积-沉淀法制备了一种新型的S型BiOBr/Ni₂P/g-C₃N₄异质结. 在可见光(λ ≥ 400 nm)下, 该催化剂对甲基橙和罗丹明B的降解活性明显优越于BiOBr/g-C₃N₄. 这主要归因于电子桥Ni₂P和S型异质结的协同效应. 密度泛函理论计算表明, 电子从BiOBr通过电子桥Ni₂P转移到g-C₃N₄. 在可见光照射下以及界面内建电场的驱动下, 带边缘弯曲和库仑相互作用协同促进了复合物中相对无用的电子和空穴的重组, 从而保留了较强氧化还原能力的电子和空穴. 活性氧捕获实验、电子顺磁共振光谱和电流-电压曲线结果进一步证明, 光催化剂中的电荷迁移方式遵循S型异质结的迁移机制. 综上, 本文不仅为S型光催化剂的设计提供了有效策略, 也为界面载流子的快速分离和迁移提供了切实可行的途径.

关键词: BiOBr/Ni₂P/g-C₃N₄, S模式, 界面电子迁移, 电子桥, 光催化剂

Abstract:

Constructing step-scheme (S-scheme) heterojunctions can considerably facilitate separation and transfer of photocarriers, as well as promote strong redox ability. The interface resistance of heterojunctions immediately affects photocarrier separation and determines the photocatalytic activity. Herein, we constructed a novel BiOBr/Ni₂P/g-C₃N₄ heterojunction using Ni₂P as a novel electron bridge to reduce the interfacial resistance of photocarriers between BiOBr and g-C₃N₄. The as-prepared 10% BiOBr/Ni₂P/g-C₃N₄ sample exhibited outstanding visible-light photocatalytic performance for methyl orange and rhodamine B removal, with degradation efficiencies of 91.4% and 98.9%, respectively. The excellent photocatalytic activity of BiOBr/Ni₂P/g-C₃N₄ was mainly attributed to the synergistic effects of the Ni₂P cocatalyst and S-scheme heterojunction, which not only reduced the interface resistance but also retained the strong redox potential of the photocarriers. In addition, the formation of the S-scheme system was supported by active oxygen species investigation, current-voltage curves, and density functional theory calculations. This work provides a guideline for the design of highly efficient S-scheme photocatalysts with transition metal phosphates as electron bridges to improve photocarriers separation.

Key words: BiOBr/Ni₂P/g-C₃N₄, S-scheme, Interfacial electron transfer, Electron-bridge, Photocatalysis

陈男男, 贾雪梅, 何恒, 林海莉, 郭敏娜, 曹静, 张金锋, 陈士夫. BiOBr/Ni₂P/g-C₃N₄体系中用Ni₂P电子桥加速S型体系光生载流子分离[J]. 催化学报, 2022, 43(2): 276-287.

Nannan Chen, Xuemei Jia, Heng He, Haili Lin, Minna Guo, Jing Cao, Jinfeng Zhang, Shifu Chen. Promoting photocarriers separation in S-scheme system with Ni₂P electron bridge: The case study of BiOBr/Ni₂P/g-C₃N₄[J]. Chinese Journal of Catalysis, 2022, 43(2): 276-287.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(21)63817-2

https://www.cjcatal.com/CN/Y2022/V43/I2/276

图/表 10

Fig. 1. XRD patterns of g-C3N4, BiOBr, Ni2P, Ni2P/g-C3N4, BiOBr/g-C3N4, and BNC composites.

Fig. 2. XPS spectra of 10% BNC composite and reference samples. (a) Survey spectra; (b) C 1s; (c) N 1s; (d) O 1s; (e) Ni 2p; (f) P 2p; (g) Bi 4f; (h) Br 3d.

Fig. 3. SEM images of g-C3N4 (a), BiOBr (b), Ni2P (c), and 10% BNC (d); TEM (e) and HRTEM (f) images of the 10% BNC composite; (g) TEM and STEM-EDX elemental mapping for the 10% BNC composite: C, Ni, N, P, Bi, O, and Br.

Fig. 4. N2 adsorption-desorption isotherms (a) and pore size distribution (b) of g-C3N4, BiOBr, Ni2P, Ni2P/g-C3N4, 10% BiOBr/g-C3N4, and BNC composites.

Fig. 5. (a) UV-vis diffuse reflectance spectra of as-prepared samples; the corresponding band gap energies (b,c), Mott-Schottky curves (d,e) of g-C3N4 and BiOBr.

Fig. 6. Photocatalytic activities (a,c), and the corresponding reaction rate constants kapp (b,d) for the as-obtained photocatalysts for MO (a,b) and RhB (c,d) degradation under visible light (λ ≥ 400 nm) irradiation.

Fig. 7. Recycling test of 10% BNC for the degradation of MO under visible light (λ ≥ 400 nm) irradiation.

Fig. 8. EIS (a), TPR (b), PL (c), and TRPL (d) spectra of g-C3N4, Ni2P/g-C3N4, 10% BiOBr/g-C3N4, 10% BNC, BiOBr, and Ni2P.

Fig. 9. (a) Trapping experiment of active species; EPR responses of the DMPO-•O2- (b) and DMPO-•OH (c) spin adducts over 10% BNC; (d) Current-voltage curves of g-C3N4 and BiOBr under visible light (λ ≥ 400 nm) irradiation.

Fig. 10. The work functions of BiOBr (a), Ni2P (b), and g-C3N4 (c), and insets showing the corresponding calculation model. Schematic illustration of heterostructures: (d) before contact, (e) after contact in darkness, and (f) photogenerated charge carrier transfer process in S-scheme heterojunction under illumination.

参考文献

[1]	X. Li, J. G. Yu, M. Jaroniec, X. B. Chen, Chem Rev., 2019,119, 3962-4179.
[2]	Q. L. Xu, L. Y. Zhang, B. Cheng, J. J. Fan, J. G. Yu, Chem, 2020,6, 1543-1559.
[3]	K. Li, M. X. Ji, R. Chen, Q. Jiang, J. X. Xia, H. M. Li, Chin. J. Catal., 2020,41, 1230-1239.
[4]	X. M. Jia, J. Cao, H. L. Lin, M. Y. Zhang, X. M. Guo, S. F. Chen, Appl. Catal. B, 2017,204, 505-514.
[5]	Y. F. Li, M. H. Zhou, B. Cheng, Y. Shao, J. Mater. Sci. Technol., 2020,56, 1-17.
[6]	J. Q. Wen, J. Xie, X. B. Chen, X. Li, Appl. Surf. Sci., 2017,391, 72-123.
[7]	A. Y. Meng, Z. Y. Teng, Q. T. Zhang, C. L. Su, Chem. Asian J., 2020,15, 3405-3415.
[8]	Z. F. Jiang, W. M. Wan, H. M. Li, S. Q. Yuan, H. J. Zhao, P. K. Wong, Adv. Mater., 2018,30, 1706108.
[9]	H. H. Gao, H. C. Yang, J. Z. Xu, S. W. Zhang, J. X. Li, Small, 2018,14, 1801353.
[10]	Y. J. Ren, D. Q. Zeng, W. J. Ong, Chin. J. Catal., 2019,40, 289-319.
[11]	L. M. Hu, J. T. Yan, C. L. Wang, B. Chai, J. F. Li, Chin. J. Catal., 2019,40, 458-469.
[12]	S. W. Liu, F. Chen, S. T. Li, X. X. Peng, Y. Xiong, Appl. Catal. B, 2017,211, 1-10.
[13]	J. W. Fu, B. C. Zhu, C. J. Jiang, B. Cheng, W. You, J. G. Yu, Small, 2017,13, 1603938.
[14]	R. M. Irfan, M. H. Tahir, M. Nadeem, M. Maqsood, T. Bashir, S. Iqbal, J. Q. Zhao, L. J. Gao, Appl. Catal. A, 2020,603, 117768.
[15]	Y. X. Dong, J. T. Cao, B. Wang, S. H. Ma, Y. M. Liu, ACS Appl. Mater. Interfaces, 2018,10, 3723-3731.
[16]	Y. Lia, X. Li, H. W. Zhang, J. J. Fan, Q. J. Xiang, J. Mater. Sci. Technol., 2020,56, 69-88.
[17]	Y. S. Xu, Z. F. Zhang, C. T. Qiu, S. Q. Chen, X. Ling, C. L. Su, ChemSusChem, 2021,14, 582-589.
[18]	Q. L. Xu, L. Y. Zhang, B. Cheng, J. J. Fan, J. G. Yu, Chem, 2020,6, 1543-1559
[19]	L. Z. Liu, T. P. Hu, K. Dai, J. F. Zhang, C. H. Liang, Chin. J. Catal., 2021,42, 46-55.
[20]	F. Y. Xu, K. Meng, B. Cheng, S. Y. Wang, J. S. Xu, J. G. Yu, Nat. Commun., 2020,11, 4613.
[21]	P. F. Xia, S. W. Cao, B. C. Zhu, M. J. Liu, M. S. Shi, J. G. Yu, Y. F. Zhang, Angew. Chem. Int. Ed., 2020,59, 5218-5225.
[22]	H. N. Ge, F. Y. Xu, B. Cheng, J. G. Yu, W. Ho, ChemCatChem, 2019,11, 6301-6309.
[23]	Q. Q. Li, W. L. Zhao, Z. C. Zhai, K. X. Ren, T. Y. Wang, H. Guan, H. F. Shi, J. Mater. Sci. Technol., 2020,56, 216-226.
[24]	D. D. Ren, W. N. Zhang, Y. N. Ding, R. C. Shen, Z. M. Jiang, X. Y. Lu, X. Li, Sol. RRL, 2019,4, 1900423.
[25]	X. L. Wu, C. Y. Toe, C. L. Su, Y. H. Ng, R. Amal, J. Scott, J. Mater. Chem. A, 2020,8, 15302-15318.
[26]	Y. Liu, Z. F. Hu, J. C. Yu, Chem. Mater., 2020,32, 1488-1494.
[27]	J. H. Li, F. Yang, Q. Zhou, R. P. Ren, L. J. Wu, Y. K. Lv, J. Colloid Interface Sci., 2019,546, 139-151.
[28]	X. B. Li, J. Xiong, X. M. Gao, J. Ma, Z. Chen, B. B. Kang, J. Y. Liu, H. Li, Z. J. Feng, J. T. Huang, J. Hazard. Mater., 2020,387, 121690.
[29]	Z. Q. Long, G. M. Zhang, H. B. Du, J. Zhu, J. W. Li, J. Hazard. Mater., 2021,407, 124394.
[30]	H. Tada, T. Mitsui, T. Kiyonaga, T. Akita, K. Tanaka, Nat. Mater., 2006,5, 782-786.
[31]	Y. C. Yan, X. Q. Zhou, P. Yu, Z. F. Li, T. L. Zheng, Appl. Catal. A, 2020,590, 117282.
[32]	X. Q. Yan, M. Y. Xia, B. R. Xu, J. J. Wei, B. L. Yang, G. D. Yang, Appl. Catal. B, 2018,232, 481-491.
[33]	J. He, D. W. Shao, L. C. Zheng, L. J. Zheng, D. Q. Feng, J. P. Xu, X. H. Zhang, W. C. Wang, W. H. Wang, F. Lu, H. Dong, Y. H. Cheng, H. Liu, R. K. Zheng, Appl. Catal. B, 2017,203, 917-926.
[34]	Z. Zhao, Y. B. Xing, H. B. Li, P. Y. Feng, Z. C. Sun, Sci. China Mater., 2017,61, 851-860.
[35]	A. Iwase, Y. H. Ng, Y. Ishiguro, A. Kudo, R. Amal, J. Am. Chem. Soc., 2011,133, 11054-11057.
[36]	M. M. Zhang, C. Lai, B. S. Li, D. L. Huang, G. M. Zeng, P. Xu, L. Qin, S. Y. Liu, X. Liu, H. Yi, M. F. Li, C. C. Chu, Z. Chen, J. Catal., 2019,369, 469-481.
[37]	B. J. Ng, L. K. Putri, L. L. Tan, P. Pasbakhsh, S. P. Chai, Chem. Eng. J., 2017,316, 41-49.
[38]	J. Wang, Y. Xia, H. Y. Zhao, G. F. Wang, L. Xiang, J. L. Xu, S. Komarneni, Appl. Catal. B, 2017,206, 406-416.
[39]	S. X. Lu, H. H. Xu, B. Y. Gao, L. L. Ren, New J. Chem., 2017,41, 8497-8502.
[40]	E. J. Popczun, J. R. McKone, C. G. Read, A. J. Biacchi, A. M. Wiltrout, N. S. Lewis, R. E. Schaak, J. Am. Chem. Soc., 2013,135, 9267-9270.
[41]	Z. J. Sun, H. F. Zheng, J. S. Li, P. W. Du, Energy Environ. Sci., 2015,8, 2668-2676.
[42]	R. C. Shen, J. Xie, Q. J. Xiang, X. B. Chen, J. Z. Jiang, X. Li, Chin. J. Catal., 2019,40, 240-288.
[43]	H. He, J. Cao, M. N. Guo, H. L. Lin, J. F. Zhang, Y. Chen, S. F. Chen, Appl. Catal. B, 2019,249, 246-256.
[44]	P. Niu, L. L. Zhang, G. Liu, H. M. Cheng, Adv. Funct. Mater., 2012,22, 4763-4770.
[45]	W. J. Wang, T. C. An, G. Y. Li, D. H. Xia, H. J. Zhao, J. C. Yu, P. K. Wong, Appl. Catal. B, 2017,217, 570-580.
[46]	J. Wang, J. Y. Yang, Z. Y. Zheng, T. B. Lu, W. H. Gao, Appl. Catal. B, 2017,218, 277-286.
[47]	C. Wu, P. Kopold, P. A. van Aken, J. Maier, Y. Yu, Adv. Mater., 2017,29, 1604015.
[48]	J. L. Yuan, J. Q. Wen, Y. M. Zhong, X. Li, Y. P. Fang, S. S. Zhang, W. Liu, J. Mater. Chem. A, 2015,3, 18244-18255.
[49]	Z. F. Huang, J. J. Song, X. Wang, L. Pan, K. Li, X.W. Zhang, L. Wang, J. J. Zou, Nano Energy, 2017,40, 308-316.
[50]	J. Liu, Y. Liu, N. Y. Liu, Y. Z. Han, X. Zhang, H. Huang, Y. Lifshitz, S. T. Lee, J. Zhong, Z. H. Kang, Science, 2015,347, 970-974.
[51]	D. Jiang, X. J. Du, D. Y. Chen, Y. Q. Li, N. Hao, J. Qian, H. Zhong, T. Y. You, K. Wang, Carbon, 2016,102, 10-17.
[52]	B. Chang, Z. Z. Ai, D. Shi, Y. Y. Zhong, K. Zhang, Y. L. Shao, L. Zhang, J. X. Shen, Y. Z. Wu, X. P. Hao, J. Mater. Chem. A, 2019,7, 19573-19580.
[53]	F. R. Guo, J. C. Chen, J. Z. Zhao, Z. Chen, D. S. Xia, Z. L. Zhan, Q. Wang, Chem. Eng. J., 2020,386, 124014.
[54]	H. F. Li, A. Q. Ma, D. Zhang, Y. Q. Gao, Y. D. Dong, RSC Adv., 2020,10, 4681-4689.
[55]	S. Juntrapirom, S. Anuchai, O. Thongsook, S. Pornsuwan, P. Meepowpan, P. Thavornyutikarn, S. Phanichphant, D. Tantraviwat, B. Inceesungvorn, Chem. Eng. J., 2020,394, 124934.
[56]	M. M. Zhang, C. Lai, B. S. Li, D. L. Huang, G. M. Zeng, P. Xu, L. Qin, S. Y. Liu, X. G. Liu, H. Yi, M. F. Li, C. C. Chu, Z. Chen, J. Catal., 2019,369, 469-481.
[57]	H. Liu, H. L. Zhou, X. T. Liu, H. D. Li, C. J. Ren, X. Y. Li, W. J. Li, Z. Q. Lian, M. Zhang, J. Alloys Compd., 2019,798, 741-749.
[58]	Y. C. Bao, K. Z. Chen, Appl. Surf. Sci., 2018,437, 51-61.
[59]	C. Liu, Q. S. Wu, M. W. Ji, H. J. Zhu, H. J. Hou, Q. H. Yang, C. F. Jiang, J. J. Wang, L. Tian, J. Chen, W. H. Hou, J. Alloys Compd., 2017,723, 1121-1131.
[60]	X. M. Jia, Q. F. Han, H. Z. Liu, S. Z. Li, H. P. Bi, Chem. Eng. J., 2020,399, 125701.
[61]	L. Q. Jing, Y. C. Qu, B. Q. Wang, S. D. Li, B. J. Jiang, L. B. Yang, W. Fu, H. G. Fu, J. Z. Sun, Sol. Energy Mat. Sol. C, 2006,90, 1773-1787.
[62]	X. M. Jia, Q. F. Han, H. Z. Liu, S. Z. Li, H. P. Bi, Chem. Eng. J., 2020,399, 125701.
[63]	X. Y. Lu, J. Xie, X. B. Chen, X. Li, Appl. Catal. B, 2019,252, 250-259.
[64]	F. L. Liu, R. Shi, Z. Wang, Y. X. Weng, C. M. Che, Y. Chen, Angew. Chem. Int. Ed., 2019,58, 11791-11795.
[65]	K. Iwashina, A. Iwase, Y. H. Ng, R. Amal, A. Kudo, J. Am. Chem. Soc., 2015,137, 604-607.
[66]	J. R. Ran, B. C. Zhu, S. Z. Qiao, Angew. Chem. Int. Ed., 2017,56, 10373-10377.
[67]	Q. Xie, W. M. He, S. W. Liu, C. H. Li, J. F. Zhang, P. K. Wong, Chin. J. Catal., 2020,41, 140-153.
[68]	Z. F. Li, Z. H. Wu, R. A. He, L. Wan, S. Y. Zhang, J. Mater. Sci. Technol., 2020,56, 151-161.
[69]	J. Wang, G. H. Wang, B. Cheng, J. G. Yu, J. J. Fan, Chin. J. Catal., 2021,42, 56-68.
[70]	R. A. He, H. J. Liu, H. M. Liu, D. F. Xu, L. Y. Zhang, J. Mater. Sci. Technol., 2020,52, 145-151.
[71]	J. W. Fu, Q. L. Xu, J. X. Low, C. J. Jiang, J. G. Yu, Appl. Catal. B, 2019,243, 556-565.

BiOBr/Ni₂P/g-C₃N₄体系中用Ni₂P电子桥加速S型体系光生载流子分离

Promoting photocarriers separation in S-scheme system with Ni₂P electron bridge: The case study of BiOBr/Ni₂P/g-C₃N₄

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 10

参考文献

相关文章 15

编辑推荐

Metrics

[1]	蔡铭洁, 刘艳萍, 董珂欣, 陈晓波, 李世杰. 漂浮型Bi₂WO₆/C₃N₄/碳布S型异质结光催化材料用于高效净化水体环境[J]. 催化学报, 2023, 52(9): 239-251.
[2]	袁鑫, 范海滨, 刘杰, 覃龙州, 王剑, 段秀, 邱江凯, 郭凯. 连续流技术在光氧化还原催化转化的最新进展[J]. 催化学报, 2023, 50(7): 175-194.
[3]	Mengistu Tulu Gonfa, 申升, 陈浪, 胡彪, 周威, 白张君, 区泽堂, 尹双凤. 光催化苯制苯酚的研究进展[J]. 催化学报, 2023, 49(6): 16-41.
[4]	李宁, 高雪云, 苏俊珲, 高旸钦, 戈磊. 类金属WO₂/g-C₃N₄复合光催化剂的构造及其优异的光催化性能[J]. 催化学报, 2023, 47(4): 161-170.
[5]	王宁宁, 王硕, 李灿, 李晨阳, 刘春江, 陈闪山, 章福祥. ZrO₂修饰均匀氮掺杂氧化物MgTa₂O_6-_xN_x以提升其光催化分解水性能[J]. 催化学报, 2023, 54(11): 220-228.
[6]	刘伟旭, 贺唱, 朱博文, 朱恩伟, 张亚宁, 陈云宁, 李军山, 朱永法. 利用有机超分子光催化剂在太阳光下处理污水的研究进展[J]. 催化学报, 2023, 53(10): 13-30.
[7]	雷一鸣, 叶金花, Jordi García-Antón, 刘慧敏. 内建电场辅助光催化甲烷干重整的研究进展[J]. 催化学报, 2023, 53(10): 72-101.
[8]	杨辉, 代凯, 张金锋, Graham Dawson. 无机-有机杂化光催化剂: 合成、机理及应用[J]. 催化学报, 2022, 43(8): 2111-2140.
[9]	吴玉兰, 祁明雨, 谭昌龙, 唐紫蓉, 徐艺军. CdS/WO₃复合材料用于光催化选择性芳香醇氧化及析氢反应[J]. 催化学报, 2022, 43(7): 1851-1859.
[10]	陈方帅, 吴崇备, 郑耿锋, 曲良体, 韩庆. 少层氮化碳光催化剂合成太阳燃料和高附加值化学品: 现状与展望[J]. 催化学报, 2022, 43(5): 1216-1229.
[11]	王爱霞, 张临河, 李旭力, 高旸钦, 李宁, 卢贵武, 戈磊. 三元复合材料Ni₂P@UiO-66-NH₂/Zn_0.5Cd_0.5S的合成及其显著提升光催化产氢性能[J]. 催化学报, 2022, 43(5): 1295-1305.
[12]	张亚萍, 徐继香, 周洁, 王磊. 金属-有机框架衍生的多功能光催化剂[J]. 催化学报, 2022, 43(4): 971-1000.
[13]	赵英男, 覃星, 赵鑫宇, 王馨, 谭华桥, 孙慧颖, 闫刚, 李海玮, 何咏基, 李顺诚. 多酸掺杂Bi₂O_3-_x/Bi光催化剂用于高效可见光催化降解四溴双酚A和NO去除[J]. 催化学报, 2022, 43(3): 771-781.
[14]	李月华, 唐紫蓉, 徐艺军. 以石墨烯作用为导向的多功能石墨烯基复合光催化剂[J]. 催化学报, 2022, 43(3): 708-730.
[15]	王黎, 李雨坤, 吴超, 李鑫, 邵国胜, 张鹏. 追踪SrTiO₃/CoP/Mo₂C纳米纤维中的电荷转移路径以增强光催化产生太阳燃料[J]. 催化学报, 2022, 43(2): 507-518.